F3PO+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   G
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 85800 ± 1100 gas Basset and Lloyd, 1972

State:   F
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 61240 ± 480 gas Basset and Lloyd, 1972
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
654 ± 80 gas PE Basset and Lloyd, 1972

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 55190 ± 400 gas Basset and Lloyd, 1972
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
718 ± 50 gas PE Basset and Lloyd, 1972

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 45830 ± 480 gas Basset and Lloyd, 1972
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
718 ± 25 gas PE Basset and Lloyd, 1972

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 39620 T gas Basset and Lloyd, 1972

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 31630 ± 720 gas Basset and Lloyd, 1972

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 19280 ± 640 gas Basset and Lloyd, 1972

Additional references: Jacox, 1994, page 298

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Basset and Lloyd, 1972
Basset, P.J.; Lloyd, D.R., Photoelectron spectra of halides. Part III. Trifluorides and oxide trifluorides of nitrogen and phosphorus, and phosphorus oxide trichloride, J. Chem. Soc. Dalton Trans., 1972, 248. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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