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Fluorene

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid90.2 ± 2.8kJ/molReviewRoux, Temprado, et al., 2008There are sufficient literature values to make a qualified recommendation where the suggested value is in good agreement with values predicted using thermochemical cycles or from reliable estimates. In general, the evaluated uncertainty limits are on the order of (2 to 4) kJ/mol.; DRB
Deltafsolid89.9 ± 1.4kJ/molCcrRakus, Verevkin, et al., 1994ALS
Deltafsolid86.7 ± 4.1kJ/molCcbSabbah, 1991see Sabbah and Antipine, 1987; ALS
Quantity Value Units Method Reference Comment
Deltacsolid-6634.6 ± 1.1kJ/molCcrRakus, Verevkin, et al., 1994Corresponding «DELTA»fsolid = 89.85 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-6631.5 ± 4.0kJ/molCcbSabbah, 1991see Sabbah and Antipine, 1987; Corresponding «DELTA»fsolid = 86.7 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar207.32J/mol*KN/AFinke, Messerly, et al., 1977crystaline, I phase; DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
203.13298.15Finke, Messerly, et al., 1977crystaline, I phase; T = 10 to 440 K.; DH
189.5298.1Eibert, 1944T = 25 to 200°C, equations only, in t°C. Cp(c) = 0.2479 + 0.001233t cal/g*K (25 to 70°C); Cp(liq) = 0.320 + 0.00845t cal/g*K (114 to 200°C).; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Roux, Temprado, et al., 2008
Roux, M.V.; Temprado, M.; Chickos, J.S.; Nagano, Y., Critically Evaluated Thermochemical Properties of Polycyclic Aromatic Hydrocarbons, J. Phys. Chem. Ref. Data, 2008, 37, 4, 1855-1996. [all data]

Rakus, Verevkin, et al., 1994
Rakus, K.; Verevkin, S.P.; Schatzer, J.; Beckhaus, H.-D.; Ruchardt, C., Thermochemistry and thermal decomposition of 9,9'-bifluorenyl and 9,9'-dimethyl-9,9'-bifluorenyl - the stabilization energy of 9-fluorenyl radicals, Chem. Ber., 1994, 127, 1095-1103. [all data]

Sabbah, 1991
Sabbah, R., Thermodynamic study of fluorene and dibenzofuran, Bull. Soc. Chim. Fr., 1991, 128, 350. [all data]

Sabbah and Antipine, 1987
Sabbah, R.; Antipine, I., Thermodynamic study on four polycycles. Relationship between their energy values and their structure, Bull. Soc. Chim. Fr., 1987, 392-400. [all data]

Finke, Messerly, et al., 1977
Finke, H.L.; Messerly, J.F.; Lee, S.H.; Osborn, A.G.; Douslin, D.R., Comprehensive thermodynamic studies of seven aromatic hydrocarbons, J. Chem. Thermodyn., 1977, 9, 937-956. [all data]

Eibert, 1944
Eibert, J., Thesis Washington University (St. Louis), 1944. [all data]


Notes

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