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Germane, tetramethyl-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
9.56 ± 0.06EIMacLean and Sacher, 1974LLK
9.33 ± 0.04PEJonas, Schweitzer, et al., 1973LLK
9.4 ± 0.1PEEvans, Green, et al., 1972LLK
9.29 ± 0.14EILappert, Pedley, et al., 1971LLK
9.29 ± 0.14EILappert, Simpson, et al., 1969RDSH
11.2EIdeRidder and Dijkstra, 1967RDSH
9.2 ± 0.2EIHobrock and Kiser, 1962Personal communication from R.M. Reese and V.H. Dibeler; RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH3+20.1 ± 0.5?EIHobrock and Kiser, 1962Personal communication from R.M. Reese and V.H. Dibeler; RDSH
CH3Ge+13.8?EIdeRidder and Dijkstra, 1967RDSH
CH3Ge+16.8 ± 0.4?EIHobrock and Kiser, 1962Personal communication from R.M. Reese and V.H. Dibeler; RDSH
CH4Ge+13.2?EIdeRidder and Dijkstra, 1967RDSH
CH5Ge+13.4?EIdeRidder and Dijkstra, 1967RDSH
C2H6Ge+14.2?EIdeRidder and Dijkstra, 1967RDSH
C2H6Ge+14.1 ± 0.2?EIHobrock and Kiser, 1962Personal communication from R.M. Reese and V.H. Dibeler; RDSH
C2H7Ge+14.2?EIdeRidder and Dijkstra, 1967RDSH
C3H9Ge+10.07 ± 0.07CH3EIMacLean and Sacher, 1974LLK
C3H9Ge+10.05 ± 0.14CH3EILappert, Pedley, et al., 1971LLK
C3H9Ge+10.05 ± 0.14CH3EILappert, Simpson, et al., 1969RDSH
C3H9Ge+11.4CH3EIdeRidder and Dijkstra, 1967RDSH
C3H9Ge+10.2 ± 0.1CH3EIHobrock and Kiser, 1962Personal communication from R.M. Reese and V.H. Dibeler; RDSH
Ge+18.1?EIdeRidder and Dijkstra, 1967RDSH
Ge+19.2 ± 0.5?EIHobrock and Kiser, 1962Personal communication from R.M. Reese and V.H. Dibeler; RDSH
GeH+17.8?EIdeRidder and Dijkstra, 1967RDSH
GeH3+17.1?EIdeRidder and Dijkstra, 1967RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

MacLean and Sacher, 1974
MacLean, D.I.; Sacher, R.E., A study of some spectroscopic properties of Group IVA acetylides, J. Organomet. Chem., 1974, 74, 197. [all data]

Jonas, Schweitzer, et al., 1973
Jonas, A.E.; Schweitzer, G.K.; Grimm, F.A.; Carlson, T.A., The photoelectron spectra of the tetrafluoro and tetramethyl compounds of the group IV elements, J. Electron Spectrosc. Relat. Phenom., 1973, 1, 29. [all data]

Evans, Green, et al., 1972
Evans, S.; Green, J.C.; Joachim, P.J.; Orchard, A.F.; Turner, D.W.; Maier, J.P., Electronic structures of the Group IVB tetramethyls by helium-(I) photoelectron spectroscopy, J. Chem. Soc. Faraday Trans. 2, 1972, 68, 905. [all data]

Lappert, Pedley, et al., 1971
Lappert, M.F.; Pedley, J.B.; Simpson, J.; Spalding, T.R., Bonding studies of compounds of boron and the Group IV elements. VI. Mass spectrometric studies on compounds Me4M and Me3M-M'Me3 (M and M'=C, Si, Ge, Sn, and Pb): thermochemical data, J. Organomet. Chem., 1971, 29, 195. [all data]

Lappert, Simpson, et al., 1969
Lappert, M.F.; Simpson, J.; Spalding, T.R., Bonding studies of compounds of the group IV elements: ionisation potentials of the Me3M radicals, J.Organometal. Chem., 1969, 17, PI. [all data]

deRidder and Dijkstra, 1967
deRidder, J.J.; Dijkstra, G., Mass spectra of the tetramethyl and tetraethyl compounds of carbon, silicon, germanium, tin and lead, Rec. Trav. Chim., 1967, 86, 737. [all data]

Hobrock and Kiser, 1962
Hobrock, B.G.; Kiser, R.W., Electron impact spectroscopy of tetramethylgermanium, trimethylsilane, and dimethylmercury, J. Phys. Chem., 1962, 66, 155. [all data]


Notes

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