Carbazole

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Δfgas205.0 ± 3.0kJ/molCcbJimenez, Roux, et al., 1990ALS
Δfgas209.6 ± 3.5kJ/molCcrSabbah and Antipine, 1987ALS
Δfgas222.9kJ/molN/ATavernier and Lamouroux, 1957Value computed using ΔfHsolid° value of 125.1±3.6 kj/mol from Tavernier and Lamouroux, 1957 and ΔsubH° value of 97.8 kj/mol from Tavernier and Lamouroux, 1957.; DRB

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid101.7 ± 2.8kJ/molCcbJimenez, Roux, et al., 1990ALS
Δfsolid111.8 ± 3.5kJ/molCcrSabbah and Antipine, 1987ALS
Δfsolid125.1 ± 3.6kJ/molCcbTavernier and Lamouroux, 1957Reanalyzed by Cox and Pilcher, 1970, Original value = 136.3 kJ/mol; Author's hf298_condensed=26.844 kcal/mol; ALS
Quantity Value Units Method Reference Comment
Δcsolid-6110.1 ± 2.3kJ/molCcbJimenez, Roux, et al., 1990ALS
Δcsolid-6120.1 ± 3.4kJ/molCcrSabbah and Antipine, 1987ALS
Δcsolid-6116.2kJ/molCcbZimmerman and Geisenfelder, 1961ALS
Δcsolid-6133.5 ± 3.6kJ/molCcbTavernier and Lamouroux, 1957Reanalyzed by Cox and Pilcher, 1970, Original value = -6144.744 kJ/mol; Author's hf298_condensed=26.844 kcal/mol; ALS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
194.0298.15Jimenez, Roux, et al., 1990DH
190.8298.15Radomska and Radomski, 1980T = 180 to 410 K. Cp = 54.87 + 0.2328T + 7.477x10-4T2.; DH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jimenez, Roux, et al., 1990
Jimenez, P.; Roux, M.V.; Turrion, C., Thermochemical properties of N-heterocyclic compounds. III. Enthalpies of combustion, vapour pressures and enthalpies of sublimation, and enthalpies of formation of 9H-carbazole, 9-methylcarbazole, and 9-ethylcarbazole, J. Chem. Thermodyn., 1990, 22, 721-726. [all data]

Sabbah and Antipine, 1987
Sabbah, R.; Antipine, I., Thermodynamic study on four polycycles. Relationship between their energy values and their structure, Bull. Soc. Chim. Fr., 1987, 392-400. [all data]

Tavernier and Lamouroux, 1957
Tavernier, P.; Lamouroux, M., Determinations calorimetriques relatives a vingt et une substances organiques, Mem. Poudres, 1957, 39, 335-356. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Zimmerman and Geisenfelder, 1961
Zimmerman, H.; Geisenfelder, H., Uber die Mesomerieenergie von Azolen, Z. Electrochem., 1961, 65, 368-371. [all data]

Radomska and Radomski, 1980
Radomska, M.; Radomski, R., Calorimetric studies of binary systems of 1,3,5-trinitrobenzene with naphthalene, anthracene, and carbazole. I. Phase transitions and heat capacities of the pure components and charge-transfer complexes, Thermochim. Acta, 1980, 40, 405-414. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References