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Benzoic acid, ethyl ester

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil485. ± 2.KAVGN/AAverage of 10 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus239. ± 2.KAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Deltavap61.1 ± 0.3kJ/molGSVasiltsova, Verevkin, et al., 2006Based on data from 283. - 332. K.; AC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
360.20.013Weast and Grasselli, 1989BS
360.30.013Buckingham and Donaghy, 1982BS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
52.5 ± 0.2380.EBSteele, Chirico, et al., 2002Based on data from 369. - 531. K.; AC
49.6 ± 0.2420.EBSteele, Chirico, et al., 2002Based on data from 369. - 531. K.; AC
46.7 ± 0.3460.EBSteele, Chirico, et al., 2002Based on data from 369. - 531. K.; AC
43.6 ± 0.5500.EBSteele, Chirico, et al., 2002Based on data from 369. - 531. K.; AC
57.0356.BGKatayama, 1988Based on data from 344. - 440. K.; AC
50.5419.BGKatayama, 1988Based on data from 344. - 440. K.; AC
55.9303.AStephenson and Malanowski, 1987Based on data from 288. - 333. K.; AC
50.4373.AStephenson and Malanowski, 1987Based on data from 358. - 487. K.; AC
51.9332.N/AStull, 1947Based on data from 317. - 486. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
317. - 486.64.765032139.509-37.032Stull, 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Vasiltsova, Verevkin, et al., 2006
Vasiltsova, Tatiana V.; Verevkin, Sergey P.; Bich, Eckard; Heintz, Andreas; Bogel-Lukasik, Rafal; Domanska, Urszula, Thermodynamic Properties of Mixtures Containing Ionic Liquids. 7. Activity Coefficients of Aliphatic and Aromatic Esters and Benzylamine in 1-Methyl-3-ethylimidazolium Bis(trifluoromethylsulfonyl) Imide Using the Transpiration Method, J. Chem. Eng. Data, 2006, 51, 1, 213-218, https://doi.org/10.1021/je050334+ . [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Buckingham and Donaghy, 1982
Buckingham, J.; Donaghy, S.M., Dictionary of Organic Compounds: Fifth Edition, Chapman and Hall, New York, 1982, 1. [all data]

Steele, Chirico, et al., 2002
Steele, W.V.; Chirico, R.D.; Cowell, A.B.; Knipmeyer, S.E.; Nguyen, A., Thermodynamic Properties and Ideal-Gas Enthalpies of Formation for Methyl Benzoate, Ethyl Benzoate, ( R )-(+)-Limonene, tert -Amyl Methyl Ether, trans -Crotonaldehyde, and Diethylene Glycol, J. Chem. Eng. Data, 2002, 47, 4, 667-688, https://doi.org/10.1021/je0100847 . [all data]

Katayama, 1988
Katayama, Hirotake, Vapor pressures of methyl, ethyl, n-propyl, isobutyl, and n-butyl benzoates at reduced pressures, J. Chem. Eng. Data, 1988, 33, 2, 75-77, https://doi.org/10.1021/je00052a002 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]


Notes

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