Methyl(1,1,2-trimethylpropyl)malononitrile

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas18.96 ± 0.23kcal/molCcbBeckhaus, Dogan, et al., 1990 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid4.13 ± 0.15kcal/molCcbBeckhaus, Dogan, et al., 1990 
Quantity Value Units Method Reference Comment
Δcsolid-1491.16 ± 0.15kcal/molCcbBeckhaus, Dogan, et al., 1990 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub14.83 ± 0.17kcal/molVBeckhaus, Dogan, et al., 1990ALS
Δsub14.8kcal/molN/ABeckhaus, Dogan, et al., 1990DRB
Δsub14.8 ± 0.2kcal/molN/ABeckhaus, Dogan, et al., 1990AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Beckhaus, Dogan, et al., 1990
Beckhaus, H.D.; Dogan, B.; Pakusch, J.; Verevkin, S.; Ruechardt, C., Geminal substituent effects. 4. The dependence of the inverse anomeric effect of geminal cyano groups on the structure, Chem. Ber., 1990, 123, 2153-2159. [all data]


Notes

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