Phenanthrene
- Formula: C14H10
- Molecular weight: 178.2292
- IUPAC Standard InChI: InChI=1S/C14H10/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13/h1-10H
- IUPAC Standard InChIKey: YNPNZTXNASCQKK-UHFFFAOYSA-N
- CAS Registry Number: 85-01-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Isotopologues:
- Other names: Phenanthren; Phenanthrin; Phenantrin
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Enthalpy of combustion of solid at standard conditions (nominally 298.15 K, 1 atm.)
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| ΔcH°solid (kcal/mol) | Method | Reference | Comment |
|---|---|---|---|
| -1684.52 ± 0.35 | Ccb | Steele, Chirico, et al., 1990 | Δ Hfusion = 15.96±0.05 kJ/mol; Corresponding ΔfHºsolid = 26.233 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS |
| -1686.06 ± 0.30 | Ccb | Coleman and Pilcher, 1966 | Author was aware that data differs from previously reported values; Corresponding ΔfHºsolid = 27.77 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS |
| -1685.3 | Ccb | Bender and Farber, 1952 | Corresponding ΔfHºsolid = 27.0 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS |
| -1684.88 ± 0.34 | Ccb | Magnus, Hartmann, et al., 1951 | Corresponding ΔfHºsolid = 26.59 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS |
| -1675.70 ± 0.61 | Ccb | Richardson and Parks, 1939 | High level of uncertainty in the data; Reanalyzed by Cox and Pilcher, 1970, Original value = -1674.95 kcal/mol; see Richardson, 1939; Corresponding ΔfHºsolid = 17.41 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS |
| -1685.20 ± 0.64 | Ccb | Fries, Walter, et al., 1935 | Reanalyzed by Cox and Pilcher, 1970, Original value = -1684.2 kcal/mol; Corresponding ΔfHºsolid = 26.91 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS |
| -1676.46 | Ccb | Milone and Rossignoli, 1932 | Corresponding ΔfHºsolid = 18.17 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS |
References
Go To: Top, Enthalpy of combustion of solid at standard conditions (nominally 298.15 K, 1 atm.), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Steele, Chirico, et al., 1990
Steele, W.V.; Chirico, R.D.; Nguyen, A.; Hossenlopp, I.A.; Smith, N.K.,
Determination of ideal-gas enthalpies of formation for key compounds,
Am. Inst. Chem. Eng. Symp. Ser. (AIChE Symp. Ser.), 1990, 138-154. [all data]
Coleman and Pilcher, 1966
Coleman, D.J.; Pilcher, G.,
Heats of combustion of biphenyl, bibenzyl, naphthalene, anthracene, and phenanthrene,
Trans. Faraday Soc., 1966, 62, 821-827. [all data]
Bender and Farber, 1952
Bender, P.; Farber, J.,
The heats of combustion of anthracene transannular peroxide and dianthracene,
J. Am. Chem. Soc., 1952, 74, 1450-1452. [all data]
Magnus, Hartmann, et al., 1951
Magnus, A.; Hartmann, H.; Becker, F.,
Verbrennungswarmen und resonanzenergien von mehrkernigen aromatischen kohlenwasserstoffen,
Z. Phys. Chem., 1951, 197, 75-91. [all data]
Richardson and Parks, 1939
Richardson, J.W.; Parks, G.S.,
Thermal data on organic compounds. XIX. Modern combustion data for some non-volatile compounds containing carbon, hydrogen and oxygen,
J. Am. Chem. Soc., 1939, 61, 3543-3546. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Richardson, 1939
Richardson, J.W.,
Precise determination of the heats of combustion of some representative organic compounds, Ph.D. Thesis for Standford University, 1939, 1-122. [all data]
Fries, Walter, et al., 1935
Fries, K.; Walter, R.; Schilling, K.,
Uber tricyclische verbindungen in denen naphtalin mit einem heterocyclus anelliert ist,
Ann. Chim., 1935, 516, 248-285. [all data]
Milone and Rossignoli, 1932
Milone, M.; Rossignoli, P.,
Sul calore di combustione di alcune miscele di composti organici,
Gazz. Chim. Ital., 1932, 62, 644-655. [all data]
Notes
Go To: Top, Enthalpy of combustion of solid at standard conditions (nominally 298.15 K, 1 atm.), References
- Symbols used in this document:
ΔcH°solid Enthalpy of combustion of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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