Butane, 2-chloro-
- Formula: C4H9Cl
- Molecular weight: 92.567
- IUPAC Standard InChI: InChI=1S/C4H9Cl/c1-3-4(2)5/h4H,3H2,1-2H3
- IUPAC Standard InChIKey: BSPCSKHALVHRSR-UHFFFAOYSA-N
- CAS Registry Number: 78-86-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Species with the same structure:
- Stereoisomers:
- Other names: sec-Butyl Chloride; 1-Methylpropyl chloride; 2-Chlorobutane; sec-C4H9Cl; UN 1127
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -166.66 ± 0.99 | kJ/mol | Ccr | He, An, et al., 1992 |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -198.43 ± 0.99 | kJ/mol | Ccr | He, An, et al., 1992 | ALS |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°liquid | -2685.47 ± 0.95 | kJ/mol | Ccr | He, An, et al., 1992 | ALS |
Constant pressure heat capacity of liquid
| Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 160.9 | 298.15 | Shehatta, 1993 | DH |
| 174.0 | 298.15 | He, An, et al., 1992 | DH |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
=
+
By formula: C4H9Cl = C4H8 + HCl
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 67.15 | kJ/mol | Eqk | Levanova and Andreevskii, 1964 | gas phase; At 420 K |
=
+
By formula: C4H9Cl = C4H8 + HCl
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 75.31 | kJ/mol | Eqk | Levanova and Andreevskii, 1964 | gas phase; At 420 K |
=
+
By formula: C4H9Cl = C4H8 + HCl
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 63.81 | kJ/mol | Eqk | Levanova and Andreevskii, 1964 | gas phase; At 420 K |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
He, An, et al., 1992
He, J.; An, X.; Hu, R.,
Measurements of enthalpies of formation of 2-chlorobutane and 1,2-dichlorobutane in gaseous state,
Acta Chim. Sin., 1992, 50, 961-966. [all data]
Shehatta, 1993
Shehatta, I.,
Heat capacity at constant pressure of some halogen compounds,
Thermochim. Acta, 1993, 213, 1-10. [all data]
Levanova and Andreevskii, 1964
Levanova, S.V.; Andreevskii, D.N.,
The equilibrium of 2-chlorobutane dehydrochlorination,
Neftekhimiya, 1964, 4, 329-336. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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