(SCN)2+

Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   J
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 58500 ± 1000 gas Frost, Kirby, et al., 1980

State:   I
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 43250 ± 320 gas Frost, Kirby, et al., 1980

State:   H
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 33480 ± 320 gas Frost, Kirby, et al., 1980

State:   G
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 25660 ± 320 gas Frost, Kirby, et al., 1980

State:   F
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 23480 ± 320 gas Frost, Kirby, et al., 1980

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 21060 ± 320 gas Frost, Kirby, et al., 1980

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 19690 ± 320 gas Frost, Kirby, et al., 1980

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 19040 ± 320 gas Frost, Kirby, et al., 1980

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 11050 ± 320 gas Frost, Kirby, et al., 1980
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a 1 CN stretch 1590 ± 60 gas PE Frost, Kirby, et al., 1980

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 2180 ± 320 gas Frost, Kirby, et al., 1980

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a 920 ± 80 gas PE Frost, Kirby, et al., 1980

Additional references: Jacox, 1994, page 346

Notes

xxEnergy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Frost, Kirby, et al., 1980
Frost, D.C.; Kirby, C.; Lau, W.M.; MacDonald, C.A.; McDowell, C.A.; Westwood, N.P.C., Thiocyanogen (SCN)2. Preparation, ultraviolet photoelectron spectrum and structure, Chem. Phys. Lett., 1980, 69, 1. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

Go To: Top, Vibrational and/or electronic energy levels, References