HSiCl3+
- Formula: Cl3HSi+
- Molecular weight: 135.452
- CAS Registry Number: 80003-39-0
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: F
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Txx = 50020 ± 320 | gas | Frost, Herring, et al., 1971 | |||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 1 | SiH stretch | 2000 | T | gas | PE | Frost, Herring, et al., 1971 |
State: E
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Txx = 24530 ± 320 | gas | Frost, Herring, et al., 1971 | |||||
State: D
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Txx = 22670 ± 320 | gas | Frost, Herring, et al., 1971 | |||||
State: C
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Txx = 9120 ± 320 | gas | Frost, Herring, et al., 1971 | |||||
State: A,B
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Txx = 3790 ± 320 | gas | Frost, Herring, et al., 1971 | |||||
Additional references: Jacox, 1994, page 276
Notes
T | Tentative assignment or approximate value |
xx | Energy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Frost, Herring, et al., 1971
Frost, D.C.; Herring, F.G.; Katrib, A.; McLean, R.A.N.; Drake, J.E.; Westwood, N.P.C.,
Photoelectron spectra and bonding in some halosilanes,
Can. J. Chem., 1971, 49, 4033. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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