SiH2Cl2+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   G


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Txx = 53400 T gas Cradock and Whiteford, 1971
Frost, Herring, et al., 1971

State:   F


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Txx = 23400 ± 720 gas Frost, Herring, et al., 1971

State:   E


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Txx = 22180 ± 720 gas Frost, Herring, et al., 1971

State:   D


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Txx = 20170 ± 720 gas Cradock and Whiteford, 1971
Frost, Herring, et al., 1971

State:   C


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Txx = 8550 ± 480 gas Frost, Herring, et al., 1971

State:   B


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Txx = 6700 ± 480 gas Cradock and Whiteford, 1971
Frost, Herring, et al., 1971

State:   A


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Txx = 3150 ± 320 gas Cradock and Whiteford, 1971
Frost, Herring, et al., 1971

Additional references: Jacox, 1994, page 262

Notes

TTentative assignment or approximate value
xxEnergy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cradock and Whiteford, 1971
Cradock, S.; Whiteford, R.A., Photo-electron spectra of the mono and dihalo silanes and germanes, J. Chem. Soc. Faraday Trans., 1971, 67, 3425. [all data]

Frost, Herring, et al., 1971
Frost, D.C.; Herring, F.G.; Katrib, A.; McLean, R.A.N.; Drake, J.E.; Westwood, N.P.C., Photoelectron spectra and bonding in some halosilanes, Can. J. Chem., 1971, 49, 4033. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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