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Oxirane, (methoxymethyl)-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C4H8O2+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
9.5PERodin, Chistyakov, et al., 1985LBLHLM
10.08PERodin, Chistyakov, et al., 1985Vertical value; LBLHLM

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CHO+14.4 ± 0.2?EIWada and Kiser, 1962RDSH
CH2+21.3 ± 0.5?EIWada and Kiser, 1962RDSH
CH2O+10.9 ± 0.2?EIWada and Kiser, 1962RDSH
CH3+16.0 ± 0.3?EIWada and Kiser, 1962RDSH
CH3O+13.9 ± 0.4?EIWada and Kiser, 1962RDSH
C2HO+13.0 ± 0.3?EIWada and Kiser, 1962RDSH
C2H2+16.2 ± 0.3?EIWada and Kiser, 1962RDSH
C2H2O+12.3 ± 0.3?EIWada and Kiser, 1962RDSH
C2H3+16.3 ± 0.2?EIWada and Kiser, 1962RDSH
C2H3O+13.1 ± 0.2?EIWada and Kiser, 1962RDSH
C2H5O+12.1 ± 0.15?EIWada and Kiser, 1962RDSH
C3H3+15.9 ± 0.4?EIWada and Kiser, 1962RDSH
C3H5O+11.2 ± 0.2CH3OEIWada and Kiser, 1962RDSH
C3H6O+10.2 ± 0.2CH2O?EIWada and Kiser, 1962RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rodin, Chistyakov, et al., 1985
Rodin, A.A.; Chistyakov, A.B.; Sarkisov, Y.S.; Sergeev, Y.L.; V'yunov, K.A.; Golovin, A.V., Electronic structure and geometric structure of three-member J. Heterocycl. Chem.. I. hotoelectron spectra of gylcidyl and thioglycidyl ethers, Russ. J. Phys. Chem., 1985, 59, 444, In original 764. [all data]

Wada and Kiser, 1962
Wada, Y.; Kiser, R.W., Electron impact spectroscopy of some substituted oxiranes, J. Phys. Chem., 1962, 66, 1652. [all data]


Notes

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