2,2,2-Trinitroethanol

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-62.4 ± 0.6kcal/molCcbLebedeva, Ryadnenko, et al., 1968Hfusion =2.70±0.30
Quantity Value Units Method Reference Comment
Δcsolid-228.2 ± 0.6kcal/molCcbLebedeva, Ryadnenko, et al., 1968Hfusion =2.70±0.30
Δcsolid-227.kcal/molCcbHandrick, 1956Assume solid

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
0.650344.9Rosen, Holden, et al., 1969AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
13.8312.5Rosen, Holden, et al., 1969, 2CAL
1.9344.9

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lebedeva, Ryadnenko, et al., 1968
Lebedeva, N.D.; Ryadnenko, V.L.; Kuznetsova, I.N., Heats of combustion and formation of nitroacetone, ethyl nitroacetate, trinitroacetonitrile, trinitroethanol, and trinitroethyl acetate, Russ. J. Phys. Chem. (Engl. Transl.), 1968, 42, 962-964. [all data]

Handrick, 1956
Handrick, G.R., Report of the study of pure explosive compounds. Part IV. Calculation of heat of combustion of organic compounds from structural features and calculation of power of high explosives, Rpt. C-58247 for the Office of the Chief of Ordnance, contract DA-19-020-ORD-47 by the Arthur D. Little, Inc., Cambridge, MA, 1956, 467-573. [all data]

Rosen, Holden, et al., 1969
Rosen, Jerome M.; Holden, James R.; Simmons, Herbert T., Heats of Transition and Fusion of Nitroalkane Alcohols and Related Nitroalkanes, Molecular Crystals, 1969, 6, 2, 205-210, https://doi.org/10.1080/15421406908082959 . [all data]

Rosen, Holden, et al., 1969, 2
Rosen, J.M.; Holden, J.R.; Simmons, H.T., Mol. Cryst. Liq. Cryst., 1969, 205. [all data]


Notes

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