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Quinoline

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis

Quantity Value Units Method Reference Comment
Tboil511. ± 2.KAVGN/AAverage of 18 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus256. ± 6.KAVGN/AAverage of 19 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple258.360KN/ASteele, Archer, et al., 1988Crystal phase 1 phase; Uncertainty assigned by TRC = 0.002 K; TRC
Quantity Value Units Method Reference Comment
Tc782.15KN/AAmbrose, 1963Uncertainty assigned by TRC = 3. K; TRC
Tc800.15KN/AGlaser and Ruland, 1957Uncertainty assigned by TRC = 3. K; TRC
Tc793.55KN/ALivingston, Morgan, et al., 1908Uncertainty assigned by TRC = 10. K; calculation based on extrap. of density and surface tension; TRC
Quantity Value Units Method Reference Comment
Pc57.80barN/AGlaser and Ruland, 1957Uncertainty assigned by TRC = 3.0398 bar; TRC
Quantity Value Units Method Reference Comment
Deltavap59.31 ± 0.20kJ/molVSteele, Archer, et al., 1988, 2ALS
Deltavap59.3kJ/molN/ASteele, Archer, et al., 1988, 2DRB
Deltavap58.1kJ/molGSVan de Rostyne and Prausnitz, 1980Based on data from 286. - 309. K.; AC
Deltavap47.45kJ/molCGlaser and Ruland, 1957ALS

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
387.20.023Weast and Grasselli, 1989BS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
46.9588.DSCBack, Grzyll, et al., 1996Based on data from 573. - 668. K.; AC
46.5519.N/ALee, Chen, et al., 1992Based on data from 504. - 616. K.; AC
57.9 ± 0.1320.IP,EBSteele, Archer, et al., 1988, 2Based on data from 298. - 559. K.; AC
55.5 ± 0.1360.IP,EBSteele, Archer, et al., 1988, 2Based on data from 298. - 559. K.; AC
53.1 ± 0.1400.IP,EBSteele, Archer, et al., 1988, 2Based on data from 298. - 559. K.; AC
50.7 ± 0.1440.IP,EBSteele, Archer, et al., 1988, 2Based on data from 298. - 559. K.; AC
48.4 ± 0.2480.IP,EBSteele, Archer, et al., 1988, 2Based on data from 298. - 559. K.; AC
46.0 ± 0.3520.IP,EBSteele, Archer, et al., 1988, 2Based on data from 298. - 559. K.; AC
46.1478.AStephenson and Malanowski, 1987Based on data from 463. - 794. K.; AC
49.2448.EBStephenson and Malanowski, 1987Based on data from 433. - 511. K. See also Malanowski, 1961.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
437.82 - 511.093.940431667.104-87.085Malanowski, 1961, 2Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
10.724257.93Mastrangelo, 1957DH
10.66258.4Domalski and Hearing, 1996AC
10.799258.4Parks, Todd, et al., 1936DH

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
41.79258.4Parks, Todd, et al., 1936DH

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
0.31220.Domalski and Hearing, 1996CAL
41.27258.4

Temperature of phase transition

Ttrs (K) Initial Phase Final Phase Reference Comment
220.093crystaline, IIcrystaline, ISteele, Chirico, et al., 1986DH
258.369crystaline, IliquidSteele, Chirico, et al., 1986DH
290.liquidliquidJalabert, Robert, et al., 1990DH

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.06818220.000crystaline, IIcrystaline, ISteele, Archer, et al., 1988, 2DH
10.66290258.369crystaline, IliquidSteele, Archer, et al., 1988, 2DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
0.310220.000crystaline, IIcrystaline, ISteele, Archer, et al., 1988, 2DH
41.27258.369crystaline, IliquidSteele, Archer, et al., 1988, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Steele, Archer, et al., 1988
Steele, W.V.; Archer, D.G.; Chirico, R.D.; Collier, W.B.; Hossenlopp, I.A.; Nguyen, A.; Smith, N.K.; Gammon, B.E., The thermodynamic properties of quinoline and isoquinoline, J. Chem. Thermodyn., 1988, 20, 1233-64. [all data]

Ambrose, 1963
Ambrose, D., Critical Temperatures of Some Phenols and Other Organic Compounds, Trans. Faraday Soc., 1963, 59, 1988. [all data]

Glaser and Ruland, 1957
Glaser, F.; Ruland, H., Untersuchungsen über dampfdruckkurven und kritische daten einiger technisch wichtiger organischer substanzen, Chem. Ing. Techn., 1957, 29, 772. [all data]

Livingston, Morgan, et al., 1908
Livingston, J.; Morgan, R.; Higgins, E., The Weight of Falling Drops and Tate's Laws. Determination of Molecular Weights and Critical Temp. of Liquids Using Drop Weights: II., Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1908, 64, 170. [all data]

Steele, Archer, et al., 1988, 2
Steele, W.V.; Archer, D.G.; Chirico, R.D.; Collier, W.B.; Hossenlopp, I.A.; Nguyen, A.; Smith, N.K.; Gammon, B.E., The thermodynamic properties of quinoline and isoquinoline, J. Chem. Thermodyn., 1988, 20, 1233-1264. [all data]

Van de Rostyne and Prausnitz, 1980
Van de Rostyne, Catherine; Prausnitz, John M., Vapor pressures of some nitrogen-containing, coal-derived liquids, J. Chem. Eng. Data, 1980, 25, 1, 1-3, https://doi.org/10.1021/je60084a008 . [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Back, Grzyll, et al., 1996
Back, Dwight D.; Grzyll, Lawrence R.; Corrigan, Mary, DSC enthalpy of vaporization measurements of high temperature two-phase working fluids, Thermochimica Acta, 1996, 272, 53-63, https://doi.org/10.1016/0040-6031(95)02615-0 . [all data]

Lee, Chen, et al., 1992
Lee, Chang Ha; Chen, Quen; Mohamed, Rahoma S.; Holder, Gerald D., Vapor-liquid equilibria in the system of toluene/aniline, aniline/naphthalene, and naphthalene/quinoline, J. Chem. Eng. Data, 1992, 37, 2, 179-183, https://doi.org/10.1021/je00006a011 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Malanowski, 1961
Malanowski, S., Bull. Acad. Pol. Sci. Ser. Sci. Chim., 1961, 9, 71. [all data]

Malanowski, 1961, 2
Malanowski, S., Vapour Pressures and Boiling Temperatures of Some Quinoline Bases, Bull. Acad. Pol. Sci. Ser. Sci. Chim., 1961, 9, 2, 71-76. [all data]

Mastrangelo, 1957
Mastrangelo, S.V.R., Adiabatic calorimeter for determination of cryoscopic data, Anal. Chem., 1957, 29(5), 841-845. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Parks, Todd, et al., 1936
Parks, G.S.; Todd, S.S.; Moore, W.A., Thermal data on organic compounds. XVI. Some heat capacity, entropy and free energy data for typical benzene derivatives and heterocyclic compounds, J. Am. Chem. Soc., 1936, 58, 398-401. [all data]

Steele, Chirico, et al., 1986
Steele, W.V.; Chirico, R.D.; Collier, W.B.; Hossenlopp, I.A.; Nguyen, A.; Strube, M.M., Thermochemical and thermophysical properties of organic nitrogen compounds found in fossil materials, NIPER Report, 1986, 188, 112p. [all data]

Jalabert, Robert, et al., 1990
Jalabert, D.; Robert, J.B.; Roux-Buisson, H., Comportment anormal en temperature de la quinline liquide, Calorim. Anal. Therm., 1990, 20-21, 441-447. [all data]


Notes

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