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Biphenyl

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Enthalpy of combustion of solid at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Deltacsolid (kcal/mol) Method Reference Comment
-1493.3 ± 0.5CcbMontgomery, Rossini, et al., 1978Corresponding «DELTA»fsolid = 23.12 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-1494.22 ± 0.33CcbColeman and Pilcher, 1966Corresponding «DELTA»fsolid = 24.03 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-1493.35 ± 0.96CcbMackle and O'Hare, 1963Corresponding «DELTA»fsolid = 23.16 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-1493.43 ± 0.39CcbParks and Vaughan, 1951Reanalyzed by Cox and Pilcher, 1970, Original value = -1493.30 kcal/mol; Corresponding «DELTA»fsolid = 23.24 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-1493.5 ± 1.5CcbBrull, 1935Reanalyzed by Cox and Pilcher, 1970, Original value = -1493.26 kcal/mol; Corresponding «DELTA»fsolid = 23.31 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-1492.CcbWieland, Heymann, et al., 1934Corresponding «DELTA»fsolid = 22. kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-1500.0CcbBarker, 1925Author was aware that data differs from previously reported values; Corresponding «DELTA»fsolid = 29.8 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS

References

Go To: Top, Enthalpy of combustion of solid at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Montgomery, Rossini, et al., 1978
Montgomery, R.L.; Rossini, F.D.; Mansson, M., Enthalpies of combustion, vaporization, and formation of phenylbenzene, cyclohexylbenzene, and cyclohexylcyclohexane; enthalpy of hydrogenation of certain aromatic systems, J. Chem. Eng. Data, 1978, 23, 125-129. [all data]

Coleman and Pilcher, 1966
Coleman, D.J.; Pilcher, G., Heats of combustion of biphenyl, bibenzyl, naphthalene, anthracene, and phenanthrene, Trans. Faraday Soc., 1966, 62, 821-827. [all data]

Mackle and O'Hare, 1963
Mackle, H.; O'Hare, P.A.G., A high-precision aneroid semi-micro combustion calorimeter, Trans. Faraday Soc., 1963, 59, 2693-2701. [all data]

Parks and Vaughan, 1951
Parks, G.S.; Vaughan, L.M., The heat of combustion of biphenyl, J. Am. Chem. Soc., 1951, 73, 2380-2381. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Brull, 1935
Brull, L., Sui calori di combustione di alcuni derivati del bifenil, Gazz. Chim. Ital., 1935, 65, 19-28. [all data]

Wieland, Heymann, et al., 1934
Wieland, H.; Heymann, K.; Tsatsas, T.; Juchum, D.; Varvoglis, G.; Labriola, G.; Dobbelstein, O.; Boyd-Barrett, H.S., Uber das Auftreten freier Radikale bei chemischen Reaktionen. VIII, Ann., 1934, 514, 145-181. [all data]

Barker, 1925
Barker, M.F., Calorific value and constitution, J. Phys. Chem., 1925, 29, 1345-1363. [all data]


Notes

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