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sec-Butyl nitrite

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil340. - 342.KN/AFrinton Laboratories Inc., 1986BS
Tboil341.5KN/AKornblum, Smiley, et al., 1955Uncertainty assigned by TRC = 0.5 K; TRC
Tboil341.15KN/AKornblum, Patton, et al., 1948Uncertainty assigned by TRC = 1.5 K; TRC
Quantity Value Units Method Reference Comment
Deltavap8.4kcal/molEBatt, Christie, et al., 1974ALS

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
7.07277.AStephenson and Malanowski, 1987Based on data from 267. - 287. K. See also Thompson and Dainton, 1937.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Frinton Laboratories Inc., 1986
Frinton Laboratories Inc., Catalog Number 11, Frinton Laboratories Inc., Vineland, NJ, 1986, 99. [all data]

Kornblum, Smiley, et al., 1955
Kornblum, N.; Smiley, R.A.; Ungnade, H.E.; White, A.M.; Taub, B., The reaction of silver nitrite with secondary and tertiary alkyl halides, J. Am. Chem. Soc., 1955, 77, 5528-33. [all data]

Kornblum, Patton, et al., 1948
Kornblum, N.; Patton, J.T.; Nordmann, J.B., The Basis for the Reported Optical Activity of the Salts of Aliphatic Nitro Compounds: 2-Nitrobutane, J. Am. Chem. Soc., 1948, 70, 746. [all data]

Batt, Christie, et al., 1974
Batt, L.; Christie, K.; Milne, R.T.; Summers, A.J., Heats of formation of C1-C4 alkyl nitrites (RONO) and their RO-NO bond dissociation energies, Int. J. Chem. Kinet., 1974, 6, 877-886. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Thompson and Dainton, 1937
Thompson, H.W.; Dainton, F.S., The photochemistry of alkyl nitrites. III, Trans. Faraday Soc., 1937, 33, 1546, https://doi.org/10.1039/tf9373301546 . [all data]


Notes

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