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Ethene, 1,1-dichloro-2,2-difluoro-

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Methyl Alcohol + Ethene, 1,1-dichloro-2,2-difluoro- = Methoxyflurane

By formula: CH4O + C2Cl2F2 = C3H4Cl2F2O

Quantity Value Units Method Reference Comment
Deltar-38.0 ± 0.5kcal/molCmKennedy, Lacher, et al., 1969gas phase
Deltar-37.2kcal/molCmHine and Rogers, 1968gas phase

Chlorine + Ethene, 1,1-dichloro-2,2-difluoro- = Ethane, 1,1,1,2-tetrachloro-2,2-difluoro-

By formula: Cl2 + C2Cl2F2 = C2Cl4F2

Quantity Value Units Method Reference Comment
Deltar-41.08 ± 0.56kcal/molCmLacher, McKinley, et al., 1949gas phase; Heat of chlorination at 363 °K

3Hydrogen + Ethene, 1,1-dichloro-2,2-difluoro- = Ethane, 1,1-difluoro- + 2Hydrogen chloride

By formula: 3H2 + C2Cl2F2 = C2H4F2 + 2HCl

Quantity Value Units Method Reference Comment
Deltar-83.33kcal/molChydLacher, Kianpour, et al., 1956gas phase; At 410 K

Hydrogen + Ethene, 1,1-dichloro-2,2-difluoro- = Ethene, 2-chloro-1,1-difluoro- + Hydrogen chloride

By formula: H2 + C2Cl2F2 = C2HClF2 + HCl

Quantity Value Units Method Reference Comment
Deltar-21.56kcal/molChydLacher, Kianpour, et al., 1956gas phase; At 298 K

Isopropyl Alcohol + Ethene, 1,1-dichloro-2,2-difluoro- = C5H8Cl2F2O

By formula: C3H8O + C2Cl2F2 = C5H8Cl2F2O

Quantity Value Units Method Reference Comment
Deltar-43.7 ± 0.3kcal/molEqkKennedy, Lacher, et al., 1969gas phase

Ethanol + Ethene, 1,1-dichloro-2,2-difluoro- = C4H6Cl2F2O

By formula: C2H6O + C2Cl2F2 = C4H6Cl2F2O

Quantity Value Units Method Reference Comment
Deltar-39.3 ± 0.6kcal/molCmKennedy, Lacher, et al., 1969gas phase

1-Propanol + Ethene, 1,1-dichloro-2,2-difluoro- = C5H8Cl2F2O

By formula: C3H8O + C2Cl2F2 = C5H8Cl2F2O

Quantity Value Units Method Reference Comment
Deltar-39.1 ± 0.4kcal/molCmKennedy, Lacher, et al., 1969gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kennedy, Lacher, et al., 1969
Kennedy, M.B.; Lacher, J.R.; Park, J.D., Reaction heats of organic compounds. VI. Heats of addition of some alcohols to 1,1-dichloro-2,2-difluoroethylene, Trans. Faraday Soc., 1969, 65, 1435-1442. [all data]

Hine and Rogers, 1968
Hine, J.; Rogers, F.E., Stabilizing interactions between substituents attached to the same saturated carbon atom. Enthalpies of addition of methanol, pyrrolidine, and 1-butanethiol to 1,1-dichloro-2,2-difluoroethylene, J. Am. Chem. Soc., 1968, 90, 6701-6. [all data]

Lacher, McKinley, et al., 1949
Lacher, J.R.; McKinley, J.J.; Walden, C.; Lea, K.; Park, J.D., Reaction heats of organic fluorine compounds. II. The vapor phase heats of chlorination of some simple fluoroolefins, J. Am. Chem. Soc., 1949, 71, 1334-1337. [all data]

Lacher, Kianpour, et al., 1956
Lacher, J.R.; Kianpour, A.; Oetting, F.; Park, J.D., Reaction calorimetry. The hydrogenation of organic fluorides and chlorides, Trans. Faraday Soc., 1956, 52, 1500-1508. [all data]


Notes

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