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Ethene, chlorotrifluoro-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-505.5 ± 4.7kJ/molCcrErastov and Kolesov, 1982see Erastov, Kolesov, et al., 1981 AND Papina, Erastov, et al., 1981
Deltafgas-564.8 ± 5.8kJ/molCmKolesov, Zenkov, et al., 1963Reanalyzed by Cox and Pilcher, 1970, Original value = -544.8 ± 5.4 kJ/mol
Deltafgas-510. ± 13.kJ/molCcbWartenberg and Schiefer, 1955Reanalyzed by Cox and Pilcher, 1970, Original value = -502. kJ/mol
Deltafgas-527. ± 8.kJ/molCmKirkbride and Davidson, 1954Von Wartenberg method

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-522.7 ± 4.7kJ/molCcrErastov and Kolesov, 1982see Erastov, Kolesov, et al., 1981 AND Papina, Erastov, et al., 1981; ALS
Quantity Value Units Method Reference Comment
Deltacliquid-816.0 ± 2.8kJ/molCcrErastov and Kolesov, 1982see Erastov, Kolesov, et al., 1981 AND Papina, Erastov, et al., 1981; ALS
Quantity Value Units Method Reference Comment
liquid220.66J/mol*KN/AOliver, Grisard, et al., 1951DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
122.42244.80Oliver, Grisard, et al., 1951T = 16 to 245 K.; DH

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

4sodium + Ethene, chlorotrifluoro- = 2carbon + sodium chloride + 3sodium fluoride

By formula: 4Na + C2ClF3 = 2C + ClNa + 3FNa

Quantity Value Units Method Reference Comment
Deltar-1576.1 ± 5.4kJ/molCmKolesov, Zenkov, et al., 1963gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -1543. ± 5.4 kJ/mol

2Hydrogen + Ethene, chlorotrifluoro- = 1,1,2-Trifluoroethane + Hydrogen chloride

By formula: 2H2 + C2ClF3 = C2H3F3 + HCl

Quantity Value Units Method Reference Comment
Deltar-267.7 ± 2.1kJ/molChydLacher, Kianpour, et al., 1956gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -271.6 kJ/mol; At 410 K

Hydrogen bromide + Ethene, chlorotrifluoro- = 1-Bromo-2-chloro-1,1,2-trifluoroethane

By formula: HBr + C2ClF3 = C2HBrClF3

Quantity Value Units Method Reference Comment
Deltar-109.09 ± 0.95kJ/molCmLacher, Lea, et al., 1950gas phase; Heat of hydrobromination at 367°K

Chlorine + Ethene, chlorotrifluoro- = Ethane, 1,1,2-trichloro-1,2,2-trifluoro-

By formula: Cl2 + C2ClF3 = C2Cl3F3

Quantity Value Units Method Reference Comment
Deltar-204.2 ± 2.0kJ/molCmLacher, McKinley, et al., 1949gas phase; Heat of Chlorination at 363 °K

Bromine + Ethene, chlorotrifluoro- = 1,2-Dibromo-1-chloro-1,2,2-trifluoroethane

By formula: Br2 + C2ClF3 = C2Br2ClF3

Quantity Value Units Method Reference Comment
Deltar-132.3kJ/molCmLacher, Casali, et al., 1956gas phase; Heat of bromination

1,2-Dibromo-1-chloro-1,2,2-trifluoroethane = Bromine + Ethene, chlorotrifluoro-

By formula: C2Br2ClF3 = Br2 + C2ClF3

Quantity Value Units Method Reference Comment
Deltar132.25kJ/molCmLacher, Casali, et al., 1956gas phase

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Erastov and Kolesov, 1982
Erastov, P.A.; Kolesov, V.P., Enthalpy of formation of trifluorochloroethene, J. Chem. Thermodyn., 1982, 14, 103-106. [all data]

Erastov, Kolesov, et al., 1981
Erastov, P.A.; Kolesov, V.P.; Dityateva, L.N.; Golovanova, Yu.G., The enthalpy of formation of 1,1,2-trifluoro-1,2,2-trichloroethane, J. Chem. Thermodyn., 1981, 13, 663-669. [all data]

Papina, Erastov, et al., 1981
Papina, T.S.; Erastov, P.A.; Kolesov, V.P., The enthalpies of formation of 1,1,1-trifluoro-2-chloro-2-bromoethane and 1,1,2-trifluoro-2-chloro-1-bromoethane, J. Chem. Thermodyn., 1981, 13, 683-689. [all data]

Kolesov, Zenkov, et al., 1963
Kolesov, V.P.; Zenkov, I.D.; Skuratov, S.M., Standard enthalpy of formation of chlorotrifluoroethylene, Russ. J. Phys. Chem. (Engl. Transl.), 1963, 37, 115-116. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Wartenberg and Schiefer, 1955
Wartenberg, H.V.; Schiefer, J., Bildungswarmen von fluor-chlor-kohlenstoff-verbindungen, Z. Anorg. Chem., 1955, 278, 326-332. [all data]

Kirkbride and Davidson, 1954
Kirkbride, F.W.; Davidson, F.G., Heats of formation of gaseous fluoro- and fluorochloro-carbons, Nature (London), 1954, 174, 79-80. [all data]

Oliver, Grisard, et al., 1951
Oliver, G.D.; Grisard, J.W.; Cunningham, C.W., Thermodynamic properties and P-V-T relations of chlorotrifluoroethylene, J. Am. Chem. Soc., 1951, 73, 5719-5722. [all data]

Lacher, Kianpour, et al., 1956
Lacher, J.R.; Kianpour, A.; Oetting, F.; Park, J.D., Reaction calorimetry. The hydrogenation of organic fluorides and chlorides, Trans. Faraday Soc., 1956, 52, 1500-1508. [all data]

Lacher, Lea, et al., 1950
Lacher, J.R.; Lea, K.R.; Walden, C.H.; Olson, G.G.; Park, J.D., Reaction heats of organic fluorine compounds. III. The vapor phase heats of hydrobromination of some simple fluoroolefins, J. Am. Chem. Soc., 1950, 72, 3231-3234. [all data]

Lacher, McKinley, et al., 1949
Lacher, J.R.; McKinley, J.J.; Walden, C.; Lea, K.; Park, J.D., Reaction heats of organic fluorine compounds. II. The vapor phase heats of chlorination of some simple fluoroolefins, J. Am. Chem. Soc., 1949, 71, 1334-1337. [all data]

Lacher, Casali, et al., 1956
Lacher, J.R.; Casali, L.; Park, J.D., Reaction heats of organic halogen compounds V. The vapor phase bromination of tetrafluoroethylene and trifluorochloroethylene, J. Phys. Chem., 1956, 60, 608-610. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References