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1-Naphthalenecarboxylic acid

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil573.2KN/AAldrich Chemical Company Inc., 1990BS
Quantity Value Units Method Reference Comment
Tfus434.15KN/AKhetarpal, Lal, et al., 1979Uncertainty assigned by TRC = 2. K; TRC
Tfus433.9KN/ABerliner and Winicov, 1959Uncertainty assigned by TRC = 0.8 K; TRC
Quantity Value Units Method Reference Comment
Deltasub110.4kJ/molN/AColomina, Roux, et al., 1974DRB
Deltasub113.64kJ/molCSabbah and Gilbert, 1974ALS
Deltasub113.6kJ/molCSabbah and Gilbert, 1974AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
97.2472.AStephenson and Malanowski, 1987Based on data from 457. - 573. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
429. - 573.8.270994590.279-17.54Stull, 1947Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
110.4 ± 0.2350.5VColomina, Roux, et al., 1974ALS
110.4 ± 0.2355.MEColomina, Roux, et al., 1974Based on data from 340. - 360. K. See also Pedley and Rylance, 1977 and Stephenson and Malanowski, 1987.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
19.89435.2Acree, 1991AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Khetarpal, Lal, et al., 1979
Khetarpal, S.C.; Lal, K.; Bhatnagar, H.L., Thermodynamic Studies on Melting of Some «alpha»- and «beta»-Derivitives of Naphthalene, Aust. J. Chem., 1979, 32, 49. [all data]

Berliner and Winicov, 1959
Berliner, E.; Winicov, E.H., Dissociation Constants of Nitronaphtoic Acid, J. Am. Chem. Soc., 1959, 81, 1630-5. [all data]

Colomina, Roux, et al., 1974
Colomina, M.; Roux, M.V.; Turrion, C., Thermochemical properties of naphthalene compounds. I. Enthalpies of combustion and formation of the 1- and 2-naphthoic acids, J. Chem. Thermodyn., 1974, 6, 149-155. [all data]

Sabbah and Gilbert, 1974
Sabbah, R.; Gilbert, E.M., Determination de L'energie de conjugaison des acides naphtoiques, Thermochim. Acta, 1974, 10, 345-351. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., , Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brighton, 1977. [all data]

Acree, 1991
Acree, William E., Thermodynamic properties of organic compounds: enthalpy of fusion and melting point temperature compilation, Thermochimica Acta, 1991, 189, 1, 37-56, https://doi.org/10.1016/0040-6031(91)87098-H . [all data]


Notes

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