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Adamantane-1-carboxylic acid

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafsolid-153.70kcal/molCcbSteele, Carson, et al., 1973 
Quantity Value Units Method Reference Comment
Deltacsolid-1427.38 ± 0.86kcal/molCcbSteele, Carson, et al., 1973Corresponding «DELTA»fsolid = -153.70 kcal/mol (simple calculation by NIST; no Washburn corrections)

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C11H15O2- + Hydrogen cation = Adamantane-1-carboxylic acid

By formula: C11H15O2- + H+ = C11H16O2

Quantity Value Units Method Reference Comment
Deltar343.0 ± 2.1kcal/molG+TSCaldwell, Renneboog, et al., 1989gas phase
Deltar343.6 ± 2.1kcal/molG+TSJinfeng, Topsom, et al., 1988gas phase; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Deltar336.0 ± 2.0kcal/molIMRECaldwell, Renneboog, et al., 1989gas phase
Deltar336.6 ± 2.0kcal/molIMREJinfeng, Topsom, et al., 1988gas phase; value altered from reference due to change in acidity scale

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Steele, Carson, et al., 1973
Steele, W.V.; Carson, A.S.; Laye, P.G.; Rosser, C.A., Enthalpies of formation of adamantanoid compounds. Part 3.-Adamantanecarboxylic acids, J. Chem. Soc. Faraday Trans. 1, 1973, 69, 1257-1260. [all data]

Caldwell, Renneboog, et al., 1989
Caldwell, G.; Renneboog, R.; Kebarle, P., Gas Phase Acidities of Aliphatic Carboxylic Acids, Based on Measurements of Proton Transfer Equilibria, Can. J. Chem., 1989, 67, 4, 661, https://doi.org/10.1139/v89-092 . [all data]

Jinfeng, Topsom, et al., 1988
Jinfeng, C.; Topsom, R.D.; Headley, A.D.; Koppel, I.; Mishima, M.; Taft, R.W.; Veji, S., Acidities of Substituted Acetic Acids, J. Mol. Struct., 1988, 168, 141, https://doi.org/10.1016/0166-1280(88)80349-X . [all data]


Notes

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