2-Hexen-1-ol, (Z)-

Formula: C₆H₁₂O
Molecular weight: 100.1589
IUPAC Standard InChI: InChI=1S/C6H12O/c1-2-3-4-5-6-7/h4-5,7H,2-3,6H2,1H3/b5-4-
IUPAC Standard InChIKey: ZCHHRLHTBGRGOT-PLNGDYQASA-N
CAS Registry Number: 928-94-9
Chemical structure:
This structure is also available as a 2d Mol file
Species with the same structure:
- (Z)-2-Hexenol
Stereoisomers:
Other names: cis-2-Hexen-1-ol; cis-2-Hexenol; Z-2-Hexen-1-ol; (Z)-2-Hexenol; (Z)-Hex-2-en-1-ol; (Z)-Hex-2-ene-1-ol; (Z)-Hex-2-enol; cis-hex-2-en-1-ol
Information on this page:
Other data available:
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Normal alkane RI, non-polar column, temperature ramp

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	RTX-1	HP-5	HP-5	SPB-1	SPB-1
Column length (m)	60.	30.	30.	30.	30.
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.22	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	50.	50.	40.	40.
T_end (C)	230.	300.	300.	200.	200.
Heat rate (K/min)	2.	5.	5.	3.	3.
Initial hold (min)		5.	5.	10.	10.
Final hold (min)	35.	5.	5.
I	827.	856.	856.	855.	855.
Reference	Paolini, Tomi, et al., 2008	Figuérédo, Cabassu, et al., 2006	Figuérédo, Cabassu, et al., 2005	Vichi, Castellote, et al., 2003	Vichi, Pizzale, et al., 2003
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	SPB-1	HP-1	OV-101	DB-1	OV-101
Column length (m)	30.	25.	15.		50.
Carrier gas	He		He		N2
Substrate
Column diameter (mm)	0.25	0.2	0.32		0.25
Phase thickness (μm)	0.25
T_start (C)	40.	35.	35.	50.	80.
T_end (C)	200.	200.	250.	230.	200.
Heat rate (K/min)	3.	5.	6.	4.	2.
Initial hold (min)	10.	5.	3.
Final hold (min)				10.
I	855.	855.	863.	847.	845.
Reference	Vichi, Pizzale, et al., 2003, 2	Quiroz A. and Niemeyer H.M., 1998	Chisholm, Guiher, et al., 1995	Binder, Turner, et al., 1990	Sugisawa, Yang, et al., 1989
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary
Active phase	OV-101
Column length (m)	50.
Carrier gas	N2
Substrate
Column diameter (mm)	0.25
Phase thickness (μm)
T_start (C)	80.
T_end (C)	200.
Heat rate (K/min)	2.
Initial hold (min)
Final hold (min)
I	846.
Reference	Sugisawa, Yang, et al., 1989
Comment	MSDC-RI

References

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes

Paolini, Tomi, et al., 2008
Paolini, J.; Tomi, P.; Bernardini, A.-F.; Bradesi, P.; Casanova, J.; Kaloustian, J., Detailed analysis of the essential oil from Cistus albidus L. by combination of GC/RI, GC/MS and 13C-NMR spectroscopy, N.Z. J. Agric. Res., 2008, 22, 14, 1270-1278. [all data]

Figuérédo, Cabassu, et al., 2006
Figuérédo, G.; Cabassu, P.; Chalchat, J.-C.; Pasquier, B., Studies of Mediterranean oregano populations. VIII. Chemical composition of essential oils of oreganos of various origins, Flavour Fragr. J., 2006, 21, 1, 134-139, https://doi.org/10.1002/ffj.1543 . [all data]

Figuérédo, Cabassu, et al., 2005
Figuérédo, G.; Cabassu, P.; Chalchat, J.-C.; Pasquier, B., Studies of Mediterranean oregano populations- V. Chemical composition of essential oils of oregano: Origanum syriacum L. var. bevanii (Holmes) Ietswaart, O. syriacum L. var. sinaicum (Boiss.) Ietswaart, and O. syriacum L. var. syriacum from Lebanon and Israel, Flavour Fragr. J., 2005, 20, 164-168. [all data]

Vichi, Castellote, et al., 2003
Vichi, S.; Castellote, A.I.; Pizzale, L.; Conte, L.S.; Buxaderas, S.; López-Tamames, E., Analysis of virgin olive oil volatile compounds by headspace solid-phase microextraction coupled to gas chromatography with mass spectrometric and flame ionization detection, J. Chromatogr. A, 2003, 983, 1-2, 19-33, https://doi.org/10.1016/S0021-9673(02)01691-6 . [all data]

Vichi, Pizzale, et al., 2003
Vichi, S.; Pizzale, L.; Conte, L.S.; Buxaderas, S.; López-Tamames, E., Solid-phase microextraction in the analysis of virgin olive oil volatile fraction: modifications induced by oxidation and suitable markers of oxidative status, J. Agric. Food Chem., 2003, 51, 22, 6564-6571, https://doi.org/10.1021/jf030268k . [all data]

Vichi, Pizzale, et al., 2003, 2
Vichi, S.; Pizzale, L.; Conte, L.S.; Buxaderas, S.; López-Tamames, E., Solid-phase microextraction in the analysis of virgin olive oil volatile fraction: characterization of virgin olive oils from two distinct geographical areas of Northern Italy, J. Agric. Food Chem., 2003, 51, 22, 6572-6577, https://doi.org/10.1021/jf030269c . [all data]

Quiroz A. and Niemeyer H.M., 1998
Quiroz A.; Niemeyer H.M., Olfactometer-assessed responses of aphid Rhopalosiphum padi to wheat and oat volatiles, J. Chem. Ecol., 1998, 24, 1, 113-124, https://doi.org/10.1023/A:1022393029987 . [all data]

Chisholm, Guiher, et al., 1995
Chisholm, M.G.; Guiher, L.A.; Zaczkiewicz, S.M., Aroma characteristics of aged Vidal blanc wine, Am. J. Enol. Vitic, 1995, 46, 1, 56-62. [all data]

Binder, Turner, et al., 1990
Binder, R.G.; Turner, C.E.; Flath, R.A., Volatile components of purple starthistle, J. Agric. Food Chem., 1990, 38, 4, 1053-1055, https://doi.org/10.1021/jf00094a030 . [all data]

Sugisawa, Yang, et al., 1989
Sugisawa, H.; Yang, R.H.; Kawabata, C.; Tamura, H., Volatile constituents in the peel oil of sudachi (Citrus sudachi), Agric. Biol. Chem., 1989, 53, 6, 1721-1723, https://doi.org/10.1271/bbb1961.53.1721 . [all data]

Notes

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References

Symbols used in this document:

T_end Final temperature

T_start Initial temperature
Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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