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Acetic acid, methyl ester

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Kovats' RI, non-polar column, isothermal

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-5HP-1HP-1HP-1
Column length (m) 30.60.30.30.30.
Carrier gas N2N2   
Substrate      
Column diameter (mm) 0.2560.3210.250.250.25
Phase thickness (mum) 0.250.250.250.250.25
Temperature (C) 80.80.0.10.20.
I 501.15522.17520.6521.526.2
ReferenceMijin and Antonovic, 2006Mijin and Antonovic, 2006Wang, Liu, et al., 2005Wang, Liu, et al., 2005Wang, Liu, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-1HP-1HP-1HP-1SE-54
Column length (m) 30.30.30.30.15.
Carrier gas     Ar
Substrate      
Column diameter (mm) 0.250.250.250.250.28
Phase thickness (mum) 0.250.250.250.252.5
Temperature (C) 30.40.50.60.110.
I 521.3515.7513.8511.5529.7
ReferenceWang, Liu, et al., 2005Wang, Liu, et al., 2005Wang, Liu, et al., 2005Wang, Liu, et al., 2005Grigor'eva, Vasil'ev, et al., 1989
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SE-54SE-54SE-54SE-54SE-54
Column length (m) 15.15.15.15.15.
Carrier gas ArArArArAr
Substrate      
Column diameter (mm) 0.280.280.280.280.28
Phase thickness (mum) 2.52.52.52.52.5
Temperature (C) 130.150.110.130.150.
I 525.7523.7530.525.7522.4
ReferenceGrigor'eva, Vasil'ev, et al., 1989Grigor'eva, Vasil'ev, et al., 1989Grigor'eva, Vasil'ev, et al., 1989Grigor'eva, Vasil'ev, et al., 1989Grigor'eva, Vasil'ev, et al., 1989
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SE-30SE-30SE-30SE-30SE-30
Column length (m)   25.25.25.
Carrier gas   N2N2N2
Substrate      
Column diameter (mm)   0.330.330.33
Phase thickness (mum)      
Temperature (C) 100.80.100.60.80.
I 505.505.505.509.505.
ReferenceTarjan, Nyiredy, et al., 1989Tarjan, Nyiredy, et al., 1989Haken and Korhonen, 1986Haken and Korhonen, 1986Haken and Korhonen, 1986
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryPackedPacked
Active phase Apiezon L + KFSE-30OV-101SE-30SE-30
Column length (m) 30.25.15.3.73.7
Carrier gas   N2  
Substrate     Celaton (62-72 mesh)
Column diameter (mm) 0.250.220.22  
Phase thickness (mum) 0.06    
Temperature (C) 70.100.80.150.150.
I 529.560.525.9509.509.
ReferenceSvetlova, Samusenko, et al., 1986Haken, Madden, et al., 1983Komárek, Hornová, et al., 1982Haken, Ho, et al., 1975Ashes and Haken, 1974
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPacked
Active phase SE-30SE-30SE-30
Column length (m) 2.3.76.
Carrier gas   He
Substrate Chromosorb WCelite 560Chromosorb P
Column diameter (mm)    
Phase thickness (mum)    
Temperature (C) 100.150.80.
I 505.506.510.
ReferenceZarazir, Chovin, et al., 1970Germaine and Haken, 1969Viani, Müggler-Chavan, et al., 1965
Comment MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Kovats' RI, non-polar column, isothermal, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mijin and Antonovic, 2006
Mijin, D.; Antonovic, D.G., The temperature dependence of the retention index for n-alkyl esters of acetic, propionic, cyclohexanecarboxylic, benzoic and phenylacetic acid on DB-1 and DB-5 capillary columns, J. Serb. Chem. Soc., 2006, 71, 6, 629-637, https://doi.org/10.2298/JSC0606629M . [all data]

Wang, Liu, et al., 2005
Wang, Y.; Liu, J.; Li, N.; Shi, G.; Jiang, G.; Ma, W., Preliminary study of the retention behavior for different compounds using cryogenic chromatography at different initial temperatures, Microchem. J., 2005, 81, 2, 184-190, https://doi.org/10.1016/j.microc.2005.02.003 . [all data]

Grigor'eva, Vasil'ev, et al., 1989
Grigor'eva, D.N.; Vasil'ev, A.V.; Golovnya, R.V., Variation in retention indices and equivalent chain lengths of homologous series of n-alkyl acetates, n-alkyl methyl ketones, and methyl esters of aliphatic carboxylic acids as a function of homolog number and analysis temperature, Zh. Anal. Khim., 1989, 44, 1, 68-73. [all data]

Tarjan, Nyiredy, et al., 1989
Tarjan, G.; Nyiredy, Sz.; Gyor, M.; Lombosi, E.R.; Lombosi, T.S.; Budahegyi, M.V.; Meszaros, S.Y.; Takacs, J.M., Review. Thirtieth Anniversary of the Retention Index According to Kovats in Gas-Liquid Chromatography, J. Chromatogr., 1989, 472, 1-92, https://doi.org/10.1016/S0021-9673(00)94099-8 . [all data]

Haken and Korhonen, 1986
Haken, J.K.; Korhonen, I.O.O., Gas chromatography of homologous esters. XXXII. Capillary chromatography of C1-C18 monochlorinated n-alkyl acetates, J. Chromatogr., 1986, 356, 79-94, https://doi.org/10.1016/S0021-9673(00)91468-7 . [all data]

Svetlova, Samusenko, et al., 1986
Svetlova, N.I.; Samusenko, A.L.; Golovnya, R.V., Advantage of the universal equation over the linear equation for the calculation of retention parameters of homologous series in capillary chromatography, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1986, 9, 12, 737-740, https://doi.org/10.1002/jhrc.1240091205 . [all data]

Haken, Madden, et al., 1983
Haken, J.K.; Madden, B.G.; Korhonen, I.O.O., Gas chromatography of homologous esters. XX. Capillary column studies of alkyl acetates, chloroacetates, dichloroacetates and trichloroacetates, J. Chromatogr., 1983, 256, 221-229, https://doi.org/10.1016/S0021-9673(01)88235-2 . [all data]

Komárek, Hornová, et al., 1982
Komárek, K.; Hornová, L.; Churácek, J., Glass capillary gas chromatography of homologous series of esters. Separation of homologous series of esters of halogenated carboxylic acids on a glass capillary column with the non-polar stationary silicone phase OV-101, J. Chromatogr., 1982, 244, 1, 142-147, https://doi.org/10.1016/S0021-9673(00)80131-4 . [all data]

Haken, Ho, et al., 1975
Haken, J.K.; Ho, D.K.M.; Vaughan, C.E., Gas chromatography of homologous esters. VII. The retention behaviour of pyruvate esters and related carbonyl and carboxyl compounds, J. Chromatogr., 1975, 106, 2, 317-325, https://doi.org/10.1016/S0021-9673(00)93839-1 . [all data]

Ashes and Haken, 1974
Ashes, J.R.; Haken, J.K., Gas chromatography of homologous esters. VI. Structure-retention increments of aliphatic esters, J. Chromatogr., 1974, 101, 1, 103-123, https://doi.org/10.1016/S0021-9673(01)94737-5 . [all data]

Zarazir, Chovin, et al., 1970
Zarazir, D.; Chovin, P.; Guiochon, G., Identification of hydroxylic compounds and their derivatives by gas chromatography, Chromatographia, 1970, 3, 4, 180-195, https://doi.org/10.1007/BF02269018 . [all data]

Germaine and Haken, 1969
Germaine, R.W.; Haken, J.K., Gas chromatography of homologous esters. Part 1. Simple aliphatic esters, J. Chromatogr., 1969, 43, 33-42, https://doi.org/10.1016/S0021-9673(00)99162-3 . [all data]

Viani, Müggler-Chavan, et al., 1965
Viani, R.; Müggler-Chavan, F.; Reymond, D.; Egli, R.H., 196. Sur la composition de l'arôme de café, Helv. Chim. Acta, 1965, 48, 195-196, 1809-1815, https://doi.org/10.1002/hlca.19650480743 . [all data]


Notes

Go To: Top, Kovats' RI, non-polar column, isothermal, References