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1-Propanol, 2-methyl-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-334.6 ± 0.9kJ/molEqkConnett, 1975Heat of dehydrogenation; ALS
Deltafliquid-333.6 ± 0.63kJ/molCcbChao and Rossini, 1965see Rossini, 1934; ALS
Deltafliquid-334.7 ± 0.84kJ/molCcbSkinner and Snelson, 1960ALS
Quantity Value Units Method Reference Comment
Deltacliquid-2669.6 ± 0.59kJ/molCcbChao and Rossini, 1965see Rossini, 1934; Corresponding «DELTA»fliquid = -333.5 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-2668.5 ± 0.84kJ/molCcbSkinner and Snelson, 1960Corresponding «DELTA»fliquid = -334.7 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-2665.79kJ/molCcbRichards and Davis, 1920At 291 K; Corresponding «DELTA»fliquid = -337.40 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid214.5J/mol*KN/ACounsell, Lees, et al., 1968DH
Quantity Value Units Method Reference Comment
solid,1 bar140.7J/mol*KN/ACounsell, Lees, et al., 1968glass phase; DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
181.05298.15Okano, Ogawa, et al., 1988DH
182.01298.15Piekarski and Somsen, 1988DH
185.6303.15Rybalkin, Emel'yanov, et al., 1978T = 293.15 to 353.15 K. Cp given as 2504 J/kg*K.; DH
185.4301.2Paz Andrade, Paz, et al., 1970T = 28, 40°C.; DH
181.0298.15Counsell, Lees, et al., 1968T = 10 to 350 K.; DH
201.3323.Swietoslawski and Zielenkiewicz, 1960Mean value 21 to 78°C.; DH
215.1333.Swietoslawski and Zielenkiewicz, 1958Mean value 21 to 99°C.; DH
184.1298.1Zhdanov, 1941T = 5 to 46°C.; DH
187.0303.Willams and Daniels, 1924T = 303 to 343 K. Equation only.; DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
129.2180.Counsell, Lees, et al., 1968glass phase; T = 10 to 180 K.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Connett, 1975
Connett, J.E., Chemical equilibria 6. Measurement of equilibrium constants for the dehydrogenation of 2-methylpropan-1-ol by a vapour-flow technique, J. Chem. Thermodyn., 1975, 7, 1159-1162. [all data]

Chao and Rossini, 1965
Chao, J.; Rossini, F.D., Heats of combustion, formation, and isomerization of nineteen alkanols, J. Chem. Eng. Data, 1965, 10, 374-379. [all data]

Rossini, 1934
Rossini, F.D., Heats of combustion and of formation of the normal aliphatic alcohols in the gaseous and liquid states, and the energies of their atomic linkages, J. Res. NBS, 1934, 13, 189-197. [all data]

Skinner and Snelson, 1960
Skinner, H.A.; Snelson, A., The heats of combustion of the four isomeric butyl alcohols, Trans. Faraday Soc., 1960, 56, 1776-1783. [all data]

Richards and Davis, 1920
Richards, T.W.; Davis, H.S., The heats of combustion of benzene, toluene, aliphatic alcohols, cyclohexanol, and other carbon compounds, J. Am. Chem. Soc., 1920, 42, 1599-1617. [all data]

Counsell, Lees, et al., 1968
Counsell, J.F.; Lees, E.B.; Martin, J.F., Thermodynamic properties of organic oxygen compounds. Part XIX. Low temperature heat capacity and entropy of propan-1-ol, 2-methyl-propan-1-ol, and pentan-1-ol, 1968, J. [all data]

Okano, Ogawa, et al., 1988
Okano, T.; Ogawa, H.; Murakami, S., Molar excess volumes, isentropic compressions, and isobaric heat capacities of methanol-isomeric butanol systems at 298.15 K, Can. J. Chem., 1988, 66, 713-717. [all data]

Piekarski and Somsen, 1988
Piekarski, H.; Somsen, G., Heat capacities and volumes of mixtures of N,N-dimethylformamide with isobutanol, sec-butanol and t-pentanol, J. Chem. Soc., Faraday Trans. 1, 1988, 84(2), 529-537. [all data]

Rybalkin, Emel'yanov, et al., 1978
Rybalkin, V.I.; Emel'yanov, V.M.; Stupak, P.M.; Litovchenko, N.P.; Z'ola, M.I., Study of the heat capacity of initial compounds and reaction products in the production of metal dialkyldithiophosphates, B.S.R. Inst. Neftepererab. Neftekhim. Prom. (Kiev), 1978, (16), 48-50. [all data]

Paz Andrade, Paz, et al., 1970
Paz Andrade, M.I.; Paz, J.M.; Recacho, E., Contribucion a la microcalorimetria de los calores especificos de solidos y liquidos, An. Quim., 1970, 66, 961-967. [all data]

Swietoslawski and Zielenkiewicz, 1960
Swietoslawski, W.; Zielenkiewicz, A., Mean specific heat in homologous series of binary and ternary positive azeotropes, Bull. Acad. Pol. Sci. Ser. Sci. Chim., 1960, 8, 651-653. [all data]

Swietoslawski and Zielenkiewicz, 1958
Swietoslawski, W.; Zielenkiewicz, A., Mean specific heats of binary positive azeotropes, Bull. Acad. Pol. Sci. Ser. Sci. Chim., 1958, 6, 367-369. [all data]

Zhdanov, 1941
Zhdanov, A.K., Specific heats of some liquids and azeotropic mixtures, Zhur. Obshch. Khim., 1941, 11, 471-482. [all data]

Willams and Daniels, 1924
Willams, J.W.; Daniels, F., The specific heats of certain organic liquids at elevated temperatures, J. Am. Chem. Soc., 1924, 46, 903-917. [all data]


Notes

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