Biphenyl
- Formula: C12H10
- Molecular weight: 154.2078
- IUPAC Standard InChIKey: ZUOUZKKEUPVFJK-UHFFFAOYSA-N
- CAS Registry Number: 92-52-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Isotopologues:
- Other names: 1,1'-Biphenyl; Bibenzene; Diphenyl; Phenylbenzene; 1,1'-Diphenyl; Lemonene; Phenador-X; PhPh; Xenene; Carolid AL; Tetrosin LY; NSC 14916; 1,1-Biphenyl
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Van Den Dool and Kratz RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5 | DB-5 | DB-5 | DB-5 | DB-5 |
Column length (m) | 30. | 30. | 30. | 30. | 30. |
Carrier gas | He | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 40. | 40. | 40. | 40. | 40. |
Tend (C) | 310. | 310. | 310. | 310. | 310. |
Heat rate (K/min) | 4. | 4. | 2. | 4. | 6. |
Initial hold (min) | 5. | ||||
Final hold (min) | |||||
I | 1377.3 | 1375.4 | 1368.5 | 1377.3 | 1381.8 |
Reference | Song, Lai, et al., 2003 | Song, Lai, et al., 2003 | Song, Lai, et al., 2003 | Song, Lai, et al., 2003 | Song, Lai, et al., 2003 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-1 | OV-1 | HP-5MS | DB-5 | DB-5 |
Column length (m) | 30. | 25. | 30. | 30. | 30. |
Carrier gas | He | He | He | ||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.2 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.33 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 40. | 100. | 50. | 40. | 40. |
Tend (C) | 325. | 180. | 300. | 310. | 310. |
Heat rate (K/min) | 3. | 5. | 10. | 2. | 4. |
Initial hold (min) | |||||
Final hold (min) | |||||
I | 1338.4 | 1392.2 | 1387. | 1368.5 | 1377.3 |
Reference | Sun and Stremple, 2003 | Zhang, Shen, et al., 2000 | Nahir, 1999 | Lai and Song, 1995 | Lai and Song, 1995 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5 | DB-5 | DB-5 | SP-2100 | SP-2100 |
Column length (m) | 30. | 30. | 30. | ||
Carrier gas | He | He | He | H2 | H2 |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | ||
Phase thickness (μm) | 0.25 | 0.25 | |||
Tstart (C) | 40. | 40. | 50. | 170. | 170. |
Tend (C) | 310. | 310. | 250. | ||
Heat rate (K/min) | 6. | 4. | 4. | 2. | 4. |
Initial hold (min) | 5. | ||||
Final hold (min) | |||||
I | 1381.8 | 1375.4 | 1381. | 1375.78 | 1377.20 |
Reference | Lai and Song, 1995 | Lai and Song, 1995 | Gómez, Ledbetter, et al., 1993 | Podmaniczky, Szepesy, et al., 1986 | Podmaniczky, Szepesy, et al., 1986 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | SP-2100 | SP-2100 | SP-2100 | SP-2100 | CP Sil 5 CB |
Column length (m) | |||||
Carrier gas | H2 | H2 | H2 | H2 | H2 |
Substrate | |||||
Column diameter (mm) | |||||
Phase thickness (μm) | |||||
Tstart (C) | 170. | 170. | 170. | 170. | 170. |
Tend (C) | |||||
Heat rate (K/min) | 6. | 2. | 4. | 6. | 4. |
Initial hold (min) | |||||
Final hold (min) | |||||
I | 1377.91 | 1396.81 | 1392. | 1392.64 | 1390.72 |
Reference | Podmaniczky, Szepesy, et al., 1986 | Podmaniczky, Szepesy, et al., 1986 | Podmaniczky, Szepesy, et al., 1986 | Podmaniczky, Szepesy, et al., 1986 | Podmaniczky, Szepesy, et al., 1986 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5 | SE-30 | SE-30 | Methyl Silicone | OV-101 |
Column length (m) | 30. | 25. | 25. | 10. | 108. |
Carrier gas | He | N2 | N2 | He | |
Substrate | |||||
Column diameter (mm) | 0.26 | 0.33 | 0.33 | 0.21 | 0.25 |
Phase thickness (μm) | 0.25 | 0.2 | |||
Tstart (C) | 50. | 100. | 140. | 60. | 35. |
Tend (C) | 300. | 320. | 320. | 210. | 200. |
Heat rate (K/min) | 6. | 10. | 6. | 5. | 1. |
Initial hold (min) | 4. | ||||
Final hold (min) | 20. | ||||
I | 1384. | 1374. | 1378. | 1349. | 1350. |
Reference | Rostad and Pereira, 1986 | Korhonen and Lind, 1985 | Korhonen and Lind, 1985 | Kozloski, 1985 | Hayes and Pitzer, 1981 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary |
---|---|---|---|
Active phase | SE-52 | SE-52 | SE-52 |
Column length (m) | 33.3 | 65. | 50. |
Carrier gas | He | N2 | N2 |
Substrate | |||
Column diameter (mm) | 0.50 | 0.3 | |
Phase thickness (μm) | |||
Tstart (C) | 50. | 100. | 100. |
Tend (C) | 320. | 300. | 300. |
Heat rate (K/min) | 6. | 1.8 | 2.5 |
Initial hold (min) | 5. | ||
Final hold (min) | |||
I | 1364. | 1373. | 1362. |
Reference | Beernaert, 1979 | Carugno and Rossi, 1967 | Cantuti, Cartoni, et al., 1965 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Song, Lai, et al., 2003
Song, C.; Lai, W.-C.; Madhusudan Reddy, K.; Wei, B.,
Chapter 7. Temperature-programmed retention indices for GC and GC-MS of hydrocarbon fuels and simulated distillation GC of heavy oils
in Analytical advances for hydrocarbon research, Hsu,C.S., ed(s)., Kluwer Academic/Plenum Publishers, New York, 2003, 147-193. [all data]
Sun and Stremple, 2003
Sun, G.; Stremple, P.,
Retention index characterization of flavor, fragrance, and many other compounds on DB-1 and DB-XLB, 2003, retrieved from http://www.chem.agilent.com/cag/cabu/pdf/b-0279.pdf. [all data]
Zhang, Shen, et al., 2000
Zhang, M.-J.; Shen, S.-D.; Chen, S.-Y.; Sun, Y.-H.,
Analysis of heavy oil fractions in high-temperature coal tar by capillary gas chromatography/fourier transform infrared spectrometry,
Chin. J. Chromatogr., 2000, 18, 3, 241-246. [all data]
Nahir, 1999
Nahir, T.M.,
Analysis of semivolatile organic compounds in fuels using gas chromatography-mass spectrometry,
J. Chem. Educ., 1999, 76, 12, 1695-1696, https://doi.org/10.1021/ed076p1695
. [all data]
Lai and Song, 1995
Lai, W.-C.; Song, C.,
Temperature-programmed retention indices for g.c. and g.c.-m.s. analysis of coal- and petroleum-derived liquid fuels,
Fuel, 1995, 74, 10, 1436-1451, https://doi.org/10.1016/0016-2361(95)00108-H
. [all data]
Gómez, Ledbetter, et al., 1993
Gómez, E.; Ledbetter, C.A.; Hartsell, P.L.,
Volatile compounds in apricot, plum, and their interspecific hybrids,
J. Agric. Food Chem., 1993, 41, 10, 1669-1676, https://doi.org/10.1021/jf00034a029
. [all data]
Podmaniczky, Szepesy, et al., 1986
Podmaniczky, L.; Szepesy, L.; Lakszner, K.; Schomburg, G.,
Determination of Retention Indices in LPTGC,
Chromatographia, 1986, 21, 7, 387-391, https://doi.org/10.1007/BF02346137
. [all data]
Rostad and Pereira, 1986
Rostad, C.E.; Pereira, W.E.,
Kovats and Lee retention indices determined by gas chromatography/mass spectrometry for organic compounds of environmental interest,
J. Hi. Res. Chromatogr. Chromatogr. Comm., 1986, 9, 6, 328-334, https://doi.org/10.1002/jhrc.1240090603
. [all data]
Korhonen and Lind, 1985
Korhonen, I.O.O.; Lind, M.A.,
Gas-liquid chromatographic analyses. XXXIV. Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column,
J. Chromatogr., 1985, 322, 71-81, https://doi.org/10.1016/S0021-9673(01)97660-5
. [all data]
Kozloski, 1985
Kozloski, R.P.,
Polychlorinated biphenyl retention time standards obtained by chemical dechlorination of polychlorinated biphenyl isomers,
J. Chromatogr., 1985, 318, 211-219, https://doi.org/10.1016/S0021-9673(01)90682-X
. [all data]
Hayes and Pitzer, 1981
Hayes, P.C., Jr.; Pitzer, E.W.,
Kovats indices as a tool in characterizing hydrocarbon fuels in temperature programmed glass capillary gas chromatography. Part 1. Qualitative identification, Inhouse rpt. for Air Force Wright Aeronautical Labs., Air Force Wright Aeronautical Labs., Wright-Patterson AFB, Ohio, 1981, 75. [all data]
Beernaert, 1979
Beernaert, H.,
Gas Chromatographic Analysis of Polyclylic Aromatic Hydrocarbons,
J. Chromatogr., 1979, 173, 1, 109-118, https://doi.org/10.1016/S0021-9673(01)80450-7
. [all data]
Carugno and Rossi, 1967
Carugno, N.; Rossi, S.,
Evaluation of polynuclear hydrocarbons in cigarette smoke by glass capillary columns,
J. Gas Chromatogr., 1967, 5, 2, 103-106, https://doi.org/10.1093/chromsci/5.2.103
. [all data]
Cantuti, Cartoni, et al., 1965
Cantuti, V.; Cartoni, G.P.; Liberti, A.; Torri, A.G.,
Improved evaluation of polynuclear hydrocarbons in atmospheric dust by gas chromatography,
J. Chromatogr., 1965, 17, 60-65, https://doi.org/10.1016/S0021-9673(00)99836-4
. [all data]
Notes
Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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