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Trichloroethylene

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
BS - Robert L. Brown and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil360.2 ± 0.3KAVGN/AAverage of 13 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus188.5KN/AGolovanova and Kolesov, 1984Uncertainty assigned by TRC = 0.2 K; TRC
Tfus188.35KN/ATimmermans and Hennaut-Roland, 1955Uncertainty assigned by TRC = 0.3 K; TRC
Quantity Value Units Method Reference Comment
Tc571.KN/AMajer and Svoboda, 1985 
Quantity Value Units Method Reference Comment
Deltavap8.274kcal/molN/AMajer and Svoboda, 1985 
Deltavap8.26 ± 0.02kcal/molReviewManion, 2002employed 1980MMS calorimetry data plus a correction for non-ideality; DRB
Deltavap8.119 ± 0.031kcal/molEPapina and Kolesov, 1985ALS
Deltavap8.25 ± 0.02kcal/molCMajer, Sváb, et al., 1980AC
Deltavap8.30 ± 0.10kcal/molVMathews, 1926Reanalyzed by Pedley, Naylor, et al., 1986, Original value = 7.52 ± 0.03 kcal/mol; ALS

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
7.50360.4N/AMajer and Svoboda, 1985 
8.17313.N/AAucejo, Gonzalez-Alfaro, et al., 1995Based on data from 297. - 360. K.; AC
8.27295.N/AStephenson and Malanowski, 1987Based on data from 280. - 428. K. See also Dykyj, 1970.; AC
7.680360.19VMcDonald, 1944ALS
8.65305.N/AMcDonald, 1944Based on data from 290. - 359. K.; AC
8.51313.N/AHerz and Rathmann, 1912Based on data from 298. - 360. K. See also Boublik, Fried, et al., 1984.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
290.9 - 359.623.54775974.538-85.811McDonald, 1944Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Reference Comment
2.020188.5Golovanova and Kolesov, 1984, 2DH
2.02188.5Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (cal/mol*K) Temperature (K) Reference Comment
10.7188.5Golovanova and Kolesov, 1984, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Golovanova and Kolesov, 1984
Golovanova, Y.G.; Kolesov, V.P., Enthalpies of melting, melting temperatures, and cryoscopic constants of some haloorganic compounds, Vestn. Mosk. Univ., Ser. 2: Khim., 1984, 25, 244. [all data]

Timmermans and Hennaut-Roland, 1955
Timmermans, J.; Hennaut-Roland, M., Work of the International Bureau of Physical-Chemical Standards. IX. The Physical Constants of Twenty Organic Compounds, J. Chim. Phys. Phys.-Chim. Biol., 1955, 52, 223. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Manion, 2002
Manion, J.A., Evaluated Enthalpies of Formation of the Stable Closed Shell C1 and C2 Chlorinated Hydrocarbons, J. Phys. Chem. Ref. Data, 2002, 31, 1, 123-172, https://doi.org/10.1063/1.1420703 . [all data]

Papina and Kolesov, 1985
Papina, T.S.; Kolesov, V.P., Standard enthalpy of formation of trichloroethylene, Russ. J. Phys. Chem. (Engl. Transl.), 1985, 59, 1289-1291. [all data]

Majer, Sváb, et al., 1980
Majer, V.; Sváb, L.; Svoboda, V., Enthalpies of vaporization and cohesive energies for a group of chlorinated hydrocarbons, The Journal of Chemical Thermodynamics, 1980, 12, 9, 843-847, https://doi.org/10.1016/0021-9614(80)90028-2 . [all data]

Mathews, 1926
Mathews, J.H., The accurate measurement of heats of vaporization of liquids, J. Am. Chem. Soc., 1926, 48, 562-576. [all data]

Pedley, Naylor, et al., 1986
Pedley, J.B.; Naylor, R.D.; Kirby, S.P., Thermochemical Data of Organic Compounds, Chapman and Hall, New York, 1986, 1-792. [all data]

Aucejo, Gonzalez-Alfaro, et al., 1995
Aucejo, Antonio; Gonzalez-Alfaro, Vicenta; Monton, Juan B.; Vazquez, M. Isabel, Isobaric Vapor-Liquid Equilibria of Trichloroethylene with 1-Propanol and 2-Propanol at 20 and 100 kPa, J. Chem. Eng. Data, 1995, 40, 1, 332-335, https://doi.org/10.1021/je00017a073 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Dykyj, 1970
Dykyj, J., Petrochemica, 1970, 10, 2, 51. [all data]

McDonald, 1944
McDonald, H.J., The vapor pressure and heat of vaporization of trichloroethylene, J. Phys. Chem., 1944, 48, 47-50. [all data]

Herz and Rathmann, 1912
Herz, W.; Rathmann, W., Chem. Ztg., 1912, 36, 1417. [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

Golovanova and Kolesov, 1984, 2
Golovanova, Yu.G.; Kolesov, V.P., Enthalpies of melting, melting temperatures, and cryoscopic constants of some haloorganic compounds, Vestn. Mosk Univ., Ser. 2: Khim., 1984, 25(3), 244-248. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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