Butanoic acid, 4,4,4-trinitro-, 2,2,2-trinitroethyl ester

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-118.6kcal/molCcbFedoroff and Shefield, 1975 
Quantity Value Units Method Reference Comment
Δcsolid-650.6kcal/molCcbHandrick, 1956NBS Project 0509-10-3204 (1952)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus367.KN/AHu, Li, et al., 1990Crystal phase 1 phase; Uncertainty assigned by TRC = 0.1 K; TRC
Tfus366.KN/ARosen, Holden, et al., 1971Crystal phase 1 phase; Uncertainty assigned by TRC = 0.2 K; TRC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Method Reference Comment
1.60366.5DSCRosen, Holden, et al., 1971AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Fedoroff and Shefield, 1975
Fedoroff, B.T.; Shefield, O.E., Table 1. Standard heats of formation and heats of detonation of common explosives in Encyclopedia of Explosives and Related Items, Part 2700 Volume 7, Picatinny Arsenal, Dover, NJ., 1975, 41-42. [all data]

Handrick, 1956
Handrick, G.R., Report of the study of pure explosive compounds. Part IV. Calculation of heat of combustion of organic compounds from structural features and calculation of power of high explosives, Rpt. C-58247 for the Office of the Chief of Ordnance, contract DA-19-020-ORD-47 by the Arthur D. Little, Inc., Cambridge, MA, 1956, 467-573. [all data]

Hu, Li, et al., 1990
Hu, R.; Li, J.; Liang, Y.; Wu, S.; Sun, L.; Wang, Y., Thermal behavior of 2,2,2-trinitroethyl-4,4,4-trinitrobutyrate, J. Therm. Anal., 1990, 36, 1155-60. [all data]

Rosen, Holden, et al., 1971
Rosen, J.M.; Holden, J.R.; Simmons, H.T., Sr., Microscope, 1971, 19, 2, 151. [all data]


Notes

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