Camphene

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil380. ± 100.KAVGN/AAverage of 11 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus322. ± 8.KAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δvap10.7kcal/molGCHoskovec, Grygarová, et al., 2005Based on data from 313. - 413. K.; AC
Quantity Value Units Method Reference Comment
Δsub11.20 ± 0.13kcal/molCKozina, Bychikhina, et al., 1977ALS
Δsub11.2kcal/molN/AKozina, Bychikhina, et al., 1977DRB

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
10.5335.AStephenson and Malanowski, 1987Based on data from 320. - 434. K. See also Stull, 1947.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
320.4 - 433.74.732951893.487-33.855Stull, 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hoskovec, Grygarová, et al., 2005
Hoskovec, Michal; Grygarová, Dana; Cvacka, Josef; Streinz, Ludvík; Zima, Jirí; Verevkin, Sergey P.; Koutek, Bohumír, Determining the vapour pressures of plant volatiles from gas chromatographic retention data, Journal of Chromatography A, 2005, 1083, 1-2, 161-172, https://doi.org/10.1016/j.chroma.2005.06.006 . [all data]

Kozina, Bychikhina, et al., 1977
Kozina, M.P.; Bychikhina, L.V.; Gal'chenko, G.L., The enthalpies of combustion and formation of 2,2-dimethyl-3-methylene bicyclo[2,2,1]heptane and 7-methylenebicyclo[2,2,1]heptane, Russ. J. Phys. Chem. (Engl. Transl.), 1977, 51, 1258-1259. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]


Notes

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