Naphthalene
- Formula: C10H8
- Molecular weight: 128.1705
- IUPAC Standard InChIKey: UFWIBTONFRDIAS-UHFFFAOYSA-N
- CAS Registry Number: 91-20-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Isotopologues:
- Other names: Albocarbon; Dezodorator; Moth flakes; Naphthalin; Naphthaline; Naphthene; Tar camphor; White tar; Camphor tar; Moth balls; Naftalen; NCI-C52904; Mighty 150; Mighty RD1; Rcra waste number U165; UN 1334; UN 2304; NSC 37565
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Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.)
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
ΔsubH° (kcal/mol) | Method | Reference | Comment |
---|---|---|---|
17.4 ± 0.07 | Review | Roux, Temprado, et al., 2008 | There are sufficient high-quality literature values to make a good evaluation with a high degree of confidence. In general, the evaluated uncertainty limits are on the order of (0.5 to 2.5) kJ/mol.; DRB |
16.8 | CGC-DSC | Chickos, Hesse, et al., 1998 | AC |
17.3 ± 0.1 | DSC | Torres-Gomez, Barreiro-Rodriguez, et al., 1988 | AC |
17.4 ± 0.02 | TE,ME,DM | Van Ekeren, Jacobs, et al., 1983 | See also de Kruif, Kuipers, et al., 1981.; AC |
17.3 ± 0.2 | C | Murata, Sakiyama, et al., 1982 | AC |
17.3 | GS | Sinke, 1974 | AC |
17.45 ± 0.060 | V | Irving, 1972 | ALS |
17.4 ± 0.07 | C | Irving, 1972 | AC |
17.22 ± 0.06 | V | Morawetz, 1972 | ALS |
17.2 ± 0.060 | C | Morawetz, 1972, 2 | AC |
17.4 | N/A | Coleman and Pilcher, 1966 | DRB |
17.37 ± 0.08 | V | Miller, 1963 | ALS |
17.50 ± 0.75 | V | Speros and Rossini, 1960 | ALS |
17.5 | N/A | Speros and Rossini, 1960 | DRB |
15.3 | ME | Inokuchi, 1951 | AC |
15.9 ± 0.41 | QF | Wolf and Weghofer, 1938 | AC |
15.9 ± 0.4 | V | Wolf and Weghofer, 1938, 2 | ALS |
References
Go To: Top, Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Roux, Temprado, et al., 2008
Roux, M.V.; Temprado, M.; Chickos, J.S.; Nagano, Y.,
Critically Evaluated Thermochemical Properties of Polycyclic Aromatic Hydrocarbons,
J. Phys. Chem. Ref. Data, 2008, 37, 4, 1855-1996. [all data]
Chickos, Hesse, et al., 1998
Chickos, James; Hesse, Donald; Hosseini, Sarah; Nichols, Gary; Webb, Paul,
Sublimation enthalpies at 298.15K using correlation gas chromatography and differential scanning calorimetry measurements,
Thermochimica Acta, 1998, 313, 2, 101-110, https://doi.org/10.1016/S0040-6031(97)00432-2
. [all data]
Torres-Gomez, Barreiro-Rodriguez, et al., 1988
Torres-Gomez, L.A.; Barreiro-Rodriguez, G.; Galarza-Mondragon, A.,
A new method for the measurement of enthalpies of sublimation using differential scanning calorimetry,
Thermochim. Acta, 1988, 124, 229-233. [all data]
Van Ekeren, Jacobs, et al., 1983
Van Ekeren, P.J.; Jacobs, M.H.G.; Offringa, J.C.A.; De Kruif, C.G.,
Vapour-pressure measurements on trans-diphenylethene and naphthalene using a spinning-rotor friction gauge,
The Journal of Chemical Thermodynamics, 1983, 15, 5, 409-417, https://doi.org/10.1016/0021-9614(83)90038-1
. [all data]
de Kruif, Kuipers, et al., 1981
de Kruif, C.G.; Kuipers, T.; van Miltenburg, J.C.; Schaake, R.C.F.; Stevens, G.,
The vapour pressure of solid and liquid naphthalene,
The Journal of Chemical Thermodynamics, 1981, 13, 11, 1081-1086, https://doi.org/10.1016/0021-9614(81)90006-9
. [all data]
Murata, Sakiyama, et al., 1982
Murata, S.; Sakiyama, M.; Seki, S.,
Construction and testing of a sublimation calorimetric system using a Calvet microcalorimeter,
The Journal of Chemical Thermodynamics, 1982, 14, 8, 707-721, https://doi.org/10.1016/0021-9614(82)90167-7
. [all data]
Sinke, 1974
Sinke, G.C.,
A method for measurement of vapor pressures of organic compounds below 0.1 Toor Naphthalene as a reference substance,
The Journal of Chemical Thermodynamics, 1974, 6, 4, 311-316, https://doi.org/10.1016/0021-9614(74)90160-8
. [all data]
Irving, 1972
Irving, R.J.,
The standard enthalpy of sublimation of naphthalene,
J. Chem. Thermodyn., 1972, 4, 793-794. [all data]
Morawetz, 1972
Morawetz, E.,
Enthalpies of vaporization for a number of aromatic compounds,
J. Chem. Thermodyn., 1972, 4, 455. [all data]
Morawetz, 1972, 2
Morawetz, Ernst,
Enthalpies of vaporization for a number of aromatic compounds,
The Journal of Chemical Thermodynamics, 1972, 4, 3, 455-460, https://doi.org/10.1016/0021-9614(72)90029-8
. [all data]
Coleman and Pilcher, 1966
Coleman, D.J.; Pilcher, G.,
Heats of combustion of biphenyl, bibenzyl, naphthalene, anthracene, and phenanthrene,
Trans. Faraday Soc., 1966, 62, 821-827. [all data]
Miller, 1963
Miller, G.A.,
Vapor pressure of naphthalene,
J. Chem. Eng. Data, 1963, 8, 69. [all data]
Speros and Rossini, 1960
Speros, D.M.; Rossini, F.D.,
Heats of combustion and formation of naphthalene, the two methylnaphthalenes, cis and trans decahydronaphthalene and related compounds,
J. Phys. Chem., 1960, 64, 1723-1727. [all data]
Inokuchi, 1951
Inokuchi, H.,
J. Chem. Soc. Jpn. Pure Chem. Sect., 1951, 72, 552. [all data]
Wolf and Weghofer, 1938
Wolf, K.L.; Weghofer, H.Z.,
Z. Phys. Chem. Abt. B, 1938, 39, 194. [all data]
Wolf and Weghofer, 1938, 2
Wolf, K.L.; Weghofer, H.,
Uber sublimationswarmen,
Z. Phys. Chem., 1938, 39, 194-208. [all data]
Notes
Go To: Top, Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.), References
- Symbols used in this document:
ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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