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Methyl methacrylate

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-91.40kcal/molChydVilcu and Perisanu, 1980ALS
Deltafliquid-92.93 ± 0.96kcal/molCcbVilcu and Perisanu, 1980ALS
Quantity Value Units Method Reference Comment
Deltacliquid-651.19 ± 0.96kcal/molCcbVilcu and Perisanu, 1980Corresponding «DELTA»fliquid = -92.33 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid63.62cal/mol*KN/ALebedev and Rabinovich, 1971DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
45.672298.15Zhang, Benson, et al., 1986DH
51.46298.15Karabaev, Abduzhaminov, et al., 1985T = 225 to 350 K. Equation only. Cp (J/kg*K) = 114.1 + 6.8299 T. Cp data calculated from equation.; DH
51.46298.15Karabaev, Saidov, et al., 1985T = 90 to 350 K. Cp(c) = 280.01 + 4.96T J/kg*K (103 to 212 K); Cp(liq) = 114.12 + 6.83T J/kg*K (225.6 to 350 K). Cp data calculated from equation.; DH
45.98300.Lebedev and Rabinovich, 1971T = 60 to 300 K.; DH
50.323298.15Melia, 1962T = 60 to 300 K.; DH
45.050293.Erds, Jger, et al., 1952T = 20 to 50°C.; DH

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
35.90210.Sochava and Trapeznikova, 1958T = 60 to 210 K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Vilcu and Perisanu, 1980
Vilcu, R.; Perisanu, S., The ideal gas state enthalpies of formation of some monomers, Rev. Roum. Chim., 1980, 25, 619-624. [all data]

Lebedev and Rabinovich, 1971
Lebedev, B.V.; Rabinovich, I.B., Heat capacities and thermodynamic functions of methyl methacrylate and poly(methyl methacrylate), Tr. Khim. Khim. Tekhnol., 1971, 1, 8-11. [all data]

Zhang, Benson, et al., 1986
Zhang, D.; Benson, G.C.; Kumaran, M.K.; Lu, B.C.-Y., Excess thermodynamic properties for methyl methacrylate + methanol and + ethanol, J. Chem. Thermodynam., 1986, 18, 149-158. [all data]

Karabaev, Abduzhaminov, et al., 1985
Karabaev, M.; Abduzhaminov, T.P.; Saidov, A.A.; Igamberdyev, Kh.T., Thermophysical properties of liquid methacrylic acid and its simple esters, Izv. Akad. Nauk Uzb. SSR, Ser. Fiz.-Mat. Nauk, 1985, (4), 71-74. [all data]

Karabaev, Saidov, et al., 1985
Karabaev, M.; Saidov, A.A.; Abduzhaminov, T.P.; Kenisarin, M.M., Heat capacity and molecular kinetic processes of condensed phase acrylates and methacrylates, Izv. Akad. Nauk UzSSR, Ser. Fiz.-Math., 1985, (6), 51-54. [all data]

Melia, 1962
Melia, T.P., Part VIII-Methylmethacrylate and polymethylmethacrylate, Polymer, 1962, 3, 317-319. [all data]

Erds, Jger, et al., 1952
Erds, E.; Jger, L.; Pouchly, J., Specificka tepla methylesteru a butylesteru kyseliny methakrylove, Chem. Listy, 1952, 46, 770. [all data]

Sochava and Trapeznikova, 1958
Sochava, I.V.; Trapeznikova, O.N., Internal rotation and specific heat of some polymers at low temperatures, Vestn. Leningrad. Univ. 13, No.16, Ser. Fiz. Khim., 1958, No.3, 65-72. [all data]


Notes

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