CH3NiH

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Td = 25000 T Ar Chang, Hauge, et al., 1988

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
CH stretch 2950.5 Ar IR Chang, Hauge, et al., 1988
CH stretch 2861.0 Ar IR Chang, Hauge, et al., 1988
NiH stretch 1945.1 Ar IR Chang, Hauge, et al., 1988
Himmel, 2004
CH3 deform. 1139.0 Ar IR Chang, Hauge, et al., 1988
CH3 deform. 1120.3 Ar IR Chang, Hauge, et al., 1988
CH3 rock 642.7 Ar IR Chang, Hauge, et al., 1988
NiC stretch 554.9 Ar IR Chang, Hauge, et al., 1988

Additional references: Jacox, 1994, page 306

Notes

TTentative assignment or approximate value
dPhotodissociation threshold

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chang, Hauge, et al., 1988
Chang, S.-C.; Hauge, R.H.; Billups, W.E.; Margrave, J.L.; Kafafi, Z.H., Low-temperature reactions of methane with photoexcited nickel atoms, Inorg. Chem., 1988, 27, 1, 205, https://doi.org/10.1021/ic00274a043 . [all data]

Himmel, 2004
Himmel, H.-J., A Comparison of the Reactivity of Ni Atoms Toward CH4, SiH4, and SnH4: A Combined Matrix Isolation and Quantum-Chemical Study, Chem. Eur. J., 2004, 10, 11, 2851, https://doi.org/10.1002/chem.200305763 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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