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Undecafluoropiperidine

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-2003.7 ± 5.0kJ/molCcbGood, Todd, et al., 1963Reanalyzed by Cox and Pilcher, 1970, Original value = -1990.7 kJ/mol; Heat of combustion corrected for CF4 formation
Deltafgas-1995.kJ/molCcrGood and Scott, 1959Private communication

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-2071.3 ± 4.6kJ/molCcbGood, Todd, et al., 1963Reanalyzed by Cox and Pilcher, 1970, Original value = -2020.6 kJ/mol; Heat of combustion corrected for CF4 formation; ALS
Deltafliquid-2020.kJ/molCcrGood and Scott, 1959Private communication; ALS
Quantity Value Units Method Reference Comment
Deltacliquid-1463. ± 3.kJ/molCcbGood, Todd, et al., 1963Heat of combustion corrected for CF4 formation; ALS
Quantity Value Units Method Reference Comment
liquid393.38J/mol*KN/AGood, Todd, et al., 1963DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
296.77298.15Good, Todd, et al., 1963T = 12 to 320 K.; DH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Good, Todd, et al., 1963
Good, W.D.; Todd, S.S.; Messerly, J.F.; Lacina, J.L.; Dawson, J.P.; Scott, D.W.; McCullough, J.P., Perfluoropiperidine: Entropy, heat of formation, and vapor pressure; N-F bond energy; and solid-state transitions, J. Phys. Chem., 1963, 67, 1306-1311. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Good and Scott, 1959
Good, W.D.; Scott, D.W., Thermochemistry of organic fluorine compounds and carbon compounds of metals by rotating-bomb calorimetry, Symposium uber Thermodynamik, Freitag, 1959, 1-7. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References