Methyleugenol


Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSHP-5HP-5MSHP-101HP-101
Column length (m) 30.30.30.25.25.
Carrier gas HeN2HeHeliumHe
Substrate      
Column diameter (mm) 0.250.250.250.200.2
Phase thickness (μm) 0.250.250.250.200.2
Tstart (C) 60.60.60.70.70.
Tend (C) 250.220.280.200.200.
Heat rate (K/min) 2.5.3.3.3.
Initial hold (min) 8.10. 2.2.
Final hold (min) 30.  15.15.
I 1402.1404.1408.1402.1378.
ReferenceBenkaci-Ali, Baaliouamer, et al., 2007Flamini, Tebano, et al., 2007Kundakovic, Fokialakis, et al., 2007Politeo, Jukic, et al., 2007Politeo, Jukic, et al., 2007, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5MSHP-5MSCP Sil 5 CBBP-1
Column length (m) 30.30.30.30.50.
Carrier gas HeHeHeN2 
Substrate      
Column diameter (mm) 0.220.250.250.250.22
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 55.60.80.50.60.
Tend (C) 240.280.300.200.220.
Heat rate (K/min) 3.3.4.5.2.
Initial hold (min) 2.    
Final hold (min) 15.   20.
I 1406.1404.1407.21385.1367.
ReferenceSilva, Barbosa, et al., 2007Vagionas, Ngassapa, et al., 2007Zeng, Zhao, et al., 2007Andrianoelisoa H.S., Menut C., et al., 2006Blanc, Bradesi, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5DB-1HP-5MSDB-5
Column length (m) 50.30.30.30.30.
Carrier gas N2N2HeHeHe
Substrate      
Column diameter (mm) 0.20.250.250.250.25
Phase thickness (μm) 0.320.250.250.250.25
Tstart (C) 60.60.50.60.50.
Tend (C) 220.220.265.280.250.
Heat rate (K/min) 5.5.2.54.5.
Initial hold (min) 3.10. 5.2.
Final hold (min) 5.    
I 1401.1402.1371.1402.1404.
ReferenceEsmaeili, Nematollahi, et al., 2006Flamini, Tebano, et al., 2006Ramezani, Behravan, et al., 2006Saroglou, Dorizas, et al., 2006Su, Ho, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSDB-5DB-1DB-1HP-5
Column length (m) 30.30.30.25.30.
Carrier gas HeH2  He
Substrate      
Column diameter (mm) 0.250.250.320.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 80.35.50.60.60.
Tend (C) 300.270.250.180.260.
Heat rate (K/min) 4.5.2.3.3.
Initial hold (min)   8.10. 
Final hold (min)  20. 10. 
I 1405.51405.1403.1402.1405.
ReferenceZhao C.X., Li, et al., 2006Alves, Pinto, et al., 2005Dob, Dahmane, et al., 2005bin Jantan, Yalvema, et al., 2005Javidnia, Miri, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSDB-5DB-5DB-5DB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeN2N2N2
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.40.45.60.60.
Tend (C) 250.260.180.240.240.
Heat rate (K/min) 4.2.2.53.3.
Initial hold (min) 2.5.10.  
Final hold (min) 20.20.20.  
I 1410.1401.1412.1402.1402.
ReferencePino, Mesa, et al., 2005Senatore, Napolitano, et al., 2005Zhang, Xu, et al., 2005Flamini, Cioni, et al., 2004Flamini, Cioni, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Methyl SiliconeBP-1Optima 5DB-5HP-5
Column length (m) 50.30.25.30.30.
Carrier gas HeN2HeHeN2
Substrate      
Column diameter (mm) 0.250.320.250.250.25
Phase thickness (μm)  0.250.250.250.25
Tstart (C) 50.60.60.60.60.
Tend (C) 240.220.280.240.220.
Heat rate (K/min) 3.5.3.3.5.
Initial hold (min)     10.
Final hold (min)  13.20.  
I 1401.1364.1394.1402.1402.
ReferenceÖzcan and Chalchat, 2004Raina, Kumar, et al., 2004Vérité, Nacer, et al., 2004Flamini, Cioni, et al., 2003Flamini, Luigi Cioni, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5HP-5HP-5MSHP-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 75.60.60.50.60.
Tend (C) 230.240.280.250.280.
Heat rate (K/min) 3.3.3.3.4.
Initial hold (min) 10.   5.
Final hold (min) 20.    
I 1396.1402.1400.1402.1399.
ReferenceJantan, Ling, et al., 2003Macchioni, Cioni, et al., 2003Ngassapa, Runyoro, et al., 2003Salido, Altarejos, et al., 2003Skaltsa, Demetzos, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSHP-5HP-5SE-30RTX-5
Column length (m) 30.30.30.25.30.
Carrier gas  N2 N2He
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.60.60.60.45.
Tend (C) 280.220.280.180.300.
Heat rate (K/min) 3.5.3.3.3.
Initial hold (min) 5.10.5.10.6.
Final hold (min)    10.10.
I 1401.1403.1401.1372.1405.
ReferenceDemetzos, Angelopoulou, et al., 2002Flamini, Cioni, et al., 2002Fokialakis, Magiatis, et al., 2002bin Jantan, Ayop, et al., 2002Mondello, Zappia, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-1DB-1DB-5BP-1HP-5
Column length (m) 24.50.30.50.30.
Carrier gas HeHeH2HeHe
Substrate      
Column diameter (mm) 0.320.220.250.220.25
Phase thickness (μm) 0.170.250.250.250.25
Tstart (C) 60.60.60.60.50.
Tend (C) 250.220.240.220.280.
Heat rate (K/min) 4.2.3.2.4.
Initial hold (min) 2.   5.
Final hold (min) 20.20. 20. 
I 1371.1369.1402.1368.1401.
ReferenceNath, Sarma, et al., 2002Pintore, Usai, et al., 2002Nogueira, Bittrich, et al., 2001Rezzi, Bighelli, et al., 2001Lazari, Skaltsa, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SE-30Methyl SiliconeCP Sil 5 CBOV-1BP-1
Column length (m) 50.50.25.25.50.
Carrier gas  N2He He
Substrate      
Column diameter (mm) 0.20.250.250.250.22
Phase thickness (μm)  0.17 0.30.25
Tstart (C) 50.80.60.50.60.
Tend (C) 250.200.260.200.220.
Heat rate (K/min) 6.2.5.3.2.
Initial hold (min)    1. 
Final hold (min)    20.20.
I 1384.1376.1376.1370.1373.
ReferenceParamonov, Khalilova, et al., 2000Sumathykutty, Rao, et al., 1999Weyerstahl, Marschall, et al., 1999Bicchi, Rubiolo, et al., 1998Tam, An, et al., 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-1OV-101OV-101DB-1OV-101
Column length (m) 25.50.50.60.50.
Carrier gas H2N2N2HeH2
Substrate      
Column diameter (mm) 0.250.250.250.250.32
Phase thickness (μm) 0.3  0.25 
Tstart (C) 50.80.80.40.50.
Tend (C) 200.200.200.280.200.
Heat rate (K/min) 3.2.2.2.2.
Initial hold (min) 1.  3. 
Final hold (min) 20.  10. 
I 1370.1371.1372.1360.1369.
ReferenceBicchi, Fresia, et al., 1997Yang, Sugisawa, et al., 1992Yang, Sugisawa, et al., 1992Adedeji, Hartman, et al., 1991Pieribattesti, Smadja, et al., 1988
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillary
Active phase OV-1OV-1
Column length (m) 30.30.
Carrier gas HeHe
Substrate   
Column diameter (mm) 0.50.5
Phase thickness (μm) 0.80.8
Tstart (C) 40.40.
Tend (C) 220.220.
Heat rate (K/min) 2.2.
Initial hold (min)   
Final hold (min)   
I 1368.1373.
ReferenceDe Pooter, Omar, et al., 1985De Pooter, Omar, et al., 1985
Comment MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Benkaci-Ali, Baaliouamer, et al., 2007
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Kundakovic, Fokialakis, et al., 2007
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Politeo, Jukic, et al., 2007
Politeo, O.; Jukic, M.; Milos, M., Chemical Composition and Antioxidant Activity of Free Volatile Aglycones from Laurel (Laurus nobilis L.) Compared to Its Essential Oil, Croatica Chem. Acta, 2007, 80, 1, 121-126. [all data]

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Zhao C.X., Li, et al., 2006
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bin Jantan, Yalvema, et al., 2005
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Raina, Kumar, et al., 2004
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Vérité, Nacer, et al., 2004
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Flamini, Cioni, et al., 2003
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Flamini, Luigi Cioni, et al., 2003
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Jantan, Ling, et al., 2003
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Macchioni, Cioni, et al., 2003
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Ngassapa, Runyoro, et al., 2003
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Salido, Altarejos, et al., 2003
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Skaltsa, Demetzos, et al., 2003
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Demetzos, Angelopoulou, et al., 2002
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Flamini, Cioni, et al., 2002
Flamini, G.; Cioni, P.L.; Morelli, I., Differences in the fragrances of pollen and different floral parts of male and female flowers of Laurus nobilis, J. Agric. Food Chem., 2002, 50, 16, 4647-4652, https://doi.org/10.1021/jf020269x . [all data]

Fokialakis, Magiatis, et al., 2002
Fokialakis, N.; Magiatis, P.; Mitaku, S., Essential oil constituents of Valeriana italica and Valeriana tuberosa. Stereochemical and conformational study of 15-acetoxyvaleranone, Z. Naturforsch., 2002, 57c, 791-796. [all data]

bin Jantan, Ayop, et al., 2002
bin Jantan, I.; Ayop, N.; Hiong, A.B.; Ahmad, A.S., Chemical composition of the essential oils of Cinnamomum cordatum Kosterm, Flavour Fragr. J., 2002, 17, 3, 212-214, https://doi.org/10.1002/ffj.1075 . [all data]

Mondello, Zappia, et al., 2002
Mondello, L.; Zappia, G.; Cotroneo, A.; Bonaccorsi, I.; Chowdhury, J.U.; Yusuf, M.; Dugo, G., Studies on the essential oil-bearing plants of Bangladesh. Part VIII. Composition of some Ocimum oils O. basilicum L. var. purpurascens; O. sanctum L. green; O. sanctum L. purple; O. americanum L., citral type; O. americanum L., camphor type, Flavour Fragr. J., 2002, 17, 5, 335-340, https://doi.org/10.1002/ffj.1108 . [all data]

Nath, Sarma, et al., 2002
Nath, S.C.; Sarma, K.K.; Vajezikova, I.; Leclercq, P.A., Comparison of volatile inflorescence oils and taxonomy of certain Cymbopogon taxa described as Cymbopogon flexuosus (Nees ex Steud.) Wats., Biochem. Syst. Ecol., 2002, 30, 2, 151-162, https://doi.org/10.1016/S0305-1978(01)00066-7 . [all data]

Pintore, Usai, et al., 2002
Pintore, G.; Usai, M.; Bradesi, P.; Juliano, C.; Boatto, G.; Tomi, F.; Chessa, M.; Cerri, R.; Casanova, J., Chemical composition and antimicrobial activity of Rosmarinus officinalis L. oils from Sardinia and Corsica, Flavour Fragr. J., 2002, 17, 1, 15-19, https://doi.org/10.1002/ffj.1022 . [all data]

Nogueira, Bittrich, et al., 2001
Nogueira, P.C.L.; Bittrich, V.; Shepherd, G.J.; Lopes, A.V.; Marsaioli, A.J., The ecological and taxonomic importance of flower volatiles of Clusia species (Guttiferae), Phytochemistry, 2001, 56, 5, 443-452, https://doi.org/10.1016/S0031-9422(00)00213-2 . [all data]

Rezzi, Bighelli, et al., 2001
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Notes

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