2-Nonanone
- Formula: C9H18O
- Molecular weight: 142.2386
- IUPAC Standard InChIKey: VKCYHJWLYTUGCC-UHFFFAOYSA-N
- CAS Registry Number: 821-55-6
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Heptyl methyl ketone; Methyl heptyl ketone; Methyl n-heptyl ketone; Nonan-2-one; n-C7H15COCH3; β-Nonanone; Ketone, heptyl methyl; Nonanone-2
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Normal alkane RI, polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | RTX-Wax | DB-Wax | CP-Wax | Innowax | HP Innowax |
Column length (m) | 60. | 30. | 60. | 30. | 30. |
Carrier gas | Helium | Helium | Helium | Helium | |
Substrate | |||||
Column diameter (mm) | 0.22 | 0.32 | 0.25 | 0.25 | 0.32 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.50 |
Tstart (C) | 60. | 50. | 40. | 60. | |
Tend (C) | 230. | 240. | 230. | 200. | 260. |
Heat rate (K/min) | 2. | 6. | 6. | 10. | 3. |
Initial hold (min) | 2. | 5. | |||
Final hold (min) | 5. | 5. | 15. | 15. | |
I | 1392. | 1402. | 1366. | 1388. | 1385. |
Reference | Bendiabdellah, El Amine Dib, et al., 2012 | Mallia, Escher, et al., 2009 | Mo, Fan, et al., 2009 | Kaypak and Avsar, 2008 | Capetanos, Saroglou, et al., 2007 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | Stabilwax | HP-Wax | CP-Wax 52CB | CP-Wax 52CB | CP-Wax 52CB |
Column length (m) | 60. | 30. | 30. | 60. | 60. |
Carrier gas | Helium | N2 | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.32 | 0.32 | 0.32 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.5 | 0.5 |
Tstart (C) | 40. | 50. | 40. | 40. | 40. |
Tend (C) | 240. | 250. | 220. | 220. | 220. |
Heat rate (K/min) | 3. | 5. | 3. | 4. | 4. |
Initial hold (min) | 5. | 1. | 8. | 8. | |
Final hold (min) | 10. | 10. | 2. | 20. | 20. |
I | 1380. | 1392. | 1392. | 1392. | 1389. |
Reference | Cros, Vandanjon, et al., 2007 | Fredj, Marzouk, et al., 2007 | Hymete, Rohloff, et al., 2007 | Povolo, Contarini, et al., 2007 | Povolo, Contarini, et al., 2007 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | Supelcowax-10 | Innowax | TC-Wax | Stabilwax DA | DB-Wax |
Column length (m) | 30. | 50. | 60. | 60. | 60. |
Carrier gas | He | He | N2 | Nitrogen | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.2 | 0.25 | 0.25 | 0.32 |
Phase thickness (μm) | 0.25 | 0.5 | 0.25 | 0.5 | 0.50 |
Tstart (C) | 50. | 60. | 70. | 40. | 35. |
Tend (C) | 220. | 250. | 220. | 180. | 235. |
Heat rate (K/min) | 4. | 2. | 3. | 5. | 2. |
Initial hold (min) | 1. | 5. | 4. | ||
Final hold (min) | 10. | 60. | 40. | 30. | |
I | 1391. | 1393. | 1398. | 1412. | 1417. |
Reference | Wong, Lim, et al., 2006 | Bendimerad and Bendiab, 2005 | Ishizaki, Tachihara, et al., 2005 | Nogueira, Lubachevsky, et al., 2005 | Qian and Wang, 2005 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | Supelcowax-10 | Supelcowax-10 | ZB-Wax | PEG-20M | Stabilwax |
Column length (m) | 60. | 60. | 30. | 50. | 60. |
Carrier gas | He | He | Helium | Helium | |
Substrate | |||||
Column diameter (mm) | 0.53 | 0.53 | 0.32 | 0.20 | 0.25 |
Phase thickness (μm) | 1. | 1. | 0.25 | 0.20 | 0.25 |
Tstart (C) | 40. | 40. | 40. | 40. | 40. |
Tend (C) | 240. | 240. | 250. | 180. | 240. |
Heat rate (K/min) | 4. | 4. | 5. | 3. | 3. |
Initial hold (min) | 2. | 2. | 2. | 5. | 5. |
Final hold (min) | 20. | 20. | 5. | 30. | 10. |
I | 1405. | 1415. | 1379. | 1350. | 1380. |
Reference | Rochat and Chaintreau, 2005 | Rochat and Chaintreau, 2005 | N/A | Narain, Almeida, et al., 2004 | Cros, Vandanjon, et al., 2003 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | CP-Wax 52CB | DB-Wax | DB-Wax | Carbowax 20M | HP-FFAP |
Column length (m) | 60. | 30. | 30. | 25. | 25. |
Carrier gas | He | N2 | |||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.32 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.52 |
Tstart (C) | 40. | 30. | 30. | 50. | 60. |
Tend (C) | 220. | 250. | 250. | 250. | 240. |
Heat rate (K/min) | 3. | 4. | 4. | 4. | 5. |
Initial hold (min) | 1. | 1. | 1. | ||
Final hold (min) | 10. | 5. | |||
I | 1388. | 1388. | 1388. | 1420. | 1372. |
Reference | Mau, Lai, et al., 2003 | Tanaka, Yamauchi, et al., 2003 | Tanaka, Yamauchi, et al., 2003 | Zrira, Elamrani, et al., 2003 | Qian and Reineccius, 2002 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-Wax | TC-Wax | Supelcowax-10 | DB-Wax | DB-Wax |
Column length (m) | 30. | 60. | 60. | 30. | 30. |
Carrier gas | Helium | He | He | ||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.53 | 0.53 |
Phase thickness (μm) | 0.25 | 0.25 | |||
Tstart (C) | 25. | 80. | 35. | 60. | 60. |
Tend (C) | 220. | 250. | 200. | 210. | 210. |
Heat rate (K/min) | 4. | 4. | 4. | 4. | 4. |
Initial hold (min) | 10. | ||||
Final hold (min) | 30. | 47. | |||
I | 1383. | 1397. | 1405. | 1405. | 1401. |
Reference | Duque, Bonilla, et al., 2001 | Miyazawa, Kurose, et al., 2001 | Girard and Durance, 2000 | Iwatsuki, Mizota, et al., 1999 | Iwatsuki, Mizota, et al., 1999 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-Wax | TC-Wax | DB-Wax | Carbowax 20M | PEG-20M |
Column length (m) | 60. | 60. | 60. | 50. | 50. |
Carrier gas | He | He | N2 | ||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 1. | ||||
Tstart (C) | 50. | 80. | 60. | 60. | 60. |
Tend (C) | 200. | 240. | 220. | 180. | 180. |
Heat rate (K/min) | 3. | 3. | 3. | 2. | 2. |
Initial hold (min) | 5. | 4. | 4. | ||
Final hold (min) | 40. | ||||
I | 1381. | 1389. | 1405. | 1366. | 1373. |
Reference | Horiuchi, Umano, et al., 1998 | Shuichi, Masazumi, et al., 1996 | Chung, Eiserich, et al., 1993 | Kawakami and Kobayashi, 1991 | Kubota, Nakamoto, et al., 1991 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | Carbowax 20M | SP-1000 | DB-Wax | DB-Wax | Supelcowax-10 |
Column length (m) | 80. | 25. | 30. | 60. | 60. |
Carrier gas | N2 | He | |||
Substrate | |||||
Column diameter (mm) | 0.2 | 0.2 | 0.32 | 0.32 | 0.25 |
Phase thickness (μm) | 0.43 | 0.25 | |||
Tstart (C) | 70. | 60. | 70. | 50. | 40. |
Tend (C) | 170. | 190. | 200. | 250. | 175. |
Heat rate (K/min) | 2. | 4. | 4. | 4. | 1. |
Initial hold (min) | 2. | 0.1 | 5. | ||
Final hold (min) | 30. | 5. | |||
I | 1420. | 1397. | 1401. | 1384. | 1390. |
Reference | Anker, Jurs, et al., 1990 | De Llano D.G., Ramos M., et al., 1990 | Wyllie, Brophy, et al., 1990 | Binder and Flath, 1989 | Hsieh, Williams, et al., 1989 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary |
---|---|
Active phase | Carbowax 20M |
Column length (m) | 31. |
Carrier gas | Helium |
Substrate | |
Column diameter (mm) | 0.50 |
Phase thickness (μm) | |
Tstart (C) | 40. |
Tend (C) | 200. |
Heat rate (K/min) | 10. |
Initial hold (min) | |
Final hold (min) | |
I | 1386. |
Reference | Labropoulos, Palmer, et al., 1982 |
Comment | MSDC-RI |
References
Go To: Top, Normal alkane RI, polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bendiabdellah, El Amine Dib, et al., 2012
Bendiabdellah, A.; El Amine Dib, M.; Djabou, N.; Allali, H.; Tabti, B.; Costa, J.; Myseli, A.,
Biological activities and volatile cinstituents of Daucus muricatus L. from Algeria,
Chem. Centr. J., 2012, 6, 48, 1-22. [all data]
Mallia, Escher, et al., 2009
Mallia, S.; Escher, F.; Dubois, S.; Schieberle, P.; Schlichtherle-Cerny, H.,
Characterization and quantification of odor-active compounds in unsaturated fatty acid/conjugated linoleic acid (UFA/CLA)-enriched butter and in conventional butter during storage and induced oxidation,
J. Agric. Food Chem., 2009, 57, 16, 7464-7472, https://doi.org/10.1021/jf9002158
. [all data]
Mo, Fan, et al., 2009
Mo, X.; Fan, W.; Xu, Y.,
Changes in volatile compounds of Chinese rice wine wheat qu during fermentation and storage,
J. of the Institute of Brewing, 2009, 115, 4, 300-307, https://doi.org/10.1002/j.2050-0416.2009.tb00385.x
. [all data]
Kaypak and Avsar, 2008
Kaypak, D.; Avsar, Y.K.,
Volatile and odor-active compounds of tuzlu yoghurt,
Asian J. Chem., 2008, 20, 5, 3641-3648. [all data]
Capetanos, Saroglou, et al., 2007
Capetanos, C.; Saroglou, V.; Marin, P.D.; Simic, A.; Skaltsa, H.D.,
Essential oil snalysis of two endemic Eringium species from Serbia,
J. Serb. Chem. Soc., 2007, 72, 10, 961-965, https://doi.org/10.2298/JSC0710961C
. [all data]
Cros, Vandanjon, et al., 2007
Cros, S.; Vandanjon, L.; Jaouen, P.; Bourseau, P.,
Processing of Industrial Mussel Cooking Juices by Reverse Osmotis: Pollution Abatement and Aromas Recovery, 2007, retrieved from title of Internet file: [imstec064]. [all data]
Fredj, Marzouk, et al., 2007
Fredj, M.B.H.; Marzouk, B.; Chraief, I.; Boukef, K.; Marzouk, Z.,
Analysis of Tunisian Ruta graveolens L. oils from Jemmel,
Journal of Food, Agriculture Environment, 2007, 5, 1, 52-55. [all data]
Hymete, Rohloff, et al., 2007
Hymete, A.; Rohloff, J.; Iversen, T.-H.; Kjosen, H.,
Volatile constituents of the roots of Echinops kebericho Mesfin,
Flavour Fragr. J., 2007, 22, 1, 35-38, https://doi.org/10.1002/ffj.1746
. [all data]
Povolo, Contarini, et al., 2007
Povolo, M.; Contarini, G.; Mele, M.; Secchiari, P.,
Study on the influence of pasture on volatile fraction of Ewes' dairy products by solid-phase microextraction and gas chromatography-mass spectrometry,
J. Dairy Sci., 2007, 90, 2, 556-569, https://doi.org/10.3168/jds.S0022-0302(07)71539-4
. [all data]
Wong, Lim, et al., 2006
Wong, K.C.; Lim, T.B.; Ali, D.M.H.,
Essential oil of Homalomena sagittifolia Jungh.,
Flavour Fragr. J., 2006, 21, 5, 786-788, https://doi.org/10.1002/ffj.1714
. [all data]
Bendimerad and Bendiab, 2005
Bendimerad, N.; Bendiab, S.A.T.,
Composition and antibacterial activity of Pseudocytisus integrifolius (Salisb.) essential oil from Algeria,
J. Agric. Food Chem., 2005, 53, 8, 2947-2952, https://doi.org/10.1021/jf047937u
. [all data]
Ishizaki, Tachihara, et al., 2005
Ishizaki, S.; Tachihara, T.; Tamura, H.; Yanai, T.; Kitahara, T.,
Evaluation of odour-active compounds in roasted shrimp (Sergia lucens Hansen) by aroma extract dilution analysis,
Flavour Fragr. J., 2005, 20, 6, 562-566, https://doi.org/10.1002/ffj.1484
. [all data]
Nogueira, Lubachevsky, et al., 2005
Nogueira, M.C.L.; Lubachevsky, G.; Rankin, S.A.,
A study of the volatile composition of Minas cheese,
Lebensm. Wiss. Technol., 2005, 38, 5, 555-563, https://doi.org/10.1016/j.lwt.2004.07.019
. [all data]
Qian and Wang, 2005
Qian, M.C.; Wang, Y.,
Seasonal Variations of Volatile Composition and Odor Activity Value of Marion (Rubus spp. hyb) and Thornless Evergreen (R.laciniatus L.) Blackberries,
J. Food. Sci., 2005, 70, 1, c13-c20, https://doi.org/10.1111/j.1365-2621.2005.tb09013.x
. [all data]
Rochat and Chaintreau, 2005
Rochat, S.; Chaintreau, A.,
Carbonyl Odorants Contributing to the In-Oven Roast Beef Top Note,
J. Agric. Food Chem., 2005, 53, 24, 9578-9585, https://doi.org/10.1021/jf058089l
. [all data]
Narain, Almeida, et al., 2004
Narain, N.; Almeida, J.N.; Galvão, M.S.; Madruga, M.S.; de Brito, E.S.,
Volatile compounds in passion fruit (Passiflora edulis forma Flavicarpa) and yellow mombin (Spondias mombin L.) fruits obtained by dynamic headspace technique,
Cienc. Tecnol. Aliment. Campinas, 2004, 24, 2, 212-216, https://doi.org/10.1590/S0101-20612004000200009
. [all data]
Cros, Vandanjon, et al., 2003
Cros, S.; Vandanjon, L.; Jaouen, P.; Bourseau, P.,
IMSTEC'03 Conference Proceedings, Processing of industrial mussel cooking juices by reverse osmosis: pollution abatement and aromas recovery, Universoty of New South Wales, Sydney, Australia, 2003, 6. [all data]
Mau, Lai, et al., 2003
Mau, J.-L.; Lai, E.Y.C.; Wang, N.-P.; Chen, C.-C.; Chang, C.-H.; Chyau, C.-C.,
Composition and antioxidant activity of the essential oil from Curcuma zedoaria,
Food Chem., 2003, 82, 4, 583-591, https://doi.org/10.1016/S0308-8146(03)00014-1
. [all data]
Tanaka, Yamauchi, et al., 2003
Tanaka, T.; Yamauchi, T.; Katsumata, R.; Kiuchi, K.,
Comparison of volatile components in commercial Itohiki-Natto by solid phase microextraction and gas chromatography,
Nippon Shokuhin Kagaku Kogaku Kaishi, 2003, 50, 6, 278-285, https://doi.org/10.3136/nskkk.50.278
. [all data]
Zrira, Elamrani, et al., 2003
Zrira, S.; Elamrani, A.; Benjilali, B.,
Chemical composition of the essential oil of Pistacia lentiscus L. from Morocco - a seasonal variation,
Flavour Fragr. J., 2003, 18, 6, 475-480, https://doi.org/10.1002/ffj.1221
. [all data]
Qian and Reineccius, 2002
Qian, M.; Reineccius, G.,
Identification of aroma compounds in Parmigiano-Reggiano cheese by gas chromatography/olfactometry,
J. Dairy Sci., 2002, 85, 6, 1362-1369, https://doi.org/10.3168/jds.S0022-0302(02)74202-1
. [all data]
Duque, Bonilla, et al., 2001
Duque, C.; Bonilla, A.; Bautista, E.; Zea, S.,
Exudation of low molecular wight compounds (thiobismethane, methyl isocyanide, amd methyl isothiocyanate) as a possible chemical defense mechanism in the marine sponge Ircinia felix,
Biochem. Systematics Ecol., 2001, 29, 5, 459-467, https://doi.org/10.1016/S0305-1978(00)00081-8
. [all data]
Miyazawa, Kurose, et al., 2001
Miyazawa, M.; Kurose, K.; Itoh, A.; Hiraoka, N.,
Comparison of the essential oils of Glehnia littoralis from Northern and Southern Japan,
J. Agric. Food Chem., 2001, 49, 11, 5433-5436, https://doi.org/10.1021/jf010219c
. [all data]
Girard and Durance, 2000
Girard, B.; Durance, T.,
Headspace volatiles of sockeye and pink salmon as affected by retort process,
Food Chem. Toxicol., 2000, 65, 1, 34-39. [all data]
Iwatsuki, Mizota, et al., 1999
Iwatsuki, K.; Mizota, Y.; Kubota, T.; Nishimura, O.; Masuda, H.; Sotoyama, K.; Tomita, M.,
Aroma extract dilution analysis. Evluation of aroma of pasteurized and UHT processed milk by aroma extract dilution analysis,
Nippon Shokuhin Kagaku Kogaku Kaishi, 1999, 46, 9, 587-597, https://doi.org/10.3136/nskkk.46.587
. [all data]
Horiuchi, Umano, et al., 1998
Horiuchi, M.; Umano, K.; Shibamoto, T.,
Analysis of volatile compounds formed from fish oil heated with cysteine and trimethylamine oxide,
J. Agric. Food Chem., 1998, 46, 12, 5232-5237, https://doi.org/10.1021/jf980482m
. [all data]
Shuichi, Masazumi, et al., 1996
Shuichi, H.; Masazumi, N.; Hiromu, K.; Kiyoshi, F.,
Comparison of volatile compounds berween the crude drugs, Onji-tsutsu and Onji-niki,
Nippon nogei kagaku kaishi, 1996, 70, 2, 151-160. [all data]
Chung, Eiserich, et al., 1993
Chung, T.Y.; Eiserich, J.P.; Shibamoto, T.,
Volatile compounds identified in headspace samples of peanut oil heated under temperatures ranging from 50 to 200 °C,
J. Agric. Food Chem., 1993, 41, 9, 1467-1470, https://doi.org/10.1021/jf00033a022
. [all data]
Kawakami and Kobayashi, 1991
Kawakami, M.; Kobayashi, A.,
Volatitle constituents of greem mate and roasted mate,
J. Agric. Food Chem., 1991, 39, 7, 1275-1279, https://doi.org/10.1021/jf00007a016
. [all data]
Kubota, Nakamoto, et al., 1991
Kubota, K.; Nakamoto, A.; Moriguchi, M.; Kobayashi, A.; Ishii, H.,
Formation of pyrrolidino[1,2-e]-4H-2,4-dimethyl-1,3,5-dithiazine in the volatiles of boiled short-necked clam, clam, and corbicula,
J. Agric. Food Chem., 1991, 39, 6, 1127-1130, https://doi.org/10.1021/jf00006a027
. [all data]
Anker, Jurs, et al., 1990
Anker, L.S.; Jurs, P.C.; Edwards, P.A.,
Quantitative structure-retention relationship studies of odor-active aliphatic compounds with oxygen-containing functional groups,
Anal. Chem., 1990, 62, 24, 2676-2684, https://doi.org/10.1021/ac00223a006
. [all data]
De Llano D.G., Ramos M., et al., 1990
De Llano D.G.; Ramos M.; Polo C.; Sanz J.; Martinez-Castro I.,
Evolution of the volatile components of an artisanal blue cheese during ripening,
J. Dairy Sci., 1990, 73, 7, 1676-1683, https://doi.org/10.3168/jds.S0022-0302(90)78842-X
. [all data]
Wyllie, Brophy, et al., 1990
Wyllie, S.G.; Brophy, J.J.; Sarafis, V.; Hobbs, M.,
Volatile Components of the Fruit of Pistacia Lentiscus,
J. Food. Sci., 1990, 55, 5, 1325-1326, https://doi.org/10.1111/j.1365-2621.1990.tb03926.x
. [all data]
Binder and Flath, 1989
Binder, R.G.; Flath, R.A.,
Volatile components of pineapple guava,
J. Agric. Food Chem., 1989, 37, 3, 734-736, https://doi.org/10.1021/jf00087a034
. [all data]
Hsieh, Williams, et al., 1989
Hsieh, T.C.Y.; Williams, S.S.; Vejaphan, W.; Meyers, S.P.,
Characterization of Volatile Components of Menhaden Fish (Brevoortia tyrannus) Oil,
J. Amer. Oil Chem. Soc., 1989, 66, 1, 114-117, https://doi.org/10.1007/BF02661797
. [all data]
Labropoulos, Palmer, et al., 1982
Labropoulos, A.E.; Palmer, J.K.; Tao, P.,
Flavor evaluation and characterization of yogurt as affected by ultra-high temperature and vat processes,
J. Dairy Sci., 1982, 65, 2, 191-196, https://doi.org/10.3168/jds.S0022-0302(82)82176-0
. [all data]
Notes
Go To: Top, Normal alkane RI, polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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