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Biphenyl

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Normal alkane RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5 MSHP-5HP-5BP-1HP-5
Column length (m) 30.60.30.50.30.
Carrier gas HeliumHeHeliumHe 
Substrate      
Column diameter (mm) 0.250.320.250.220.32
Phase thickness (mum) 0.250.250.250.750.25
Tstart (C) 70.30.50.50.50.
Tend (C) 290.260.280.200.310.
Heat rate (K/min) 5.2.3.5.5.
Initial hold (min)  2.3. 2.
Final hold (min) 10.28.20.  
I 1384.1385.31379.1388.1380.
ReferenceRadulovic, Blagojevic, et al., 2010Leffingwell and Alford, 2005Zenkevich, Moeder, et al., 2004Health Safety Executive, 2000Miao and Wu, 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5HP-5HP-5HP-5
Column length (m) 30.30.30.30.30.
Carrier gas      
Substrate      
Column diameter (mm) 0.320.320.320.320.32
Phase thickness (mum) 0.250.250.250.250.25
Tstart (C) 50.50.50.50.50.
Tend (C) 310.310.310.310.310.
Heat rate (K/min) 5.5.5.5.5.
Initial hold (min) 2.2.2.2.2.
Final hold (min)      
I 1380.1381.1381.1381.1382.
ReferenceMiao and Wu, 1999Miao and Wu, 1999Miao and Wu, 1999Miao and Wu, 1999Miao and Wu, 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5Ultra-1PB-1DB-5
Column length (m) 30.30.50.50.30.
Carrier gas   H2H2H2
Substrate      
Column diameter (mm) 0.320.320.20.320.32
Phase thickness (mum) 0.250.250.330.20.25
Tstart (C) 50.50.60.80.80.
Tend (C) 310.310.300.270.270.
Heat rate (K/min) 5.5.3.4.4.
Initial hold (min) 2.2. 2.2.
Final hold (min)   35.5.5.
I 1385.1385.1354.1356.1356.
ReferenceMiao and Wu, 1999Miao and Wu, 1999Elizalde-González, Hutfliess, et al., 1996Andersson and Weis, 1994Andersson and Weis, 1994
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillary
Active phase Ultra-1OV-101OV-101SE-30
Column length (m) 25.54.54.60.
Carrier gas HeHeliumHeliumN2
Substrate     
Column diameter (mm) 0.320.260.260.32
Phase thickness (mum) 0.25   
Tstart (C) 80.75.75.50.
Tend (C) 260.220.220.275.
Heat rate (K/min) 3.6.6.5.
Initial hold (min)  0.0.8.
Final hold (min)  0.0.10.
I 1342.1358.1366.1345.
ReferenceOkumura, 1991Zenkevich and Tsibulskaya, 1989Zenkevich and Tsibulskaya, 1989Ibrahim and Suffet, 1988
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Radulovic, Blagojevic, et al., 2010
Radulovic, N.; Blagojevic, P.; Palic, R., Comparative study of the leaf volatiles of Arctostaphylos uva-ursi (L.) Spreng. and Vaccinium vitis-idaea L. (Ericaceae), Molecules, 2010, 15, 9, 6168-6185, https://doi.org/10.3390/molecules15096168 . [all data]

Leffingwell and Alford, 2005
Leffingwell, J.C.; Alford, E.D., Volatile constituents of Perique tobacco, Electron. J. Environ. Agric. Food Chem., 2005, 4, 2, 899-915. [all data]

Zenkevich, Moeder, et al., 2004
Zenkevich, I.G.; Moeder, M.; Koeller, G.; Schrader, S., Using new structurally related additive schemes in the precalculation of gas chromatographic retention indices of polychlorinated hydroxybiphenyls on HP-5 stationary phase, J. Chromatogr. A, 2004, 1025, 2, 227-236, https://doi.org/10.1016/j.chroma.2003.10.106 . [all data]

Health Safety Executive, 2000
Health Safety Executive, MDHS 96 Volatile organic compounds in air - Laboratory method using pumed solid sorbent tubes, solvent desorption and gas chromatography in Methods for the Determination of Hazardous Substances (MDHS) guidance, Crown, Colegate, Norwich, 2000, 1-24, retrieved from http://www.hse.gov.uk/pubns/mdhs/pdfs/mdhs96.pdf. [all data]

Miao and Wu, 1999
Miao, X.; Wu, F., Study on retention behaviors of polycyclic aromatic hydrocarbons by gas chromatography in different operation models, J. Instrumental Anal., 1999, 15, 4, 288-292. [all data]

Elizalde-González, Hutfliess, et al., 1996
Elizalde-González, M.P.; Hutfliess, M.; Hedden, K., Retention index system, adsorption characteristics, and sructure correlations of polycyclic aromatic hydrocarbons in fuels, J. Hi. Res. Chromatogr., 1996, 19, 6, 345-352, https://doi.org/10.1002/jhrc.1240190608 . [all data]

Andersson and Weis, 1994
Andersson, J.T.; Weis, U., Gas Chromatographic Determination of Polycyclic Aromatic Compounds with Fluorinated Analogues as Internal Standards, J. Chromatogr. A, 1994, 659, 1, 151-161, https://doi.org/10.1016/0021-9673(94)85017-8 . [all data]

Okumura, 1991
Okumura, T., retention indices of environmental chemicals on methyl silicone capillary column, Journal of Environmental Chemistry (Japan), 1991, 1, 2, 333-358, https://doi.org/10.5985/jec.1.333 . [all data]

Zenkevich and Tsibulskaya, 1989
Zenkevich, I.G.; Tsibulskaya, I.A., Influence of Relative Amounts of Mixture Components on the Precision of Measurements of Gas Chromatographic Retention Indices, Zh. Anal. Khim. (Rus.), 1989, 44, 1, 90-96. [all data]

Ibrahim and Suffet, 1988
Ibrahim, E.A.; Suffet, I.H., Freon FC-113, an Alternative to Methylene Chloride for Liquid-Liquid Extraction of Trace Organics from Chlorinated Drinking Water, J. Chromatogr., 1988, 454, 217-232, https://doi.org/10.1016/S0021-9673(00)88615-X . [all data]


Notes

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