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Thianthrene

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil639.2KN/AWeast and Grasselli, 1989BS
Quantity Value Units Method Reference Comment
Tfus429.KN/AMayer, Howell, et al., 1990Uncertainty assigned by TRC = 1. K; TRC
Tfus429.85KN/ACullinane and Rees, 1940Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Ttriple429.570KN/ASteele, Chirico, et al., 1993Uncertainty assigned by TRC = 0.002 K; TRC
Ttriple428.43KN/ASabbah and El Watik, 1989Uncertainty assigned by TRC = 0.38 K; TRC
Quantity Value Units Method Reference Comment
Deltasub99.39 ± 0.56kJ/molCSabbah and El Watik, 1989, 2ALS
Deltasub99.4 ± 0.6kJ/molN/ASabbah and El Watik, 1989, 2AC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
477.20.015Weast and Grasselli, 1989BS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
71.2444.N/ADykyj, Svoboda, et al., 1999Based on data from 429. - 460. K.; AC
68.4475.N/ADykyj, Svoboda, et al., 1999Based on data from 460. - 539. K.; AC
72.7440.EB,IPSteele, Chirico, et al., 1993, 2Based on data from 395. - 639. K.; AC
69.9480.EB,IPSteele, Chirico, et al., 1993, 2Based on data from 395. - 639. K.; AC
67.2520.EB,IPSteele, Chirico, et al., 1993, 2Based on data from 395. - 639. K.; AC
64.5560.EB,IPSteele, Chirico, et al., 1993, 2Based on data from 395. - 639. K.; AC
61.7600.EB,IPSteele, Chirico, et al., 1993, 2Based on data from 395. - 639. K.; AC
69.1465.N/ASivaraman and Kobayashi, 1983Based on data from 430. - 593. K.; AC
68.7515.N/ASivaraman and Kobayashi, 1983Based on data from 430. - 593. K.; AC
71.1438.GSEdwards and Prausnitz, 1981Based on data from 428. - 448. K.; AC

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
103.6 ± 0.4350.IPSteele, Chirico, et al., 1993, 2AC
98.6 ± 0.5353.N/ASabbah and El Watik, 1989, 2Based on data from 338. - 368. K.; AC
98.0393.GSEdwards and Prausnitz, 1981Based on data from 358. - 428. K.; AC
97.5 ± 6.3353.HSASandman, Epstein, et al., 1979Based on data from 338. - 368. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
27.5551429.576Steele, Chirico, et al., 1993, 2DH
27.55429.6Steele, Chirico, et al., 1993, 2AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Mayer, Howell, et al., 1990
Mayer, M.M.; Howell, W.J.; Tomasko, D.L.; Eckert, C.A., Solid-solid Equilibria in the Systems Thianthrene + Phenanthrene, Salicylic Acid + Phenanthrene, and 3-Hydroxybenzoic Acid + Phenanthrene, J. Chem. Eng. Data, 1990, 35, 446. [all data]

Cullinane and Rees, 1940
Cullinane, N.M.; Rees, W.T., Isomorphous relationships of some organic compounds of analogous constitution, Trans. Faraday Soc., 1940, 36, 507. [all data]

Steele, Chirico, et al., 1993
Steele, W.V.; Chirico, R.D.; Knipmeyer, S.E.; Nguyen, A., The thermodynamic properties of thianthrene and phenoxathiin, J. Chem. Thermodyn., 1993, 25, 965-92. [all data]

Sabbah and El Watik, 1989
Sabbah, R.; El Watik, L., Thermodynamic study of the thianthrene molecule, Thermochim. Acta, 1989, 138, 241. [all data]

Sabbah and El Watik, 1989, 2
Sabbah, R.; El Watik, L., Etude thermodynamique de la molecule de thianthrene, Thermochim. Acta, 1989, 138, 241-247. [all data]

Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R., Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]

Steele, Chirico, et al., 1993, 2
Steele, W.V.; Chirico, R.D.; Knipmeyer, S.E.; Nguyen, A., The thermodynamic properties of thianthrene and phenoxathiin, J. Chem. Thermodyn., 1993, 25, 965-992. [all data]

Sivaraman and Kobayashi, 1983
Sivaraman, Alwarappa; Kobayashi, Riki, Vapor pressures and enthalpies of vaporization of thianthrene, acridine, and 9-methylanthracene at elevated temperatures, The Journal of Chemical Thermodynamics, 1983, 15, 12, 1127-1135, https://doi.org/10.1016/0021-9614(83)90003-4 . [all data]

Edwards and Prausnitz, 1981
Edwards, D.R.; Prausnitz, J.M., Vapor pressures of some sulfur-containing, coal-related compounds, J. Chem. Eng. Data, 1981, 26, 2, 121-124, https://doi.org/10.1021/je00024a005 . [all data]

Sandman, Epstein, et al., 1979
Sandman, D.J.; Epstein, A.J.; Chickos, J.S.; Ketchum, J.; Fu, J.S.; Scheraga, H.A., Crystal lattice and polarization energy of tetrathiafulvalene, J. Chem. Phys., 1979, 70, 1, 305, https://doi.org/10.1063/1.437191 . [all data]


Notes

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