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1-Chloro-1-methylcyclohexane

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafliquid-58.9 ± 0.3kcal/molCmArnett and Pienta, 1980Hydrochlorination

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil394.KN/ASchmerling, 1949Uncertainty assigned by TRC = 4. K; TRC
Quantity Value Units Method Reference Comment
Ttriple234.52KN/AKabo, Kozyro, et al., 1999Crystal phase 1 phase; Uncertainty assigned by TRC = 0.1 K; TRC

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Reference Comment
0.390234.5Kabo, Blokhin, et al., 1998AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Cyclohexene, 1-methyl- + Hydrogen chloride = 1-Chloro-1-methylcyclohexane

By formula: C7H12 + HCl = C7H13Cl

Quantity Value Units Method Reference Comment
Deltar-13.41 ± 0.21kcal/molCmArnett and Pienta, 1980liquid phase; solvent: Methylene chloride; Hydrochlorination

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Arnett and Pienta, 1980
Arnett, E.M.; Pienta, N.J., Stabilities of carbonium ions in solution. 12. Heats of formation of alkyl chlorides as an entree to heats of solvation of aliphatic carbonium ions, J. Am. Chem. Soc., 1980, 102, 3329-3334. [all data]

Schmerling, 1949
Schmerling, L., Condensation of Saturated Halidesw with Unsaturated Compounds V. Conden- sation of Cycloalkyl Halides with Ethylene and Vinyl Halides, J. Am. Chem. Soc., 1949, 71, 698. [all data]

Kabo, Kozyro, et al., 1999
Kabo, G.J. (see Kabo; Kozyro, A.A.; Frenkel, M. (see frenke ml); Blokhin, A.V., Solid Phase Transitions of the Cyclohexane Derivatives and the Model of Energy States of Molecules in Plastic Crystals, Mol. Cryst. Liq. Cryst., 1999, 326, 333-5. [all data]

Kabo, Blokhin, et al., 1998
Kabo, G.J.; Blokhin, A.V.; Kozyro, A.A.; Diky, V.V.; Ivashkevich, L.S.; Krasulin, A.P.; Sevruk, V.M.; Frenkel, Michael, Thermodynamic properties and phase transitions of 1-methylcyclohexanol and 1-chloro-1-methylcyclohexane, Thermochimica Acta, 1998, 313, 2, 111-124, https://doi.org/10.1016/S0040-6031(97)00481-4 . [all data]


Notes

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