S2Cl2+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   G
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 48330 ± 400 gas Colton and Rabalais, 1974
Solouki and Bock, 1977

State:   F
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 35580 ± 400 gas Colton and Rabalais, 1974
Solouki and Bock, 1977

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 23700 T gas Colton and Rabalais, 1974
Solouki and Bock, 1977

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 23080 ± 400 gas Colton and Rabalais, 1974
Solouki and Bock, 1977

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 20500 ± 400 gas Colton and Rabalais, 1974
Solouki and Bock, 1977

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 14280 ± 400 gas Colton and Rabalais, 1974
Solouki and Bock, 1977

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 5160 T gas Colton and Rabalais, 1974
Solouki and Bock, 1977

Additional references: Jacox, 1994, page 224; Kaufel, Vahl, et al., 1981

Notes

TTentative assignment or approximate value
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Colton and Rabalais, 1974
Colton, R.J.; Rabalais, J.W., Photoelectron electronic absorption spectra of SCl2, S2Cl2, S2Br2 and (CH3)2S2, J. Electron Spectrosc. Relat. Phenom., 1974, 3, 345. [all data]

Solouki and Bock, 1977
Solouki, B.; Bock, H., Photoelectron spectra and molecular properties. 59. Ionization energies of disulfur dihalides and isomerization surfaces XSSX .dblarw. SSX2, Inorg. Chem., 1977, 16, 3, 665, https://doi.org/10.1021/ic50169a035 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Kaufel, Vahl, et al., 1981
Kaufel, R.; Vahl, G.; Minkwitz, R.; Baumgartel, H., Die photoionenspektren von SCl2, S2Cl2 und S2Br2, Z. Anorg. Allg. Chem., 1981, 481, 207. [all data]

Notes

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