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Kovats' RI, non-polar column, isothermal

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-1DB-1DB-1OV-1
Column length (m) 30.30.30.30.25.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.320.320.320.320.2
Phase thickness (mum) 5.5.5.5.0.5
Temperature (C) 120.120.140.140.100.
I 948.55948.81955.92956.48942.00
ReferenceHarangi, 2003Harangi, 2003Harangi, 2003Harangi, 2003Tarján, Bitter, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-1OV-1OV-1OV-1OV-1
Column length (m) 25.25.25.25.25.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.20.20.20.20.2
Phase thickness (mum) 0.50.50.50.50.5
Temperature (C) 110.120.130.140.150.
I 945.00949.00952.00956.00959.00
ReferenceTarján, Bitter, et al., 2002Tarján, Bitter, et al., 2002Tarján, Bitter, et al., 2002Tarján, Bitter, et al., 2002Tarján, Bitter, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-1OV-1DB-1SE-30OV-101
Column length (m) 25.25.28.40.25.
Carrier gas HeHeHe He
Substrate      
Column diameter (mm) 0.20.20.250.350.20
Phase thickness (mum) 0.50.50.250.35 
Temperature (C) 80.90.150.100.100.
I 935.00938.00930.940.9933.
ReferenceTarján, Bitter, et al., 2002Tarján, Bitter, et al., 2002Viswanathan, Maridass, et al., 2002Tudor, 1997Baaliouamer, Boudarene, et al., 1993
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101OV-101OV-101OV-101OV-101
Column length (m) 25.25.25.25.25.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.200.200.200.200.20
Phase thickness (mum)      
Temperature (C) 100.120.120.80.80.
I 941.934.941.926.934.
ReferenceBaaliouamer, Boudarene, et al., 1993Baaliouamer, Boudarene, et al., 1993Baaliouamer, Boudarene, et al., 1993Baaliouamer, Boudarene, et al., 1993Baaliouamer, Boudarene, et al., 1993
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryPackedPackedPackedPacked
Active phase PB-1OV-101OV-101OV-101OV-101
Column length (m) 42.2.2.2.2.
Carrier gas  ArArArAr
Substrate  W-AW-DMCSW-AW-DMCSW-AW-DMCSW-AW-DMCS
Column diameter (mm) 0.32    
Phase thickness (mum)      
Temperature (C) 130.130.140.150.160.
I 950.952.956.960.965.
ReferenceEngewald, Knobloch, et al., 1991Szabolcs, Benecke, et al., 1985Szabolcs, Benecke, et al., 1985Szabolcs, Benecke, et al., 1985Szabolcs, Benecke, et al., 1985
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101OV-101OV-101OV-101Apiezon L
Column length (m)     45.
Carrier gas      
Substrate      
Column diameter (mm)     0.25
Phase thickness (mum)      
Temperature (C) 130.140.150.160.100.
I 952.956.960.965.948.
ReferenceBenecke, Thieme, et al., 1982Benecke, Thieme, et al., 1982Benecke, Thieme, et al., 1982Benecke, Thieme, et al., 1982Morishita, Okano, et al., 1980
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryPacked
Active phase SE-30SE-30SE-30SF-96SE-30
Column length (m) 80.80.80.152.6.145
Carrier gas     N2
Substrate     Chromosorb W
Column diameter (mm) 0.50.50.50.8 
Phase thickness (mum) 0.80.80.8  
Temperature (C) 100.110.130.100.160.
I 940.7940.5950.5940.970.
ReferenceSaeed, Redant, et al., 1979Saeed, Redant, et al., 1979Saeed, Redant, et al., 1979Kepner, Ellison, et al., 1974Hedin, Thompson, et al., 1972
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryPackedCapillaryPacked
Active phase SF-96Apiezon LSqualaneSF-96Apiezon L
Column length (m)   15.152.6.1
Carrier gas   He N2
Substrate   Chromosorb P Gas Chrom P (60-80 mesh)
Column diameter (mm)   0.250.8 
Phase thickness (mum)      
Temperature (C) 100.100.86.100.130.
I 938.944.5928.942.962.
ReferenceAndersen and Syrdal, 1970Andersen and Syrdal, 1970Hively and Hinton, 1968Sakai, Maarse, et al., 1967Minyard, Tumlinson, et al., 1965
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Kovats' RI, non-polar column, isothermal, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Harangi, 2003
Harangi, J., Short communication. Retention index calculation without n-alkanes -- the virtual carbon number, J. Chromatogr. A, 2003, 993, 1-2, 187-195, https://doi.org/10.1016/S0021-9673(03)00320-0 . [all data]

Tarján, Bitter, et al., 2002
Tarján, G.; Bitter, I.; Strasser, B.; Szatmáry, M., Data for the gas-liquid chromatographic analysis of essential oils. Determination of the composition of the essential oil of marjoram, Chromatographia Sup., 2002, 56, 1, s155-s163, https://doi.org/10.1007/BF02494130 . [all data]

Viswanathan, Maridass, et al., 2002
Viswanathan, M.B.; Maridass, M.; Thangadurai, D.; Ramesh, N., Chemical constituents of the fruit essential oil of Diospyros malabarica (Desr.) Kostel (Ebenaceae), Acta Pharmaceutica, 2002, 52, 207-211. [all data]

Tudor, 1997
Tudor, E., Temperature dependence of the retention index for perfumery compounds on a SE-30 glass capillary column. I. Linear equations, J. Chromatogr. A, 1997, 779, 1-2, 287-297, https://doi.org/10.1016/S0021-9673(97)00453-6 . [all data]

Baaliouamer, Boudarene, et al., 1993
Baaliouamer, A.; Boudarene, L.; Meklati, B.Y., Use of local lagrange interpolation of calculation of retention indices in linear temperature-programmed gas chromatrography, Chromatographia, 1993, 35, 1/2, 67-72, https://doi.org/10.1007/BF02278559 . [all data]

Engewald, Knobloch, et al., 1991
Engewald, W.; Knobloch, T.; Haufe, G.; Muller, M.; Pohris, V., A Novel Method for Terpene Pattern Determination of Essential Oils by Selectivity Tuning in GC, Fresenius' J. Anal. Chem., 1991, 341, 10, 641-643, https://doi.org/10.1007/BF00322279 . [all data]

Szabolcs, Benecke, et al., 1985
Szabolcs, N.; Benecke, R.; Thieme, H., Természetes eredetu növényi anyagok gázkromatográfiás retenciós tulajdonságai. I. A lavandula- és lavandinolaj fo kimponenseinek retenciós indexei, Acta Pharm. Hung., 1985, 55, 49-58. [all data]

Benecke, Thieme, et al., 1982
Benecke, R.; Thieme, H.; Nyiredy, Sz., Retentionsverhalten der Hauptkomponenten der Lavendel und Lavandinöle an Verschiedenen stationären Phasen in Abhängigkeit von der Säulentemperatur, J. Chromatogr., 1982, 238, 1, 75-87, https://doi.org/10.1016/S0021-9673(00)82713-2 . [all data]

Morishita, Okano, et al., 1980
Morishita, F.; Okano, T.; Kojima, T., Retention indices of monocyclic monoterpene hydrocarbons, Bunseki Kagaku, 1980, 29, 1, 48-53, https://doi.org/10.2116/bunsekikagaku.29.48 . [all data]

Saeed, Redant, et al., 1979
Saeed, T.; Redant, G.; Sandra, P., Kovats Indices of Monoterpene Hydrocarbons on Glass Capillary Columns, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1979, 2, 2, 75-76, https://doi.org/10.1002/jhrc.1240020208 . [all data]

Kepner, Ellison, et al., 1974
Kepner, R.E.; Ellison, B.O.; Breckenridge, M.; Connolly, G.; Madden, S.C.; Muller, C.J., Volatile terpenes in California Bay foliage. Changes in composition during maturation, J. Agric. Food Chem., 1974, 22, 5, 781-784, https://doi.org/10.1021/jf60195a027 . [all data]

Hedin, Thompson, et al., 1972
Hedin, P.A.; Thompson, A.C.; Gueldner, R.C., Application of a Sequential Reduction Regimen to Fractionation of Essential Oils, Anal. Chem., 1972, 44, 7, 1254-1257, https://doi.org/10.1021/ac60315a030 . [all data]

Andersen and Syrdal, 1970
Andersen, N.H.; Syrdal, D.D., Terpenes and sesquiterpenes of chamaecyparis nootkatensis leaf oil, Phytochemistry, 1970, 9, 6, 1325-1340, https://doi.org/10.1016/S0031-9422(00)85326-1 . [all data]

Hively and Hinton, 1968
Hively, R.A.; Hinton, R.E., Variation of the retention index with temperature on squalane substrates, J. Gas Chromatogr., 1968, 6, 4, 203-217, https://doi.org/10.1093/chromsci/6.4.203 . [all data]

Sakai, Maarse, et al., 1967
Sakai, T.; Maarse, H.; Kepner, R.E.; Jennings, W.G.; Longhurst, W.M., Volatile components of Douglas fir needles, J. Agric. Food Chem., 1967, 15, 6, 1070-1072, https://doi.org/10.1021/jf60154a027 . [all data]

Minyard, Tumlinson, et al., 1965
Minyard, J.P.; Tumlinson, J.H.; Hedin, P.A.; Thompson, A.C., Constituents of the cotton bud. Terpene hydrocarbons, J. Agric. Food Chem., 1965, 13, 6, 599-602, https://doi.org/10.1021/jf60142a034 . [all data]


Notes

Go To: Top, Kovats' RI, non-polar column, isothermal, References