1-Propanol, 2-methyl-

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Normal alkane RI, polar column, custom temperature program

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxCarbowax 20MDB-WaxDB-WaxDB-Wax
Column length (m) 60. 30.30.30.
Carrier gas Helium HeliumHeliumHydrogen
Substrate      
Column diameter (mm) 0.20 0.250.250.25
Phase thickness (μm) 0.25 0.250.250.25
Program 40 0C (3 min) 2 0C/min -> 150 0C 4 0C/min -> 220 0C (20 min) 5 0C/min -> 230 0Cnot specifiednot specifiednot specified35 0C (9 min) 5 0C/min -> 80 0C 1 0C/min -> 100 0C 16 0C/min -> 210 0C (20 min)
I 1090.1092.1090.1098.1096.
ReferenceGyawali and Kim, 2012Lee, Chong, et al., 2012Welke, Manfroi, et al., 2012Welke, Manfroi, et al., 2012Sampaio, Garruti, et al., 2011
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-InnowaxDB-WaxDB-WaxDB-WaxDB-Wax
Column length (m) 60.60.30.30.60.
Carrier gas HeliumHeliumHydrogen Helium
Substrate      
Column diameter (mm) 0.250.320.320.320.25
Phase thickness (μm) 0.251.00.500.500.25
Program 40 0C (2 min) 3 0C/min -> 150 0C 5 0C/min -> 220 0C (5 min)40 0C (2 min) 4 0C/min -> 190 0C (11 min) 8 0C/min -> 220 0C (8 min)40 0C (5 min) 4 0C/min -> 100 0C 6 0C/min -> 220 0C (20 min)40 0C (5 min) 4 0C/min -> 100 0C 6 0C/min -> 220 0C (40 min)40 0C (3 min) 2 0C/min -> 150 0C 4 0C/min -> 220 0C (20 min)
I 1099.1119.1099.1099.1093.
ReferenceXiao, Dai, et al., 2011Kadar, Juan-Borras, et al., 2010San-Juan, Petka, et al., 2010Ferreira, Juan, et al., 2009Gyawali and Kim, 2009
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase FFAPDB-WaxSupelcowax-10DB-WaxDB-Wax
Column length (m) 50.20.50.30.30.
Carrier gas HeliumHeliumHeliumHeliumHelium
Substrate      
Column diameter (mm) 0.200.180.250.250.32
Phase thickness (μm) 0.330.180.250.250.25
Program 70 0C (1 min) 3 0C/min -> 142 0C 5 0C/min -> 225 0C (10 min)35 0C (1 min) 2/9 0C/min -> 100 0C 8 0C/min -> 200 0C (5 min)45 0C (15 min) 3 0C/min -> 75 0C 5 0C/min -> 180 0C (10 min)not specified40 0C (3 min) 4 0C/min -> 160 0C 7 0C/min -> 220 0C (8 min)
I 1054.1087.1113.1089.1108.
ReferenceOrtiz, Echeverra, et al., 2009Rowan, Hunt, et al., 2009Soria, Martinez-Castro, et al., 2009Zhao, Xu, et al., 2009Li, Tao, et al., 2008
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax 10Supelcowax 10DB-WaxDB-WaxPEG 20M
Column length (m) 50.50.30.30.30.
Carrier gas HeliumHeliumHeliumHeliumHelium
Substrate      
Column diameter (mm) 0.250.250.320.320.25
Phase thickness (μm) 0.250.250.250.250.25
Program 45 0C (15 min) 3 0C/min -> 75 0C 5 0C/min -> 180 0C (10 min)45 0C (15 min) 3 0C/min -> 75 0C 5 0C/min -> 180 0C (10 min)50 0C 20 0C/min -> 80 0C 3 0C/min -> 230 0C40 0C (4 min) 3 0C/min -> 50 0C 5 0C/min -> 120 0C 7 0C/min -> 175 0C 10 0C/min -> 230 0C (8 min)40 0C (3 min) 5 0C/min -> 60 0C 6 0C/min -> 130 0C 10 0C/min -> 230 0C
I 1113.1113.1106.1108.1129.
ReferenceSoria, Martinez-Castro, et al., 2008Soria, Martinez-Castro, et al., 2008Tao, Wenlai, et al., 2008Yongsheng, Hua, et al., 2008Zhang, Zhang, et al., 2008
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax-10Supelcowax-10Supelcowax-10FFAPDB-Wax
Column length (m) 30.30.30.50.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.20.32
Phase thickness (μm) 0.250.250.250.330.25
Program 35C(8min) => 6C/min => 60C => 4C/min => 160C => 20C/min => 200C(1min)35C(8min) => 6C/min => 60C => 4C/min => 160C => 20C/min => 200C(1min)40C(10min) => 2C/min => 200C(1min) => 2C/min => 250C (10min)70C(1min) => 3C/min => 142C => 5C/min => 225C (10min)40C(3min) => 4C/min => 160C => 7C/min => 230C (8min)
I 1097.1107.1108.1091.1108.
ReferenceBerard, Bianchi, et al., 2007Berard, Bianchi, et al., 2007Bosch-Fuste, Riu-Aumatell, et al., 2007Lara, Echeverría, et al., 2007Li, Tao, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase FFAPDB-WaxDB-WaxHP-InnowaxPEG-20M
Column length (m) 50.30.30.30.30.
Carrier gas HeHydrogenHeHe 
Substrate      
Column diameter (mm) 0.20.320.250.250.25
Phase thickness (μm) 0.330.500.250.50.25
Program 70C(1min) => 3C/min => 142C => 5C/min => 225C(10min)60 0C (3 min) 2 0C/min -> 220 0C 3 0C/min -> 245 0C (20 min)50 0C (2 min) 6 0C/min -> 150 0C 8 0C/min -> 230 0C (15 min)30C(2min) => 4C/min => 130C => 8C/min => 250C(5min)40C(3min) => 5C/min => 60C => 6C/min => 130C => 10C/min => 230C (10min)
I 1091.1086.1091.1072.1129.
ReferenceLopez, Villatoro, et al., 2007Selli, 2007Tian, Zhang, et al., 2007Weldegergis B.T., Tredoux A.G.J., et al., 2007Zhang C., Zhang H., et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxFFAPInnowaxCarbowax 20MHP-FFAP
Column length (m) 60.50.60. 50.
Carrier gas HeHeHe He
Substrate      
Column diameter (mm) 0.250.20.25 0.2
Phase thickness (μm) 0.250.330.25 0.33
Program 35C(5min) => 2C/min => 50C => 5C/min => 200C (5min)70C(1min) => 3C/min => 142C => 5C/min => 225C(10min)50C(10min) => 4C/min => 220C(10min) => 1C/min => 240Cnot specified70C(1min) => 3C/min => 142C => 5C/min => 225C (10min)
I 1093.1091.1096.1054.1091.
ReferenceMattheis, Fan, et al., 2005Echeverría, Correa, et al., 2004Selli, Kürkçüoglu, et al., 2004Vinogradov, 2004Echeverria, Fuentes, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxFFAPFFAPFFAPCP-Wax 52CB
Column length (m) 30.30.30.30.30.
Carrier gas HeHeliumHeliumHeliumHe
Substrate      
Column diameter (mm) 0.320.320.320.320.25
Phase thickness (μm) 0.50.250.250.250.25
Program 60C(2min) => 2C/min => 220C => 3C/min => 245C(20min)50 0C (2 min) 6 0C/min -> 180 0C 10 0C/min -> 180 0C (10 min)50 0C (2 min) 6 0C/min -> 180 0C 10 0C/min -> 180 0C (10 min)50 0C (2 min) 6 oC/min -> 180 0C 10 0C/min -> 240 0C (10 min)50C(5min) => 7C/min => 180C => 10C/min => 240C(10min)
I 1085.1084.1085.1084.1089.
ReferenceSelli, Cabaroglu, et al., 2003Bel Rhild, Fleury, et al., 2002Bel Rhild, Fleury, et al., 2002Bel Rhild, Fleury, et al., 2002, 2Escalona, Birkmyre, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase TRWAXCP-Wax 52CBDB-WaxDB-WaxDB-Wax
Column length (m) 60.30.30.30.30.
Carrier gas HeHe  He
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Program not specified50C(5min) => 7C/min => 180C => 10C/min => 240C(10min)50C(4min) => 4C/min => 130C => 1C/min => 190C => 4C/min => 220C(20min)50C(4min) => 4C/min => 130C => 1C/min => 190C => 4C/min => 220C(20min)25 0C (0.5 min) 50 K/min -> 50 0C 3.5 K/min -> 150 0C 7.5 K/min -> 240 0C
I 1108.1091.1083.1091.1098.
ReferenceTorrens, 2002Escalona, Birkmyre, et al., 2001Mayorga, Knapp, et al., 2001Mayorga, Knapp, et al., 2001Miranda, Nogueira, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Carbowax 20MFFAPCross-linked FFAPFFAPPEG
Column length (m) 50.50.50.50.40.
Carrier gas N2N2N2N2Hydrogen
Substrate      
Column diameter (mm) 0.20.20.20.20.182
Phase thickness (μm) 0.20.330.330.330.30
Program 60C => 2C/min => 150C => 4C/min => 220C70C(1min) => 3C/min => 142C(2min) => 25C/min => 230C(5min)70C(1min) => 3C/min => 142C (2min) => 25C/min => 230C(5min)70C (1min) => 3C/min => 142C (2min) => 25C/min => 230C (5min)35 0C (5 min) 5 0C/min -> 100 0C 3 0C/min -> 200 0C (1 min) 20 0C/min -> 240 0C (2 min)
I 1094.1095.1095.1095.1114.
ReferenceTeai, Claude-Lafontaine, et al., 2001Lopez, Lavilla, et al., 2000Lavilla, Puy, et al., 1999López, Lavilla, et al., 1998Vas, Gal, et al., 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-FFAPDB-FFAPSupelcowax-10Polyethylene GlycolDB-Wax
Column length (m) 30.30.30.  
Carrier gas   He  
Substrate      
Column diameter (mm) 0.320.320.32  
Phase thickness (μm) 0.250.250.25  
Program 35C (1min) => 40C/min => 60C (1min) => 6C/min => 250C (10min)35C (1min) => 40C/min => 60C (1min) => 6C/min => 250C (10min)50C(2min) => 7C/min => 140C => 17.5C/min => 230Cnot specifiednot specified
I 1110.1110.1054.1090.1092.
ReferenceGuth, 1997Guth, 1997Chang, Seitz, et al., 1995Zenkevich, Korolenko, et al., 1995Peng, Yang, et al., 1991
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillary
Active phase DB-WaxCarbowax 400, Carbowax 20M, Carbowax 1540, Carbowax 4000, Superox 06, PEG 20M, etc.Carbowax 400, Carbowax 20M, Carbowax 1540, Carbowax 4000, Superox 06, PEG 20M, etc.Carbowax 20M
Column length (m) 60.50.50. 
Carrier gas  HydrogenHydrogen 
Substrate     
Column diameter (mm) 0.320.320.32 
Phase thickness (μm)     
Program not specifiednot specifiednot specifiednot specified
I 1084.1089.1122.1076.
ReferenceBinder, Flath, et al., 1989Waggott and Davies, 1984Waggott and Davies, 1984Ramsey and Flanagan, 1982
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Normal alkane RI, polar column, custom temperature program, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gyawali and Kim, 2012
Gyawali, R.; Kim, K.-S., Bioactive volatile compounds of three medicinal plants from Nepal, Kathmandu Univ. J. Sci., Engineering and Technol., 2012, 8, 1, 51-62. [all data]

Lee, Chong, et al., 2012
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Welke, Manfroi, et al., 2012
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Sampaio, Garruti, et al., 2011
Sampaio, K.S.; Garruti, D.S.; Franco, M.R.B.; Janzantti, N.S.; Da Silva, M.A.AP., Aroma volatiles recovered in the water phase of cashew apple (Anacardium occidentale L.) juice during concentration, J. Sci. Food Agric., 2011, 91, 10, 1801-1809, https://doi.org/10.1002/jsfa.4385 . [all data]

Xiao, Dai, et al., 2011
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Ortiz, A.; Echeverra, G.; Graell, J.; Lara, I., Calcium dips enhance volatile emission of cold-stored Fuji Kiki-8 apples, J. Agric. Food Chem., 2009, 57, 11, 4931-4938, https://doi.org/10.1021/jf9003576 . [all data]

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Soria, Martinez-Castro, et al., 2008
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Selli, Cabaroglu, et al., 2003
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Bel Rhild, Fleury, et al., 2002
Bel Rhild, R.; Fleury, Y.; Devaud, S.; Fay, L.B.; Blank, I.; Juillerat, M.A., Biogeneration of roasted noted based on 2-acetyl-2-thiazoline and the precursor 2-(1-hydroxyethyl)-4,5-dihydrothiazole, 2002, retrieved from http://www.imrablank.ch/ACS2002826179.pdf. [all data]

Bel Rhild, Fleury, et al., 2002, 2
Bel Rhild, R.; Fleury, Y.; Blank, I.; Fay, L.B.; Welti, D.H.; Vera F.A.; Juillerat, M.A., Generation of roasted notes based on 2-acetyl-2-thiazolidine and its precursor, 2-(1-hydroxyethyl)-4,5-dihydrothiazoline, by combined bio and thermal approaches, J. Agr. Food Chem., 2002, 50, 8, 2350-2355, https://doi.org/10.1021/jf011170d . [all data]

Escalona, Birkmyre, et al., 2002
Escalona, H.; Birkmyre, L.; Piggott, J.R.; Paterson, A., Effect of maturation in small oak casks on the volatility of red wine aroma compounds, Anal. Chim. Acta., 2002, 458, 1, 45-54, https://doi.org/10.1016/S0003-2670(01)01538-0 . [all data]

Torrens, 2002
Torrens, J., El análisis del aroma aplicado al control de calidad del cava [CS2002 Análisis sensorial (vino)], 2002, retrieved from http://www.percepnet.com/documenta/CS0203.pdf. [all data]

Escalona, Birkmyre, et al., 2001
Escalona, H.; Birkmyre, L.; Piggott, J.R.; Paterson, A., Relationship between sensory perception volatile and phenolic components in commercial Spanish red wines from different regions, J. Inst. Brew., 2001, 107, 3, 157-166, https://doi.org/10.1002/j.2050-0416.2001.tb00087.x . [all data]

Mayorga, Knapp, et al., 2001
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Notes

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