Linalool

Formula: C₁₀H₁₈O
Molecular weight: 154.2493
IUPAC Standard InChI: InChI=1S/C10H18O/c1-5-10(4,11)8-6-7-9(2)3/h5,7,11H,1,6,8H2,2-4H3
IUPAC Standard InChIKey: CDOSHBSSFJOMGT-UHFFFAOYSA-N
CAS Registry Number: 78-70-6
Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript.
Species with the same structure:
- (S)-3,7-dimethyl-1,6-octadien-3-ol
Stereoisomers:
- (R)-linalool
Other names: 1,6-Octadien-3-ol, 3,7-dimethyl-; β-Linalool; Linalol; Linalyl alcohol; 2,6-Dimethyl-2,7-octadien-6-ol; allo-Ocimenol; 2,6-Dimethyl-2,7-octadiene-6-ol; 2,6-Dimethylocta-2,7-dien-6-ol; 3,7-Dimethyl-1,6-octadien-3-ol; 3,7-Dimethylocta-1,6-dien-3-ol; Linolool; Linanool; dl-3,7-Dimethyl-3-hydroxy-1,6-octadiene; Linalool ex bois de rose oil; Linalool ex ho oil; Linalool ex orange oil; Phantol; Linalool, β; (.+/-.)-Linalool; NSC 3789; beta-Linalool; p-Linalool; LINOLOOL (D); b-Linalool; Linaloyl oxide; (-)-linalool; 3,7-dimethyl-1,6-octandien-3-ol (linalool); R/S-linalool; ( S)-linalool; (+)-linalool; 3,7-dimethylocta-1,6-dien-3-ol (linalool); 3,7-dimethyl-1,6-octadien-3-ol (linalool); (-)-β-Linalool; (S)-Linalol; L-Linalool; (±)-linalool; 2,6-dimethyl-2,7-octadien-6-ol (linalool); linalool B; (+)-β-Linalool
Information on this page:
Other data available:
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- Gas Phase Kinetics Database
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Normal alkane RI, non-polar column, temperature ramp

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Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	RTX-5 MS	HP-5 MS	DB-5	HP-5 MS
Column length (m)	30.	30.	30.	30.	60.
Carrier gas	Helium	Helium	Helium	Helium	Helium
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25		0.25	0.25	0.25
T_start (C)	60.	60.	60.	60.	40.
T_end (C)	300.	240.	230.	240.	250.
Heat rate (K/min)	4.	3.	3.	3.	3.
Initial hold (min)	3.				1.
Final hold (min)	15.				20.
I	1098.	1104.	1110.	1095.	1103.
Reference	Bertuzzi, Tirillini, et al., 2013	Pinheiro, de Queiros, et al., 2013	Pripdeevech and Saansoomchai, 2013	Rodriques, Amorim, et al., 2013	Sardashti, Valizadeh, et al., 2013
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-1	RTX-1	RTX-1	DB-5	Mega-5
Column length (m)	30.	60.	60.	30.	25.
Carrier gas	Helium	Helium	Helium	Helium	Helium
Substrate
Column diameter (mm)	0.25	0.22	0.22	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	60.	60.	100.	50.
T_end (C)	240.	230.	230.	260.	220.
Heat rate (K/min)	3.	2.	2.	10.	3.
Initial hold (min)				1.	1.
Final hold (min)		5.	5.	10.	5.
I	1101.	1083.	1083.	1073.	1099.
Reference	Alizadeh and Shaabani, 2012	Bendiabdellah, El Amine Dib, et al., 2012	Bendiabdellah, El Amine Dib, et al., 2012	Boukhris, Bouaziz, et al., 2012	Dell'Agli, Sanna, et al., 2012
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	PTE-5	HP-5 MS	Optima-5 MS	HP-5 MS	Polydimethyl siloxane with 5 % Ph
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	Helium	Helium	Helium	Helium	Helium
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25
T_start (C)	80.	50.	35.	50.	80.
T_end (C)	300.	250.	250.	320.	200.
Heat rate (K/min)	7.	5.	10.	5.	5.
Initial hold (min)	3.	0.5	3.	5.
Final hold (min)	5.	0.5	5.		25.
I	1099.	1100.	1100.	1099.	1098.
Reference	Fabri, Coimbra, et al., 2012	Fanaro, Duarte, et al., 2012	Goeminne, Vandendriessche, et al., 2012	Nawrath, Mgode, et al., 2012	Priya, Prathapan, et al., 2012
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	HP-5	HP-5	DP-5	DP-5
Column length (m)	25.	25.	25.	30.	30.
Carrier gas	Hydrogen	Hydrogen	Hydrogen	Helium	Helium
Substrate
Column diameter (mm)	0.32	0.32	0.32	0.25	0.25
Phase thickness (μm)	0.52	0.52	0.52	0.25	0.25
T_start (C)	40.	40.	40.	80.	80.
T_end (C)	280.	280.	280.	300.	300.
Heat rate (K/min)	4.	4.	4.	4.	4.
Initial hold (min)				1.	1.
Final hold (min)	10.	10.	10.	40.	40.
I	1102.	1102.	1102.	1101.	1101.
Reference	Velickovic, Ristic, et al., 2012	Velickovic, Ristic, et al., 2012	Velickovic, Ristic, et al., 2012	Vijayakumar, Duraipandiyan, et al., 2012	Vijayakumar, Duraipandiyan, et al., 2012
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5 MS	CP-Sil 5 CB	HP-5	DB-5	DB-1
Column length (m)	30.	25.	30.	30.	30.
Carrier gas	Helium	Helium	Helium	Helium	Helium
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.15	0.25	0.25	0.25
T_start (C)	50.	50.	60.	40.	40.
T_end (C)	250.	220.	240.	250.	210.
Heat rate (K/min)	7.		3.	3.	5.
Initial hold (min)	1.			5.
Final hold (min)	5.			20.
I	1095.	1098.	1097.	1099.	1100.
Reference	Zouari, Ayadi, et al., 2012	Ameen, Usman, et al., 2011	Bertoli, Lepnardi, et al., 2011	Cao, Li, et al., 2011	Fathi, Sahari, et al., 2011
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5 MS	HP-5	DB-5	VF-5 MS	VF-5 MS
Column length (m)	30.	30.	30.	60.	60.
Carrier gas	Helium	Helium	Helium	Helium	Helium
Substrate
Column diameter (mm)	0.25	0.32	0.25	0.32	0.32
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	50.	60.	60.	30.	30.
T_end (C)	180.	240.	240.	260.	260.
Heat rate (K/min)	2.	3.	3.	2.	2.
Initial hold (min)		2.
Final hold (min)				28.	28.
I	1098.	1099.	1098.	1101.	1101.
Reference	Hammami, Kamoun, et al., 2011	Kahriman, Tosun, et al., 2011	Karimi, Farmani, et al., 2011	Leffingwell and Alford, 2011	Leffingwell and Alford, 2011
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	SE-30 MS	DB-1	HP-5 MS	CP-Sil 5 CB	RTX-5
Column length (m)	30.	50.	30.	30.	30.
Carrier gas	Helium	Helium	Helium	Nitrogen	Nitrogen
Substrate
Column diameter (mm)	0.25	0.32	0.25	0.25	0.32
Phase thickness (μm)	0.25	0.25	0.25	0.26	0.25
T_start (C)	50.	60.	40.	45.	60.
T_end (C)	250.	250.	260.	280.	210.
Heat rate (K/min)	5.	8.	4.	3.	3.
Initial hold (min)	5.
Final hold (min)	10.		5.	22.
I	1098.	1085.	1100.	1084.	1086.
Reference	Menichini, Tundis, et al., 2011	Misharina T., 2011	Miyazawa, Marumoto, et al., 2011	Mothana, Hasson, et al., 2011	Prasad, Moulekhi, et al., 2011
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	HP-5	ZB-5 MS	ZB-5 MS	HP-5
Column length (m)	50.	30.	30.	30.	30.
Carrier gas	Nitrogen	Helium	Helium	Helium	Helium
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.252
Phase thickness (μm)	0.32	0.25	0.25	0.25	0.25
T_start (C)	60.	50.	60.	60.	60.
T_end (C)	220.	300.	290.	290.	240.
Heat rate (K/min)	5.	50.	5.	5.	3.
Initial hold (min)	3.	5.
Final hold (min)	5.	5.
I	1097.	1101.	1099.	1100.	1099.
Reference	Salimi, Shafaghat, et al., 2011	Bi Kouame, Bedi, et al., 2010	Boix, Victorio, et al., 2010	Boix, Victorio, et al., 2010	Cavar, Maksimovic, et al., 2010
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5 MS	DB-5 MS	OV-1	RTX-1	DB-5
Column length (m)	25.	25.	50.	60.	30.
Carrier gas	Helium	Helium		Helium	Helium
Substrate
Column diameter (mm)	0.30	0.30	0.32	0.22	0.25
Phase thickness (μm)	0.25	0.25	0.50	0.25	0.25
T_start (C)	50.	50.	40.	60.	50.
T_end (C)	240.	240.	270.	230.	250.
Heat rate (K/min)	3.	3.	2.	2.	2.
Initial hold (min)
Final hold (min)			10.	30.
I	1099.	1100.	1085.	1086.	1097.
Reference	Chalchat, Figueredo, et al., 2010	Chalchat, Figueredo, et al., 2010	Da Costa, Yang, et al., 2010	Dib, Djabou, et al., 2010	Ho, Wang, et al., 2010
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	OV-1	HP-5 MS	HP-5 MS	HP-5	HP-5 MS
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	Helium	Helium	Helium	Helium	Helium
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.32	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	50.	70.	70.	60.	70.
T_end (C)	250.	200.	200.	240.	290.
Heat rate (K/min)	5.	3.	3.	3.	5.
Initial hold (min)	3.	2.	2.	2.
Final hold (min)	2.	18.	18.
I	1090.	1101.	1101.	1100.	1102.
Reference	Hu, Liang, et al., 2010	Jerkovic, Hegic, et al., 2010	Jerkovic and Marijanovic, 2010	Kahriman, Tosun, et al., 2010	Lazarevic, Radulovic, et al., 2010
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5 MS	BP-1	HP-5	HP-5	HP-5 MS
Column length (m)	60.		30.	30.	30.
Carrier gas	Helium	Nitrogen	Helium	Helium	Helium
Substrate
Column diameter (mm)	0.25		0.25	0.25	0.32
Phase thickness (μm)	0.25		0.25	0.25	0.25
T_start (C)	40.	60.	40.	50.	50.
T_end (C)	250.	220.	260.	240.	240.
Heat rate (K/min)	5.	5.	4.	3.	4.
Initial hold (min)	15.	10.		5.	2.
Final hold (min)	15.	30.	5.		10.
I	1102.	1092.	1100.	1109.	1099.
Reference	Mesa-Arango, Betancur-Galvis, et al., 2010	Mishra, Chaudhary, et al., 2010	Miyazawa, Kawauchi, et al., 2010	Monsef-Esfahani, Miri, et al., 2010	Pino, Marquez, et al., 2010
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5 MS	HP-5 MS	HP-5	HP-5 MS	DB-1
Column length (m)	30.	30.	30.	30.	60.
Carrier gas	Helium	Helium	Hydrogen	Helium	Nitrogen
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	100.	70.	70.	70.	60.
T_end (C)	220.	290.	290.	290.	250.
Heat rate (K/min)	2.	5.	5.	5.	4.
Initial hold (min)					1.
Final hold (min)		10.		10.	10.
I	1099.	1102.	1103.	1101.	1082.
Reference	Pripdeevech, Chumpolsri, et al., 2010	Radulovic, Blagojevic, et al., 2010	Radulovic, Dordevic, et al., 2010	Radulovic, Dordevic, et al., 2010, 2	Safaei-Ghomi, Meshkatalsadat, et al., 2010
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	SLB-5 MS	SLB-5 MS	DB-5 MS	DB-1-MS	CP Sil 5 CB
Column length (m)	10.	10.	30.	60.	25.
Carrier gas	Helium	Helium	Helium	Helium
Substrate
Column diameter (mm)	0.10	0.10	0.25	0.25	0.25
Phase thickness (μm)	0.10	0.10	0.25	0.25	0.15
T_start (C)	50.	50.	60.	30.	50.
T_end (C)	250.	250.	240.	200.	230.
Heat rate (K/min)	10.	10.	3.	2.	3.
Initial hold (min)				4.
Final hold (min)				35.
I	1099.	1101.	1098.	1090.	1098.
Reference	Scandinaro, Tranchida, et al., 2010	Scandinaro, Tranchida, et al., 2010	Silva, Pott, et al., 2010	Takeoka, Hobbs, et al., 2010	Usman, Zubair, et al., 2010
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	DB-1	HP-5MS	DB-5	OV-101
Column length (m)	30.	30.	30.	30.	50.
Carrier gas	Helium	Helium	Helium	Helium	Helium
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	80.	50.	50.	60.	70.
T_end (C)	240.	220.	250.	240.	220.
Heat rate (K/min)	3.	4.	7.	3.	2.
Initial hold (min)		2.	1.
Final hold (min)	2.	2.	5.
I	1100.	1083.	1107.	1097.	1081.
Reference	Vahirua-Lechat, Mitermite, et al., 2010	Xu, Tang, et al., 2010	Zouari, Zouari, et al., 2010	Alim, Goze, et al., 2009	Benites, Moiteiro, et al., 2009
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	SE-54	HP-5 MS	SPB-5	SPB-5	DB-5
Column length (m)	30.	30.	60.	30.	30.
Carrier gas	Helium	Helium	Nitrogen	Nitrogen	Helium
Substrate
Column diameter (mm)	0.25	0.25	0.35	0.53	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.50	0.25
T_start (C)	60.	60.	60.	50.	50.
T_end (C)	260.	250.	230.	210.	250.
Heat rate (K/min)	2.	2.	4.	3.	5.
Initial hold (min)	5.	8.		5.	2.
Final hold (min)	999.	15.	40.	45.
I	1098.	1104.	1100.	1085.	1097.
Reference	Dayisoylu and Alma, 2009	Farhat, Ginies, et al., 2009	Gauvin-Bialecki and Marodon, 2009	Gilani, Shah, et al., 2009	Ho, Wang, et al., 2009
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5 MS	SE-54	HP-5	RTX-1	RTX-1
Column length (m)	30.	30.	25.	60.	60.
Carrier gas	Helium		Helium	Helium	Helium
Substrate
Column diameter (mm)	0.25	0.32	0.20	0.22	0.22
Phase thickness (μm)	0.25	0.25	0.33	0.25	0.25
T_start (C)	35.	0.	60.	60.	60.
T_end (C)	195.	200.	240.	230.	230.
Heat rate (K/min)	2.	6.	3.	2.	2.
Initial hold (min)	5.	2.
Final hold (min)	30.		7.	30.	30.
I	1098.	1102.	1093.	1084.	1085.
Reference	Kim and Chung, 2009	Laselan, Buettner, et al., 2009	Maridass, 2009	Museli, Pau, et al., 2009	Museli, Pau, et al., 2009
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	OV-1	BP-1	DB-5 MS	DB-5	HP-5 MS
Column length (m)	30.	50.	60.	30.	30.
Carrier gas	Helium	Helium	Helium	Helium	Helium
Substrate
Column diameter (mm)	0.25	0.22	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	40.	60.	40.	45.	70.
T_end (C)	300.	220.	330.	250.	290.
Heat rate (K/min)	4.	2.	2.	3.	5.
Initial hold (min)	2.		12.	3.
Final hold (min)	10.	20.	30.	5.	10.
I	1085.	1082.	1111.	1100.	1102.
Reference	Nibret and Wink, 2009	Ottavioli, Bighelli, et al., 2009	Patil, Jayaprakasha, et al., 2009	Porto, Decorti, et al., 2009	Radulovic, Blagojevic, et al., 2009
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	5 % Phenyl methyl siloxane	Mega 5 MS	DB-5	DB-1 MS	DB-5 MS
Column length (m)	60.	60.	30.	30.	30.
Carrier gas	Helium	Helium	Nitrogen	Helium	Helium
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	90.	40.	40.	40.	40.
T_end (C)	225.	240.	230.	250.	250.
Heat rate (K/min)	3.	3.	2.	6.	4.
Initial hold (min)		2.		1.	2.
Final hold (min)	3.			4.	2.
I	1098.	1094.	1097.	1084.	1104.
Reference	Retta, Gattuso, et al., 2009	Romeo, Verzera, et al., 2009	Scrivanti, Anton, et al., 2009	Seo, Kim, et al., 2009	Su, Wang, et al., 2009
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5MS	HP-5 MS	HP-5	HP-5 MS	HP-5
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	Helium	Helium	Helium	Helium	Helium
Substrate
Column diameter (mm)	0.25	0.25	0.32	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	50.	60.	40.	50.	50.
T_end (C)	240.	325.	240.	280.	280.
Heat rate (K/min)	5.	10.	4.	4.	9.
Initial hold (min)		6.	4.		3.
Final hold (min)		10.			3.
I	1098.	1097.	1098.	1101.	1099.
Reference	Wannes, Mhamdi, et al., 2009	Zaibunnisa, Norashikin, et al., 2009	Zhannan, Shiqiong, et al., 2009	Zhao, Zeng, et al., 2009	Aicha, Ines, et al., 2008
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	BPX-5	BPX-5	BPX-5	BPX-5
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	Helium	Hydrogen	Hydrogen	Hydrogen	Hydrogen
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	100.	60.	60.	60.
T_end (C)	220.	999.	999.	999.	999.
Heat rate (K/min)	3.	3.	3.	3.	3.
Initial hold (min)
Final hold (min)
I	1093.	1108.	1106.	1107.	1107.
Reference	Bastos, Ishimoto, et al., 2008	Bieri and Marriott, 2008	Bieri and Marriott, 2008	Bieri and Marriott, 2008	Bieri and Marriott, 2008
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	BPX-5	BPX-5	HP-5	Ultra 2	HP-5
Column length (m)	30.	30.	30.	50.	30.
Carrier gas	Hydrogen	Hydrogen	Nitrogen	Helium	N2
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.20	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.11	0.25
T_start (C)	60.	60.	50.	60.	60.
T_end (C)	999.	999.	280.	230.	220.
Heat rate (K/min)	3.	5.	5.	2.	5.
Initial hold (min)			1.	5.	10.
Final hold (min)			1.	30.
I	1108.	1107.	1102.	1096.	1099.
Reference	Bieri and Marriott, 2008	Bieri and Marriott, 2008	Bousaada, Ammar, et al., 2008	Byun and Shin, 2008	Flamini, Tebano, et al., 2008
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5 MS	SPB-1	DB-1	SLB-5 MS	ZB-1
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	Helium	Helium	He	Helium	Nitrogen
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	1.0	0.25	0.25	0.25
T_start (C)	50.	60.	30.	50.	45.
T_end (C)	230.	250.	210.	250.	230.
Heat rate (K/min)	4.	5.	5.	3.	3.
Initial hold (min)	4.	5.		2.
Final hold (min)	10.			10.
I	1097.	1089.	1084.	1099.	1077.
Reference	Forero, Quijano, et al., 2008	Frerot, Velluz, et al., 2008	Kumazawa, Itobe, et al., 2008	Lo Presti, Sciarrone, et al., 2008	Mierendorff, Stahl-Biskup, et al., 2008
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	Equity-5 MS	DB-5 MS	Elite-1	HP-5 MS	HP-5 MS
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	Helium	Helium	Helium	Helium	Helium
Substrate
Column diameter (mm)	0.25	0.25	0.32	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	40.	50.	60.	60.	50.
T_end (C)	260.	300.	246.	250.	240.
Heat rate (K/min)	1.5	5.	3.	2.	3.
Initial hold (min)		5.		8.
Final hold (min)		5.		15.
I	1101.	1096.	1105.	1093.	1079.
Reference	Mondello, Casilli, et al., 2008	Noudogbessi, Yedomonhan, et al., 2008	Raj, Baby, et al., 2008	Sahraoui, Vian, et al., 2008	Sarikurkcu, Tepe, et al., 2008
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	RTX-5	DB-5 MS	OV-1	HP-5	5 % Phenyl methyl siloxane
Column length (m)	20.	30.	30.	30.	30.
Carrier gas	Helium	Helium	Helium	Helium
Substrate
Column diameter (mm)	0.18	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.20	0.25	0.25	0.32	0.25
T_start (C)	50.	60.	65.	60.	50.
T_end (C)	280.	270.	260.	250.	250.
Heat rate (K/min)	4.	3.	6.	5.	3.
Initial hold (min)	1.			30.
Final hold (min)
I	1102.	1100.	1106.	1096.	1101.
Reference	Skalicka-Wozniak, Los, et al., 2008	Victorio, Alviano, et al., 2008	Wang, Yi, et al., 2008	Yassa and Akhani, 2008	Zellner, Bicchi, et al., 2008
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5 MS	SE-54	DB-5	HP-5	CP Sil 5 CB
Column length (m)	30.	30.	50.	30.	30.
Carrier gas	Helium	Helium	Nitrogen	He	N2
Substrate
Column diameter (mm)	0.25	0.25	0.20	0.25	0.32
Phase thickness (μm)	0.25	0.25	0.32		0.25
T_start (C)	50.	60.	60.	70.	60.
T_end (C)	230.	260.	220.	240.	300.
Heat rate (K/min)	3.	2.	5.	5.	4.
Initial hold (min)	10.	5.	3.
Final hold (min)	10.	20.	5.
I	1098.	1098.	1099.	1098.	1087.
Reference	Adams, Beauchamp, et al., 2007	Alma, Ertas, et al., 2007	Amiri, 2007	Asekun, Olusegun, et al., 2007	Baran, von Reuss, et al., 2007
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5MS	HP-5MS	DB-5	HP-5MS	HP-5
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	He	He	He	He	N2
Substrate
Column diameter (mm)	0.25	0.25	0.26	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	60.	60.	60.	50.
T_end (C)	280.	280.	240.	280.	240.
Heat rate (K/min)	3.	3.	3.	3.	5.
Initial hold (min)					1.
Final hold (min)					4.
I	1094.	1101.	1096.	1101.	1098.
Reference	Basta, Pavlovic, et al., 2007	Basta, Tzakou, et al., 2007	Bos, Woerdenbag, et al., 2007	Bozin B., Mlmica-Dukic N., et al., 2007	Cheraif, Ben Jannet, et al., 2007
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	DB-5MS	HP-1	RTX-5 MS	DB-5
Column length (m)	60.	30.	30.	30.	30.
Carrier gas	He	He	Helium	He	Helium
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.26
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	40.	60.	70.	60.	60.
T_end (C)	220.	240.	200.	200.	290.
Heat rate (K/min)	3.	3.	10.	2.	3.
Initial hold (min)				2.
Final hold (min)				10.
I	1107.	1097.	1088.	1107.	1096.
Reference	Chyau, Tsai, et al., 2007	Da Silva J.K.R., Sousa P.J.C., et al., 2007	Dongmo, Tatsadjieu, et al., 2007	Edris, Chizzola, et al., 2007	Elfami, Bos, et al., 2007
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	HP-5MS	HP-5MS	ZP-5	DB-1
Column length (m)	30.	30.	30.	60.	60.
Carrier gas	Helium	He	He	He	Nitrogen
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.26	0.25	0.25	0.25	0.25
T_start (C)	60.	60.	60.	40.	60.
T_end (C)	240.	250.	250.	260.	250.
Heat rate (K/min)	4.	2.	2.	6.	4.
Initial hold (min)	2.	8.	8.	7.	1.
Final hold (min)	20.	15.	15.	1.	10.
I	1103.	1125.	1095.	1104.	1085.
Reference	Farsam, Amanlou, et al., 2007	Ferhat, Meklati, et al., 2007	Ferhat, Tigrine-Kordjani, et al., 2007	Füssel, Dötterl, et al., 2007	Ghasempour, Shirinpour, et al., 2007
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	Col-Elite 5MS	DBP-5	CP Sil 5 CB	RTX-5 MS	BP-1
Column length (m)	30.	25.	30.	30.
Carrier gas	He	Helium	N2	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.22	0.25	0.25
T_start (C)	30.	40.	50.	45.	60.
T_end (C)	246.	250.	200.	210.	220.
Heat rate (K/min)	3.	3.	5.	3.	5.
Initial hold (min)		1.
Final hold (min)		10.			6.
I	1101.	1071.	1087.	1102.	1085.
Reference	Gudaityte and Venskutonis R.P., 2007	Heravi and Sereshti, 2007	Hnawia, Cabalion, et al., 2007	Hudaib and Aburjai, 2007	Kiran, Devi, et al., 2007
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	HP-5 MS	HP-5 MS	SE-30	HP-5
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	He	Helium	Helium	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	60.	60.	40.	40.
T_end (C)	300.	220.	220.	250.	250.
Heat rate (K/min)	3.	6.	6.	5.	5.
Initial hold (min)				5.	5.
Final hold (min)				10.	10.
I	1094.	1095.	1100.	1098.	1092.
Reference	Limberger, Scopel, et al., 2007	Loghmani-Khouzani, Fini, et al., 2007	Loghmani-Khouzani, Fini, et al., 2007	Loizzo, Tundis, et al., 2007	Loizzo, Tundis, et al., 2007
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	DB-5	DB-5MS	ZB-5	DB-1
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	He	He	He		Helium
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	40.	40.	60.	60.	50.
T_end (C)	240.	240.	280.	220.	260.
Heat rate (K/min)	3.	3.	3.	4.	2.5
Initial hold (min)				5.	1.
Final hold (min)			30.	20.	20.
I	1088.	1098.	1069.	1111.	1080.
Reference	Machado, Bastos, et al., 2007	Machado, Bastos, et al., 2007	Marongiu B., Piras A., et al., 2007	Mohottalage, Tabacchi, et al., 2007	Monser-Esfahani, Karamkhani, et al., 2007
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	HP-5	Methyl Silicone	DB-1	HP-5
Column length (m)	30.	25.	50.	50.	25.
Carrier gas	Helium	H2	Helium	He	Helium
Substrate
Column diameter (mm)	0.25	0.2	0.25	0.25	0.32
Phase thickness (μm)	0.25	0.33		0.25	0.52
T_start (C)	60.	60.	50.	95.	40.
T_end (C)	300.	240.	240.	240.	280.
Heat rate (K/min)	3.	3.	3.	4.	4.
Initial hold (min)
Final hold (min)
I	1072.	1101.	1098.	1096.	1099.
Reference	Moreno, Lima, et al., 2007	Oliveira, Leitão, et al., 2007	Ozcan and Chalchat, 2007	Pala-Paul, Brophy, et al., 2007	Pavlovic, Petrovic, et al., 2007
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5 MS	SPB-1	BPX-5	DB-1	HP-5
Column length (m)	25.	30.	50.	60.	30.
Carrier gas	Helium	He	He	Nitrogen	Helium
Substrate
Column diameter (mm)	0.25	0.2	0.22	0.25	0.25
Phase thickness (μm)	0.25	0.2		0.25	0.25
T_start (C)	100.	70.	50.	60.	40.
T_end (C)	280.	220.	300.	250.	260.
Heat rate (K/min)	4.	3.	4.	4.	4.
Initial hold (min)	3.		1.	1.
Final hold (min)	5.	15.	10.	10.
I	1103.	1084.	1110.	1085.	1098.
Reference	Phutdhawong, Kawaree, et al., 2007	Pinto, Salgueiro, et al., 2007	Rali, Wossa, et al., 2007	Reza, Ebrahim, et al., 2007	Ristic, Krivokuca-Dokic, et al., 2007
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5 MS	DB-1	DB-5	DBP-5	RTX-5
Column length (m)	60.	60.	30.	25.	10.
Carrier gas	Hydrogen	He	He	Helium	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.18
Phase thickness (μm)	0.25	0.25	0.25	0.22	0.2
T_start (C)	60.	60.	50.	40.	40.
T_end (C)	260.	250.	240.	250.	275.
Heat rate (K/min)	4.	5.	4.	3.	50.
Initial hold (min)				1.	0.5
Final hold (min)	20.			10.	0.5
I	1099.	1083.	1097.	1071.	1107.
Reference	Rojas, Velasco, et al., 2007	Salehi, Fakhari, et al., 2007	Sefidkon, Abbasi, et al., 2007	Sereshti and Samadi, 2007	Setkova, Risticevic, et al., 2007
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	DB-5	Elite-5MS	DB-5	DB-5
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	He		He	Helium	Helium
Substrate
Column diameter (mm)	0.25	0.25	0.32	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.5
T_start (C)	60.	40.	40.	60.	60.
T_end (C)	320.	250.	280.	200.	200.
Heat rate (K/min)	10.	2.	4.	2.	2.
Initial hold (min)			5.
Final hold (min)	4.	33.	10.	20.	20.
I	1105.	1111.	1099.	1098.	1101.
Reference	Smelcerovic, Spiteller, et al., 2007	Sylvestre, Pichette, et al., 2007	Tava, Pecetti, et al., 2007	Tiwary, Nail, et al., 2007	Tiwary, Nail, et al., 2007
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5 MS	HP-5 MS	HP-5MS	HP-5	HP-5
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	Helium	Helium	He		He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.32
T_start (C)	60.	60.	40.	40.	60.
T_end (C)	280.	280.	250.	240.	250.
Heat rate (K/min)	3.	3.	3.	5.	5.
Initial hold (min)			5.	3.	30.
Final hold (min)			10.	10.
I	1100.	1097.	1097.	1100.	1096.
Reference	Tsokou, Georgopoulos, et al., 2007	Vagionas, Graikou, et al., 2007	Vichi, Riu-Aumatell, et al., 2007	Wenguang, Wenlai, et al., 2007	Yassa and Akhani, 2007
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	HP-5	HP-5	DB-5	DB-5
Column length (m)	25.	30.	30.	30.	30.
Carrier gas	He	N2	N2	He	He
Substrate
Column diameter (mm)	0.32	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	40.	50.	50.	40.	50.
T_end (C)	230.	280.	280.	260.	265.
Heat rate (K/min)	6.	9.	9.	4.	2.5
Initial hold (min)	1.	3.	3.	5.	1.
Final hold (min)		3.	3.		20.
I	1105.	1096.	1098.	1098.	1103.
Reference	Zeller and Rychlik, 2007	Abdelwahed, Hayder, et al., 2006	Abdelwahed, Hayder, et al., 2006	Askari and Sefidkon, 2006	Bazargani, Almasirad, et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	ZB-5	AT-5	BP-1	HP-5MS
Column length (m)	60.	30.	60.	50.	30.
Carrier gas	He		He		He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.22	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	40.	60.	60.	60.
T_end (C)	250.	300.	200.	220.	280.
Heat rate (K/min)	3.	2.	4.	2.	3.
Initial hold (min)
Final hold (min)			20.	20.
I	1101.	1099.	1097.	1083.	1100.
Reference	Bertrand, Comte, et al., 2006	Biondi, Sari, et al., 2006	Borges, Rojas, et al., 2006	Boti, Yao, et al., 2006	Bozin, Mimicá-Dukic, et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-1	HP-1	SPB-1	DB-1	DB-5
Column length (m)	50.	50.	30.	60.	30.
Carrier gas	He	He	Helium	Nitrogen	N2
Substrate
Column diameter (mm)	0.2	0.2	0.20	0.25	0.25
Phase thickness (μm)	0.5	0.33	0.20		0.25
T_start (C)	60.	60.	70.	40.	70.
T_end (C)	250.	250.	220.	200.	230.
Heat rate (K/min)	2.	2.	3.	2.	2.
Initial hold (min)		4.		1.	2.
Final hold (min)	120.	30.	15.	9.	20.
I	1089.	1089.	1082.	1089.	1098.
Reference	Castel, Fernandez, et al., 2006	Castel, Fernandez, et al., 2006	Cavaleiro, Pinto, et al., 2006	Chen, Sheu, et al., 2006	Choi, 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	DB-5	DB-5	DB-5	DB-5
Column length (m)	30.	30.	30.	60.	60.
Carrier gas	He		Helium	He	He
Substrate
Column diameter (mm)	0.32	0.32	0.26	0.32	0.32
Phase thickness (μm)	0.25	0.25	0.25
T_start (C)	60.	60.	60.	60.	50.
T_end (C)	246.	230.	290.	250.	250.
Heat rate (K/min)	3.	3.	3.	4.	4.
Initial hold (min)				5.	5.
Final hold (min)		15.
I	1099.	1098.	1096.	1103.	1103.
Reference	Coronel, Cerda-Garcia-Rojas, et al., 2006	Damjanovic, Skala, et al., 2006	Elfami, Komar, et al., 2006	Fadel, Mageed, et al., 2006	Fadel, Mageed, et al., 2006, 2
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	BP-1	BP-1	HP-5MS	HP-1	HP-5
Column length (m)	50.	50.	30.	50.	30.
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.22	0.22	0.25	0.2	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.33	0.25
T_start (C)	60.	60.	50.	60.	50.
T_end (C)	220.	220.	250.	250.	300.
Heat rate (K/min)	2.	2.	2.	2.	5.
Initial hold (min)					5.
Final hold (min)	20.	20.		60.	5.
I	1081.	1081.	1098.	1082.	1103.
Reference	Fanciullino, Tomi, et al., 2006	Fanciullino, Tomi, et al., 2006	Farah, Afifi, et al., 2006	Fernandez, Pintaric, et al., 2006	Figuérédo, Cabassu, et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-1	BPX-5	DB-5	DB-5	DB-5
Column length (m)	50.	25.	30.	30.	30.
Carrier gas	He	Helium		He	He
Substrate
Column diameter (mm)	0.2	0.20	0.25	0.25	0.25
Phase thickness (μm)	0.33	0.13	0.25	0.25	0.25
T_start (C)	60.	50.	40.	60.	60.
T_end (C)	250.	230.	210.	240.	240.
Heat rate (K/min)	2.	3.	2.	5.	5.
Initial hold (min)		2.	2.	2.	2.
Final hold (min)	40.		33.
I	1084.	1093.	1111.	1098.	1098.
Reference	Filippi, Lanfranchi, et al., 2006	Fons, Rapior, et al., 2006	Garneau F.X., Collin G., et al., 2006	Gohari, Hadjiakhoondi, et al., 2006	Gohari A.R., Hadjiakhoondi A., et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-1	CP Sil 5 CB	DB-5	BP-1	Methyl Silicone
Column length (m)	60.	30.	30.		25.
Carrier gas			Helium	Helium	He
Substrate
Column diameter (mm)	0.25	0.25	0.25		0.25
Phase thickness (μm)	0.25	0.25	0.25		0.25
T_start (C)	60.	40.	60.	60.	90.
T_end (C)	250.	220.	260.	220.	220.
Heat rate (K/min)	5.	3.	3.	5.	7.
Initial hold (min)					2.
Final hold (min)	10.	3.		6.
I	1086.	1097.	1102.	1085.	1088.
Reference	Hadian, Sonboli, et al., 2006	Hymete, Rohloff, et al., 2006	Javidnia, Miri, et al., 2006	Kiran, Bhavani, et al., 2006	Kitchlu, Bakshi, et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	RTX-1	DB-1	DB-1	OV-101	CP Sil 8 CB
Column length (m)	30.	60.	60.	25.	30.
Carrier gas	He			He
Substrate
Column diameter (mm)	0.32	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	70.	70.	100.	40.
T_end (C)	300.	230.	230.	250.	250.
Heat rate (K/min)	4.	2.	2.	8.	3.
Initial hold (min)		2.	2.		5.
Final hold (min)		20.	20.		20.
I	1087.	1083.	1083.	1094.	1101.
Reference	Kula, Izydorczyk, et al., 2006	Lan Phi N.T., Nishiyama C., et al., 2006	Lan Phi N.T., Nishiyama C., et al., 2006	Lattoo, Dhar, et al., 2006	Li, Lee, et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	CP Sil 5 CB	CP Sil 5 CB	HP-5 MS	HP-5	HP-101
Column length (m)	30.	30.	30.	30.	25.
Carrier gas	N2	N2	Nitrogen	N2	He
Substrate
Column diameter (mm)	0.32	0.25	0.25	0.25	0.2
Phase thickness (μm)	0.25	0.25	0.25	0.52	0.2
T_start (C)	50.	50.	50.	50.	70.
T_end (C)	300.	200.	280.	280.	200.
Heat rate (K/min)	4.	5.	5.	5.	3.
Initial hold (min)					2.
Final hold (min)			5.	5.	15.
I	1089.	1089.	1098.	1098.	1102.
Reference	Lis and Milczarek, 2006	Martin, Joseph, et al., 2006	Marzouk, Mansour, et al., 2006	Marzouk, Neffati, et al., 2006	Mastelic, Jerkovic, et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	DB-5	DB-5	DB-5	DB-5
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	Helium	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	50.	60.	60.	60.	50.
T_end (C)	250.	220.	260.	220.	250.
Heat rate (K/min)	3.	4.	4.	4.	4.
Initial hold (min)	5.		4.	5.
Final hold (min)
I	1096.	1098.	1099.	1099.	1101.
Reference	Mirza, Navaei, et al., 2006	Morteza-Semnani, Akbarzadeh, et al., 2006	Morteza-Semnani, Saeedi, et al., 2006	Morteza-Semnani K., Saeedi M., et al., 2006	Najafpour Navaei, Mirza, et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	DB-5	CP-Sil 5 CB	NB-30	DB-5
Column length (m)	30.	30.	25.	30.	25.
Carrier gas	He		Hydrogen	He	N2
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.2	0.25
Phase thickness (μm)	0.25	0.25	0.15	0.25	0.15
T_start (C)	50.	50.	50.	50.	50.
T_end (C)	250.	265.	230.	250.	200.
Heat rate (K/min)	3.	2.5	3.	2.	4.
Initial hold (min)	5.	0.5			3.
Final hold (min)
I	1102.	1112.	1091.	1089.	1100.
Reference	Navaei and Mirza, 2006	Nickavar B., Kamalinejad M., et al., 2006	Olawore, Usman, et al., 2006	Orav, Raal, et al., 2006	Ouamba, Ouabonzi, et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	DB-1	PE-5	HP-5MS	HP-5
Column length (m)	30.	50.	50.	30.	30.
Carrier gas	He	N2	He	He	He
Substrate
Column diameter (mm)	0.32	0.25	0.32	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	95.	100.	40.	60.
T_end (C)	280.	240.	280.	260.	220.
Heat rate (K/min)	5.	4.	3.	4.	5.
Initial hold (min)	0.5		1.		10.
Final hold (min)	2.
I	1100.	1101.	1098.	1103.	1106.
Reference	Ozel, Gogus, et al., 2006	Pala-Paul J., Perez-Alonso M.J., et al., 2006	Pandey-Rai S., Mallavarapu G.R., et al., 2006	Petrovic, Ristic, et al., 2006	Pintore G., Chessa M., et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	SPB-5	DB-5	DB-5	DB-5	HP-5
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	Helium	Hydrogen	Hydrogen	Hydrogen	H2
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	70.	70.	70.	50.
T_end (C)	250.	280.	280.	280.	280.
Heat rate (K/min)	4.	4.	4.	4.	4.
Initial hold (min)	2.	4.	4.	4.	2.
Final hold (min)	20.				10.
I	1098.	1098.	1098.	1098.	1098.
Reference	Pino, Marquez, et al., 2006	Pino, Marbot, et al., 2006	Pino, Marbot, et al., 2006	Pino, Marbot, et al., 2006	Pino, Sauri-Duch, et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5MS	HP-5	HP-5MS	DB-5	HP-5MS
Column length (m)	30.	25.	30.	30.	30.
Carrier gas	He	H2		He	He
Substrate
Column diameter (mm)	0.25	0.32	0.25	0.25	0.32
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	60.	50.	60.	60.
T_end (C)	280.	240.	250.	200.	243.
Heat rate (K/min)	3.	3.	10.	2.	3.
Initial hold (min)			5.
Final hold (min)				60.
I	1062.	1100.	1099.	1105.	1102.
Reference	Pitarokili, Tzakou, et al., 2006	Potzernheim, Bizzo, et al., 2006	Robinson, 2006	Rout, Naik, et al., 2006	Sabulal, Dan, et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5MS	ZB-5	DB-1	Ultra-2	FSOT-RSL-200
Column length (m)	30.	30.	60.	50.	30.
Carrier gas	He	He		He	Hydrogen
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.32
Phase thickness (μm)	0.25	0.25	0.25	0.32	0.25
T_start (C)	60.	40.	70.	50.	40.
T_end (C)	280.	300.	230.	270.	280.
Heat rate (K/min)	4.	2.	2.	2.	6.
Initial hold (min)			2.		5.
Final hold (min)			20.		5.
I	1100.	1099.	1087.	1101.	1093.
Reference	Sajjadi, 2006	Sari M., Biondi D.M., et al., 2006	Sawamura, Onishi, et al., 2006	Schlumpberger B.O., Clery R.A., et al., 2006	Schmidt, Jirovetz, et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	DB-5	DB-5	DB-1	DB-5
Column length (m)	30.	30.	30.	60.	30.
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25		0.25
T_start (C)	50.	50.	40.	40.	40.
T_end (C)	240.	240.	240.	250.	260.
Heat rate (K/min)	4.	4.	4.	4.	2.
Initial hold (min)					5.
Final hold (min)					20.
I	1104.	1103.	1096.	1081.	1101.
Reference	Sefidkon, Abbasi, et al., 2006	Sefidkon, Abbasi, et al., 2006	Sefidkon and Jamzad, 2006	Sefidkon, Jamzad, et al., 2006	Senatore, Landolfi, et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5MS	HP-5	DB-5	DB-1	SPB-5
Column length (m)	30.	25.	30.	60.
Carrier gas	He	N2	H2	Helium	He
Substrate
Column diameter (mm)	0.25	0.2	0.20	0.25
Phase thickness (μm)	0.25	0.33	0.18	0.25
T_start (C)	60.	30.	60.	60.	50.
T_end (C)	280.	280.	240.	250.	250.
Heat rate (K/min)	3.	3.	3.	5.	5.
Initial hold (min)	5.				3.
Final hold (min)				10.	15.
I	1101.	1101.	1098.	1083.	1098.
Reference	Setzer, Noletto, et al., 2006	Shafi, Jose, et al., 2006	Silva, Oliveira, et al., 2006	Sonboli, Mirjalili, et al., 2006	Stojanovic, Palic, et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	CP Sil 5 CB	HP-5 MS	DB-1	Methyl Silicone	HP-5MS
Column length (m)	25.	30.	30.	25.	30.
Carrier gas	H2	Helium		N2	He
Substrate
Column diameter (mm)	0.25	0.25	0.32	0.3	0.25
Phase thickness (μm)		0.25	0.25	0.15	0.25
T_start (C)	50.	60.	60.	50.	60.
T_end (C)	230.	250.	230.	210.	280.
Heat rate (K/min)	3.	2.	3.	2.	3.
Initial hold (min)		8.	3.	5.
Final hold (min)		15.	10.
I	1090.	1095.	1085.	1109.	1092.
Reference	Tesso, König, et al., 2006	Tigrine-Kordiani, Meklati, et al., 2006	Tohar, Mohd, et al., 2006	Tonzibo, Coffy, et al., 2006	Tzakou, Said, et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-1	BPX-5	SPB-1	SPB-1	DB-5
Column length (m)	50.	50.	50.	30.	30.
Carrier gas	N2		He	He	He
Substrate
Column diameter (mm)	0.25	0.22	0.2	0.25	0.25
Phase thickness (μm)	0.25	1.	0.33	0.25	0.25
T_start (C)	90.	70.	50.	50.	40.
T_end (C)	240.	280.	220.	250.	250.
Heat rate (K/min)	4.	4.	4.	4.	4.
Initial hold (min)			1.	1.
Final hold (min)		4.	10.	10.
I	1070.	1112.	1085.	1085.	1089.
Reference	Velasco-Negueruela, Pérez-Alonso, et al., 2006	Wohlmuth, Smith, et al., 2006	Wong, Lim, et al., 2006	Wong, Sivasothy, et al., 2006	Yadegarinia, Gachkar, et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	SE-30	HP-5MS	DB-5	DB-5	DB-5
Column length (m)	30.	30.	50.	25.	30.
Carrier gas	He	He			He
Substrate
Column diameter (mm)		0.25	0.3	0.25	0.25
Phase thickness (μm)		0.25	0.25	0.15	0.25
T_start (C)	90.	60.	60.	40.	60.
T_end (C)	220.	280.	240.	220.	240.
Heat rate (K/min)	7.	3.	2.	3.	3.
Initial hold (min)	2.			5.
Final hold (min)
I	1084.	1093.	1101.	1099.	1099.
Reference	Ahuja, Bakshi, et al., 2005	Basta, Tzakou, et al., 2005	Chagonda and Chalchat, 2005	Chagonda and Chalchat, 2005, 2	Chaverri and Cicció, 2005
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	Methyl Silicone	BPX-5	HP-5	DB-5
Column length (m)	30.	60.	25.	25.	30.
Carrier gas	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.3	0.22	0.2	0.25
Phase thickness (μm)	0.25		0.25	0.33	0.25
T_start (C)	60.	50.	50.	60.	40.
T_end (C)	240.	240.	320.	240.	240.
Heat rate (K/min)	3.	3.	5.	3.	4.
Initial hold (min)			5.		2.
Final hold (min)				7.
I	1097.	1096.	1109.	1101.	1112.
Reference	Chaverri and Cicció, 2005	Chalchat and Özcan, 2005	Dickschat, Martens, et al., 2005	Duarte, Figueira, et al., 2005	El-Sayed, Heppelthwaite, et al., 2005
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	CP Sil 8 CB	DB-1	DB-1	HP-5	HP-5
Column length (m)	30.	60.	60.	30.	30.
Carrier gas	He	He	N2	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	80.	60.	60.	60.	50.
T_end (C)	200.	250.	250.	30.	300.
Heat rate (K/min)	3.	5.	5.	4.	5.
Initial hold (min)	5.			3.	5.
Final hold (min)	5.		10.	15.	5.
I	1102.	1090.	1088.	1098.	1103.
Reference	Facey, Porter, et al., 2005	Fakhari, Salehi, et al., 2005	Fakhari A.R., Sonboli A., et al., 2005	Ferretti, Maggi, et al., 2005	Figuérédo, Cabassu, et al., 2005
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5MS	CP Sil 5 CB	CP Sil 5 CB	RSL-200	DB-1
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	He	N2	N2		He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	60.	60.	40.	50.
T_end (C)	200.	250.	250.	280.	265.
Heat rate (K/min)	4.	5.	5.	6.	2.5
Initial hold (min)	30.			2.	1.
Final hold (min)		10.	10.	10.	20.
I	1091.	1088.	1088.	1095.	1078.
Reference	Gauvin and Smadja, 2005	Jassbi, Mehrdad, et al., 2005	Jassbi, Mehrdad, et al., 2005	Jirovetz, Buchbauer, et al., 2005	Khanavi, Ghasemian, et al., 2005
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	SPB-5	HP-5	DB-5	DB-5MS	DB-5
Column length (m)	30.	60.	30.	30.	30.
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.53	0.32	0.25	0.25	0.25
Phase thickness (μm)		0.25	0.25	0.25	0.25
T_start (C)	100.	30.	60.	60.	60.
T_end (C)	250.	260.	230.	280.	220.
Heat rate (K/min)	5.	2.	3.	3.	4.
Initial hold (min)		2.		30.	5.
Final hold (min)		28.
I	1106.	1103.4	1090.	1072.	1097.
Reference	Kilic, Kollmannsberger, et al., 2005	Leffingwell and Alford, 2005	Limberger, Sobral, et al., 2005	Marongiu, Piras, et al., 2005	Morteza-Semnani, Akbarzadeh, et al., 2005
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	CP Sil 5 CB	CP Sil 5 CB	DB-5	HP-5
Column length (m)	30.	25.	25.	30.	30.
Carrier gas	He			He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.15	0.15		0.25
T_start (C)	50.	50.	50.	40.	70.
T_end (C)	250.	230.	230.	220.	240.
Heat rate (K/min)	3.	3.	3.	4.	5.
Initial hold (min)	5.			1.
Final hold (min)
I	1098.	1086.	1090.	1082.	1099.
Reference	Najafpour Navaei, Mirza, et al., 2005	Ogunwande, Olawore, et al., 2005	Olawore, Ogunwande, et al., 2005	de Oliveira, Dias, et al., 2005	Oyedeji, Yani, et al., 2005
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	DB-1	DB-1	RTX-5 MS	HP-5MS
Column length (m)	30.	50.	50.	30.	30.
Carrier gas	He	N2	N2	He
Substrate
Column diameter (mm)	0.32	0.25	0.25	0.25	0.2
Phase thickness (μm)	0.25	0.25	0.25	0.25
T_start (C)	40.	95.	95.	50.	60.
T_end (C)	250.	240.	240.	280.	280.
Heat rate (K/min)	5.	4.	4.	8.	3.
Initial hold (min)	0.5			2.
Final hold (min)	2.			2.
I	1100.	1096.	1096.	1104.	1097.
Reference	Özel, Gögüs, et al., 2005	Palá-Paúl, Pérez-Alonso, et al., 2005	Pala-Paul, Perez-Alonso, et al., 2005	Pellati, Benvenuti, et al., 2005	Petrakis, Roussis, et al., 2005
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	SPB-5	Methyl Silicone	CP Sil 5 CB	CP Sil 5 CB	HP-5MS
Column length (m)	30.	12.5	30.	30.	30.
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	50.	40.	40.	60.
T_end (C)	250.	270.	220.	220.	280.
Heat rate (K/min)	4.	4.	4.	4.	4.
Initial hold (min)	2.		1.	1.
Final hold (min)	20.
I	1098.	1092.	1097.	1097.	1099.
Reference	Pino, Marbot, et al., 2005	Ricci, Fraternale, et al., 2005	Rohloff and Bones, 2005	Rohloff and Bones, 2005	Sajjadi S.E. and Eskandari B., 2005
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	DB-1	DB-1	DB-5	HP-5MS
Column length (m)	30.	60.	30.	30.	30.
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	60.	50.	40.	60.
T_end (C)	220.	250.	265.	260.	280.
Heat rate (K/min)	3.	5.	2.5	2.	3.
Initial hold (min)	4.		1.	5.	5.
Final hold (min)		10.	20.	20.
I	1097.	1085.	1081.	1101.	1097.
Reference	Salehi, Sefidkon, et al., 2005	Salehi, Sonboli, et al., 2005	Sarkhail, Amin, et al., 2005	Senatore, Apostolides Arnold, et al., 2005	Setzer, Noletto, et al., 2005
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5MS	PE-5	DB-5	HP-5MS	RTX-1
Column length (m)	30.	30.	30.	30.	60.
Carrier gas	He	H2	He	He	He
Substrate
Column diameter (mm)	0.25	0.32	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	60.	60.	60.	60.
T_end (C)	240.	230.	230.	280.	250.
Heat rate (K/min)	3.	5.	3.	3.	5.
Initial hold (min)		2.
Final hold (min)		4.	20.		10.
I	1098.	1086.	1097.	1099.	1086.
Reference	da Silva, Andrade, et al., 2005	Singh, Raina, et al., 2005	Skoula and Grayer, 2005	Slavkovska, Couladis, et al., 2005	Sonboli A., Fakhari A.R., et al., 2005
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	RTX-1	DB-1	BP-1	DB-5	CP Sil 8 CB
Column length (m)	60.	60.	30.	30.	30.
Carrier gas	He	He	N2		He
Substrate
Column diameter (mm)	0.25	0.25	0.32	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25
T_start (C)	60.	60.	60.	40.	60.
T_end (C)	25.	250.	220.	210.	290.
Heat rate (K/min)	5.	5.	5.	2.	3.
Initial hold (min)				2.	5.
Final hold (min)	10.	10.	15.	33.
I	1084.	1083.	1083.	1111.	1088.
Reference	Sonboli, Salehi, et al., 2005	Sonboli, Salehi, et al., 2005, 2	Srivastava, Srivastava, et al., 2005	Stevanovic, Garneau, et al., 2005	Suárez, Vásquez, et al., 2005
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5MS	HP-5MS	HP-5 MS	HP-5MS	DB-5
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.32
Phase thickness (μm)	0.25	0.25	0.50	0.25	0.25
T_start (C)	50.	60.	60.	60.	60.
T_end (C)	240.	285.	260.	280.	280.
Heat rate (K/min)	3.	4.3	3.	3.	3.
Initial hold (min)	3.
Final hold (min)			20.
I	1112.	1098.	1100.	1062.	1073.
Reference	Tepe B., Sokmen M., et al., 2005	Tesevic, Nikicevic, et al., 2005	Topçu, Barla, et al., 2005	Tzakou, Bazos, et al., 2005	Tzakou and Constantinidis, 2005
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	DB-1	DB-1	HP-5MS	SPB-1
Column length (m)	30.	50.	50.	30.	50.
Carrier gas	Helium	N2			He
Substrate
Column diameter (mm)	0.32	0.25	0.25	0.25	0.2
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.33
T_start (C)	40.	90.	60.	40.	50.
T_end (C)	300.	240.	240.	220.	220.
Heat rate (K/min)	4.	4.	3.	3.	4.
Initial hold (min)				5.	3.
Final hold (min)	5.			10.	30.
I	1094.	1070.	1074.	1097.	1083.
Reference	Utsunomia, Kawata, et al., 2005	Velasco-Negueruela, Pérez-Alonso, et al., 2005	Velasco-Negueruela, Pérez-Alonso, et al., 2005, 2	Vichi, Riu-Aumatell, et al., 2005	Wong, Lee, et al., 2005
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	SPB-1	HP-5	DB-5	DB-5	HP-5
Column length (m)	50.	30.	30.	30.	30.
Carrier gas	He	Helium	He	He	He
Substrate
Column diameter (mm)	0.2	0.32	0.32	0.32	0.32
Phase thickness (μm)	0.33	0.25	0.25	0.25	0.25
T_start (C)	50.	40.	40.	40.	60.
T_end (C)	220.	250.	250.	250.	260.
Heat rate (K/min)	4.	5.	5.	5.	5.
Initial hold (min)	3.	2.	2.	2.	2.
Final hold (min)	30.	5.	10.	10.	13.
I	1087.	1088.	1088.	1088.	1091.
Reference	Wong and Tan, 2005	N/A	Wu, Krings, et al., 2005	Wu, Krings, et al., 2005	Yayli, Yasar, et al., 2005
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	CP Sil 5 CB	DB-5	BP-1	DB-1	DB-5
Column length (m)	30.	30.	50.	60.	30.
Carrier gas	N2	He		N2	He
Substrate
Column diameter (mm)	0.25	0.25	0.22	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	50.	90.	60.	70.	60.
T_end (C)	200.	220.	220.	230.	240.
Heat rate (K/min)	5.	7.	2.	2.	2.
Initial hold (min)		2.		2.
Final hold (min)		5.	20.	20.
I	1093.	1085.	1081.	1092.	1097.
Reference	Agnaniet, Menut, et al., 2004	Agnihotri, Thappa, et al., 2004	Blanc, Muselli, et al., 2004	Choi, 2004	Cicció, 2004
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	SPB-5	HP-5 MS	HP-5MS	DB-1	DB-5
Column length (m)	60.	30.	30.	25.	25.
Carrier gas	He	Helium	He		Nitrogen
Substrate
Column diameter (mm)	0.32	0.25	0.25	0.25	0.25
Phase thickness (μm)	1.	0.25	0.25	0.25	0.25
T_start (C)	60.	60.	60.	60.	60.
T_end (C)	200.	275.	275.	180.	240.
Heat rate (K/min)	4.	4.	4.	3.	3.
Initial hold (min)				10.
Final hold (min)	30.			10.
I	1096.	1101.	1091.	1098.	1101.
Reference	Gauvin, Ravaomanarivo, et al., 2004	Ghannadi, Sajjadi, et al., 2004	Hajhashemi V., Ghannadi A., et al., 2004	bin Jantan, Ayop, et al., 2004	JAvidnia, Mojab, et al., 2004
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	ZB-5	DB-5	RTX-1	SE-54	SE-54
Column length (m)	60.	60.	30.	30.	30.
Carrier gas	He	He	N2	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.053
Phase thickness (μm)	0.25	0.25	0.25	0.25	1.5
T_start (C)	40.	40.	60.	60.	100.
T_end (C)	260.	280.	300.	260.	250.
Heat rate (K/min)	6.	4.	4.	2.	5.
Initial hold (min)	4.6	4.		5.
Final hold (min)	1.
I	1104.	1096.	1087.	1098.	1106.
Reference	Jürgens and Dötterl, 2004	Kalvandi, Sefidkon, et al., 2004	Kalemba and Thiem, 2004	Kilic, Hafizoglu, et al., 2004	Kilic, Hafizoglu, et al., 2004
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5MS	DB-5MS	BP-1	DB-5MS	HP-5MS
Column length (m)	30.	30.	25.	30.	30.
Carrier gas	He	He	N2	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	50.	60.	60.	60.	60.
T_end (C)	230.	240.	220.	280.	275.
Heat rate (K/min)	5.	3.	5.	3.	4.
Initial hold (min)	2.
Final hold (min)	10.			30.
I	1093.	1099.	1088.	1066.	1103.
Reference	Li and Jiang, 2004	paz Lima, Silva, et al., 2004	Mallavarapu, Kulkarni, et al., 2004	Marongiu, Piras, et al., 2004	Mehrabani, Asadipour, et al., 2004
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5MS	DB-5	DB-5	DB-1	NB-30
Column length (m)	30.	30.	50.	60.	50.
Carrier gas	He	Helium	Helium	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.2
Phase thickness (μm)	0.25			0.25	0.25
T_start (C)	60.	60.	60.	50.	50.
T_end (C)	280.	240.	240.	270.	250.
Heat rate (K/min)	3.	2.	2.	4.	2.
Initial hold (min)
Final hold (min)		999.	999.
I	1100.	1098.	1098.	1090.	1089.
Reference	Mimica-Dukic, Bozin, et al., 2004	Miyazawa, Fuhita, et al., 2004	Miyazawa, Fujita, et al., 2004	Nik, Mirza, et al., 2004	Orav, Stulova, et al., 2004
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	NB-30	DB-1	DB-1	DB-1	DB-1
Column length (m)	50.	50.	60.	60.	60.
Carrier gas	He	N2	He	He	He
Substrate
Column diameter (mm)	0.2	0.25	0.32	0.32	0.32
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	50.	95.	35.	35.	35.
T_end (C)	250.	240.	230.	230.	230.
Heat rate (K/min)	2.	4.	2.	2.	2.
Initial hold (min)			4.	4.	4.
Final hold (min)			25.	25.	25.
I	1089.	1077.	1081.	1083.	1083.
Reference	Orav, Stulova, et al., 2004	Palá-Paúl, Velasco-Negueruela, et al., 2004	Park, Lee, et al., 2004	Park, Lee, et al., 2004	Park, Lee, et al., 2004
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-1	NB-30	NB-30	Methyl Silicone	HP-5 MS
Column length (m)	60.	50.	50.	60.	30.
Carrier gas	He	He	He	He	Helium
Substrate
Column diameter (mm)	0.32	0.2	0.20	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	35.	50.	50.	60.	60.
T_end (C)	230.	250.	250.	200.	200.
Heat rate (K/min)	2.	2.	2.	4.	4.
Initial hold (min)	4.			1.	1.
Final hold (min)	25.			20.	20.
I	1083.	1089.	1089.	1095.	1095.
Reference	Park, Lee, et al., 2004	Raal, Arak, et al., 2004	Raal, Paaver, et al., 2004	Rojas, Usubillaga, et al., 2004	Royas, Usubillaga, et al., 2004
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5MS	HP-5MS	DB-1	DB-1	DB-1
Column length (m)	30.	30.	30.	60.	60.
Carrier gas	He	He	He		Nitrogen
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	60.	50.	70.	70.
T_end (C)	280.	280.	265.	230.	230.
Heat rate (K/min)	4.	4.	2.5	2.	2.
Initial hold (min)			1.	2.	2.
Final hold (min)			20.	20.
I	1098.	1100.	1081.	1092.	1092.
Reference	Sadeghpour, Asghari, et al., 2004	Sajjadi and Shahpiri, 2004	Sarkhail, Amin, et al., 2004	Sawamura, Son, et al., 2004	Sawamura, Sou, et al., 2004
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	DB-1	HP-1	DB-5	HP-5
Column length (m)	30.	60.	30.	30.	25.
Carrier gas		He	He	He	N2
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.2
Phase thickness (μm)	0.25	0.25	0.33	0.25	0.5
T_start (C)	50.	40.	40.	40.	30.
T_end (C)	250.	280.	260.	250.	280.
Heat rate (K/min)	3.	4.	2.	2.	3.
Initial hold (min)	5.	5.	5.	5.
Final hold (min)			20.	20.
I	1098.	1079.	1092.	1098.	1101.
Reference	Sefidkon, Jamzad, et al., 2004	Sefidkon and Shaabani, 2004	Senatore, Napolitano, et al., 2004	Senatore, Rigano, et al., 2004	Shafi, Nambiar, et al., 2004
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	DB-5	DB-5	BPX-5	CP Sil 8 CB
Column length (m)	25.	30.	30.	25.	30.
Carrier gas	H2	He	He	He	He
Substrate
Column diameter (mm)	0.32	0.25	0.25	0.22	0.25
Phase thickness (μm)	0.52	0.25	0.25	1.	0.25
T_start (C)	40.	60.	60.	60.	50.
T_end (C)	240.	240.	300.	250.	200.
Heat rate (K/min)	4.	3.	3.	3.	10.
Initial hold (min)				5.	3.
Final hold (min)				10.	2.
I	1097.	1097.	1097.	1112.	1100.
Reference	Simic, Sokovic, et al., 2004	Tellez, Khan, et al., 2004	Tirillini, Pellegrino, et al., 2004	Vilaseca, Guy, et al., 2004	Wang and Guo-Y. -L., 2004
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	CP Sil 8 CB	DB-5	DB-5HT	HP-5MS	OV-101
Column length (m)	30.	30.	27.	30.	25.
Carrier gas		He	He	He	N2
Substrate
Column diameter (mm)	0.32	0.249	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25		0.25	0.25
T_start (C)	50.	60.	50.	60.	50.
T_end (C)	200.	300.	250.	275.	200.
Heat rate (K/min)	5.	3.	2.	4.	5.
Initial hold (min)	5.		2.
Final hold (min)			20.
I	1102.	1096.	1099.	1098.	1081.
Reference	Wang, Guo, et al., 2004	Woerdenbag, Windono, et al., 2004	Yusufoglu, Celik, et al., 2004	Afsharypuor and Jahromy, 2003	Agnaniet, Mounzeo, et al., 2003
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	BP-5	HP-5	DB-1	HP-5MS	Methyl Silicone
Column length (m)	25.	25.	60.	30.	12.5
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.33	0.2	0.25	0.25	0.25
Phase thickness (μm)		0.33	0.25	0.25
T_start (C)	50.	40.	70.	60.	50.
T_end (C)	275.	190.	230.	280.	270.
Heat rate (K/min)	3.	4.	2.	3.	4.
Initial hold (min)			2.
Final hold (min)		5.	20.
I	1102.	1086.	1092.	1098.	1097.
Reference	Ardakani, Mosaddegh, et al., 2003	Azodanlou, Darbellay, et al., 2003	Choi, 2003	Couladis, Özcan, et al., 2003	Curini, Bianchi, et al., 2003
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-1	DB-1	RTX-5Sil	DB-1	DB-5
Column length (m)	60.	60.	30.	60.	60.
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.32
Phase thickness (μm)			0.25	0.25
T_start (C)	50.	50.	70.	50.	50.
T_end (C)	250.	250.	200.	250.	220.
Heat rate (K/min)	4.	4.	4.	4.	3.
Initial hold (min)
Final hold (min)			10.
I	1081.	1081.	1104.	1083.	1107.
Reference	Dabiri and Sefidkon, 2003	Dabiri and Sefidkon, 2003, 2	Dudai, Larkov, et al., 2003	Ebrahimzadeh, Yamini, et al., 2003	Edris and Farrag, 2003
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	DB-5	HP-5MS	HP-1	DB-1
Column length (m)	60.	60.	30.	30.	30.
Carrier gas	He	He	He	He	N2
Substrate
Column diameter (mm)	0.32	0.32	0.25	0.25	0.25
Phase thickness (μm)			0.25	0.25	0.25
T_start (C)	50.	50.	60.	70.	50.
T_end (C)	220.	200.	220.	200.	200.
Heat rate (K/min)	3.	3.	5.	10.	5.
Initial hold (min)			20.
Final hold (min)			20.
I	1107.	1102.	1102.	1086.	1072.
Reference	Edris and Farrag, 2003	Edris, Shalaby, et al., 2003	Feizbaksh, Saber Tehrani, et al., 2003	Fekam Boyom, Amvam Zollo, et al., 2003	Fekam Boyom, Ngouana, et al., 2003
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5MS	HP-5MS	RSL-200	RSL-200	RSL-200
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	He	He	H2	H2	H2
Substrate
Column diameter (mm)	0.25	0.25	0.32	0.25	0.32
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	60.	40.	40.	40.
T_end (C)	275.	275.	280.	280.	280.
Heat rate (K/min)	4.	4.	6.	6.	6.
Initial hold (min)			5.	2.	5.
Final hold (min)			5.	10.	5.
I	1097.	1096.	1087.	1095.	1090.
Reference	Ghannadi, Aghazari, et al., 2003	Hajhashemi, Ghannadi, et al., 2003	Jirovetz, Buchbauer, et al., 2003	Jirovetz, Buchbauer, et al., 2003, 2	Jirovetz, Buchbauer, et al., 2003, 3
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	SE-30	CP Sil 5 CB	CP Sil 5 CB	SPB-5
Column length (m)	50.	12.	25.	25.	30.
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.2	0.22	0.25	0.25	0.32
Phase thickness (μm)	0.25	0.3	0.25	0.39	0.25
T_start (C)	50.	70.	35.	60.	40.
T_end (C)	220.	220.	280.	220.	220.
Heat rate (K/min)	3.	3.	5.	5.	5.
Initial hold (min)	2.		2.5		1.
Final hold (min)	10.				20.
I	1099.	1086.	1084.	1087.	1103.
Reference	Juteau, Jerkovic, et al., 2003	Kambouche and El-Abed, 2003	Kanjilal, Kotoky, et al., 2003	Khanavi, Hadjiakhoondi, et al., 2003	Ledauphin, Guichard, et al., 2003
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-1	DB-5MS	CP Sil 5 CB	ZB-1	DB-1
Column length (m)	30.	30.	25.	30.	60.
Carrier gas	N2	He		N2	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.39	0.25	0.25
T_start (C)	80.	60.	60.	45.	50.
T_end (C)	250.	240.	220.	230.	270.
Heat rate (K/min)	4.	3.	5.	3.	4.
Initial hold (min)
Final hold (min)
I	1086.	1099.	1090.	1077.	1090.
Reference	Mahalwal and Ali, 2003	Maia, Taveira, et al., 2003	Mazloomifar, Saber-Tehrani, et al., 2003	Mierendorff, Stahl-Biskup, et al., 2003	Mirza, Nik, et al., 2003
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	OV-101	MPS-5	CP Sil 5 CB	DB-1
Column length (m)	30.	12.		25.	50.
Carrier gas	Helium			H2	N2
Substrate
Column diameter (mm)	0.32	0.32		0.25	0.25
Phase thickness (μm)		0.32		0.15	0.25
T_start (C)	70.	35.	70.	50.	95.
T_end (C)	210.	225.	180.	230.	240.
Heat rate (K/min)	2.	6.	5.	3.	4.
Initial hold (min)		3.	2.
Final hold (min)	60.
I	1100.	1085.	1094.	1087.	1094.
Reference	Mookdasanit, Tamura, et al., 2003	Murakami, Goldstein, et al., 2003	Nakahara, Alzoreky, et al., 2003	Oyedeji, Ekundayo, et al., 2003	Perez-Alonso, Velasco-Negueruela, et al., 2003
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	HP-5	DB-5	NB-30	DB-1
Column length (m)	30.	30.	30.	50.	60.
Carrier gas	H2	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.2	0.2	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.5	0.25
T_start (C)	60.	60.	75.	50.	40.
T_end (C)	280.	280.	220.	250.	220.
Heat rate (K/min)	4.	3.	3.	2.	4.
Initial hold (min)	10.		4.
Final hold (min)	40.
I	1098.	1088.	1104.	1090.	1087.
Reference	Pino, Marbot, et al., 2003	Pitarokili, Tzakou, et al., 2003	Priestap, van Baren, et al., 2003	Raal, Arak, et al., 2003	Rasooli and Mirmostafa, 2003
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-1	HP-5	DB-1	DB-5	HP-5
Column length (m)	60.	30.	60.	30.	60.
Carrier gas	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	40.	60.	40.	60.	40.
T_end (C)	220.	280.	260.	240.	250.
Heat rate (K/min)	4.	4.	4.	3.	5.
Initial hold (min)			5.		15.
Final hold (min)
I	1087.	1100.	1081.	1098.	1098.
Reference	Rasooli and Mirmostafa, 2003	Sajjadi and Mehregan, 2003	Sefidkon, Naderi Nik, et al., 2003	da Silva, Luz, et al., 2003	Stashenko, Jaramillo, et al., 2003
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	DB-1	DB-1	Cross-Linked Methylsilicone	HP-5
Column length (m)	60.	60.	60.	25.	25.
Carrier gas		N2	N2	He	H2
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.2	0.32
Phase thickness (μm)	0.25	0.25	0.25	0.33	0.53
T_start (C)	40.	70.	70.	70.	40.
T_end (C)	250.	230.	230.	250.	280.
Heat rate (K/min)	5.	2.	2.	4.	4.
Initial hold (min)	15.	2.	2.
Final hold (min)		20.	20.
I	1098.	1087.	1092.	1070.	1097.
Reference	Stashenko, Jaramillo, et al., 2003	Tu, Onishi, et al., 2003	Tu, Onishi, et al., 2003, 2	Velasco-Negueruela, Pérez-Alonso, et al., 2003	Velickovic, Randjelovic, et al., 2003
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	HP-5	HP-5	HP-5	HP-5
Column length (m)	25.	25.	25.	25.	25.
Carrier gas	H2	Helium	Helium	Helium	Helium
Substrate
Column diameter (mm)	0.32	0.32	0.32	0.32	0.32
Phase thickness (μm)	0.53	0.53	0.53	0.53	0.53
T_start (C)	40.	40.	40.	40.	40.
T_end (C)	280.	280.	280.	280.	280.
Heat rate (K/min)	4.	4.	4.	4.	4.
Initial hold (min)
Final hold (min)
I	1098.	1097.	1097.	1098.	1098.
Reference	Velickovic, Randjelovic, et al., 2003	Velickovic, Ristic, et al., 2003	Velickovic, Ristic, et al., 2003	Velickovic, Ristic, et al., 2003	Velickovic, Ristic, et al., 2003
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	HP-5	DB-5	OV-101	OV-101
Column length (m)	25.	30.	30.	10.	25.
Carrier gas	Helium	He	He
Substrate
Column diameter (mm)	0.32	0.25	0.25	0.25	0.32
Phase thickness (μm)	0.53	0.32	0.25
T_start (C)	40.	60.	60.	35.	50.
T_end (C)	280.	250.	240.	225.	200.
Heat rate (K/min)	4.	5.	3.	6.	5.
Initial hold (min)		30.		5.
Final hold (min)
I	1099.	1108.	1099.	1087.	1084.
Reference	Velickovic, Ristic, et al., 2003	Yassa, Akhani, et al., 2003	Zoghbi, Andrade, et al., 2003	Bloss, Acree, et al., 2002	Boyom, Keumedjio, et al., 2002
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	HP-1	5 % Phenyl methyl siloxane	DB-1	BP-1
Column length (m)	30.	30.	30.	60.	25.
Carrier gas	He	He	He	He	N2
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.32	0.50
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	70.	75.	50.	60.
T_end (C)	280.	220.	200.	200.	220.
Heat rate (K/min)	3.	3.	3.	3.	5.
Initial hold (min)			4.	6.
Final hold (min)	30.	15.	8.		10.
I	1085.	1082.	1097.	1098.	1087.
Reference	Caredda, Marongiu, et al., 2002	Cavaleiro, Salgueiro, et al., 2002	Cicció and Gómez-Laurito, 2002	Cimanga, Apers, et al., 2002	Das, Ram, et al., 2002
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	HP-5	DB-5	DB-1	HP-5
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	N2	N2	He	H2	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.32	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	50.	50.	60.	40.	60.
T_end (C)	250.	250.	240.	245.	275.
Heat rate (K/min)	4.	4.	3.	3.	4.
Initial hold (min)		5.		20.
Final hold (min)
I	1099.	1099.	1101.	1084.	1099.
Reference	Farah, Fechtal, et al., 2002	Farah, Fechtal. M., et al., 2002	Flamini, Ertugrul, et al., 2002	Gancel, Ollé, et al., 2002	Ghannadi, Sajjadi, et al., 2002
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	SE-30	RSL-200	RSL-200	DB-1	SPB-5
Column length (m)	50.	30.	30.	25.	60.
Carrier gas	He	H2	H2	He	He
Substrate
Column diameter (mm)	0.25	0.32	0.32	0.23	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.20	0.25
T_start (C)	70.	40.	50.	50.	50.
T_end (C)	240.	280.	280.	200.	240.
Heat rate (K/min)	4.	6.	6.	3.	5.
Initial hold (min)		5.	5.	3.	3.
Final hold (min)		5.	5.	30.	10.
I	1088.	1093.	1086.	1093.	1103.
Reference	Iñigo, Palá-Paúl, et al., 2002	Jirovetz, Buchbauer, et al., 2002	Jirovetz, Ngassoum, et al., 2002	Khallouki, Younos, et al., 2002	Kim and Lee, 2002
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	RTX-5	OV-101	DB-5	DB-5
Column length (m)	30.	30.	25.	30.	30.
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.32	0.32	0.32
Phase thickness (μm)	0.25	0.25		0.25	0.25
T_start (C)	60.	60.	50.	40.	40.
T_end (C)	240.	150.	200.	290.	290.
Heat rate (K/min)	3.	1.	5.	7.	7.
Initial hold (min)		3.
Final hold (min)
I	1099.	1100.	1084.	1101.	1097.
Reference	Kobaisy, Tellez, et al., 2002	Kovacevic and Kac, 2002	Kuiate, Bessière, et al., 2002	Lin, Rouseff, et al., 2002	Lin, Rouseff, et al., 2002
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	DB-5	DB-5MS	OV-101	HP-5
Column length (m)	30.	30.	30.	25.	30.
Carrier gas		He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.32	0.25
Phase thickness (μm)	0.25	0.25	0.25		0.25
T_start (C)	60.	60.	60.	50.	60.
T_end (C)	275.	240.	240.	200.	240.
Heat rate (K/min)	4.	3.	3.	5.	3.
Initial hold (min)	4.
Final hold (min)
I	1094.	1098.	1099.	1087.	1102.
Reference	Lockwood, Asghari, et al., 2002	Maia, da Silva, et al., 2002	Maia, Zoghbi, et al., 2002	Menut, Bessière, et al., 2002	Novak, Langbehn, et al., 2002
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	OV-101	OV-101	DB-1	SPB-5
Column length (m)	30.	50.	50.	50.	30.
Carrier gas		He	He	N2	Helium
Substrate
Column diameter (mm)	0.25	0.2	0.2	0.25	0.25
Phase thickness (μm)	0.25	0.5	0.5	0.25	0.25
T_start (C)	60.	50.	50.	80.	60.
T_end (C)	240.	250.	250.	225.	250.
Heat rate (K/min)	3.	2.	2.	4.	4.
Initial hold (min)					2.
Final hold (min)					20.
I	1103.	1085.	1085.	1072.	1098.
Reference	Novak, Langbehn, et al., 2002	Orav, Kailas, et al., 2002	Orav, Kailas, et al., 2002	Palá-Paúl, Pérez-Alonso, et al., 2002	Pino, Marbot, et al., 2002
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	DB-5	DB-1	DB-1	DB-1
Column length (m)	30.	25.	60.	60.	60.
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.2	0.25	0.25	0.25
Phase thickness (μm)	0.25			0.25	0.25
T_start (C)	60.	60.	40.	40.	40.
T_end (C)	300.	220.	250.	280.	280.
Heat rate (K/min)	2.	3.	4.	4.	4.
Initial hold (min)				5.	5.
Final hold (min)
I	1095.	1099.	1079.	1083.	1081.
Reference	Ruberto, Biondi, et al., 2002	Schwob, Bessière, et al., 2002	Sefidkon, Dabiri, et al., 2002	Sefidkon, Jalili, et al., 2002	Sefidkon, 2002
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	DB-1	DB-1	DB-5MS	DB-5
Column length (m)	30.	50.	50.	30.	30.
Carrier gas	He	N2	N2	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	95.	60.	60.	60.
T_end (C)	240.	240.	240.	270.	240.
Heat rate (K/min)	3.	4.	3.	3.	3.
Initial hold (min)
Final hold (min)
I	1098.	1070.	1074.	1100.	1098.
Reference	Tellez, Khan, et al., 2002	Velasco-Negueruela, Pérez-Alonso, et al., 2002	Velasco-Negueruela, Pérez-Alonso, et al., 2002, 2	Zoghbi, Andrade, et al., 2002	Zoghbi, Andrade, et al., 2002, 2
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	Optima-1	HP-5	BP-5	DB-5MS	DB-5MS
Column length (m)	25.	30.	50.	60.	60.
Carrier gas	He	N2	H2	He	He
Substrate
Column diameter (mm)	0.20	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	1.	0.25	0.25
T_start (C)	50.	60.	60.	35.	35.
T_end (C)	250.	220.	270.	250.	250.
Heat rate (K/min)	3.	5.	6.	3.	3.
Initial hold (min)	3.	10.		5.	5.
Final hold (min)
I	1093.	1099.	1108.	1100.	1103.
Reference	Brun, Bessière, et al., 2001	Campeol, Flamini, et al., 2001	Doimo, 2001	Fernando and Grün, 2001	Fernando and Grün, 2001
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	HP-5	BP-1	RSL-200	RTX-1
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	N2	N2	N2	H2	N2
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.32	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	60.	60.	40.	60.
T_end (C)	220.	220.	220.	280.	300.
Heat rate (K/min)	5.	5.	5.	6.	4.
Initial hold (min)	10.	10.		5.
Final hold (min)				5.
I	1099.	1101.	1088.	1082.	1089.
Reference	Flamini, Cioni, et al., 2001	Gallori, Flamini, et al., 2001	Gupta, Mallavarapu, et al., 2001	Jirovetz L., Buchbauer G., et al., 2001	Kalemba, Marschall, et al., 2001
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	SPB-1	HP-1	RTX-5	BP-1	CBP-1
Column length (m)	30.	25.	30.	50.	25.
Carrier gas	N2	N2	He	He	Nitrogen
Substrate
Column diameter (mm)	0.25	0.2	0.25	0.22	0.25
Phase thickness (μm)	0.25	0.11	0.25	0.25	0.25
T_start (C)	70.	60.	60.	60.	50.
T_end (C)	180.	190.	150.	230.	210.
Heat rate (K/min)	2.	2.5	1.	2.	3.
Initial hold (min)	2.	3.	3.		2.
Final hold (min)	1.	1.		35.
I	1084.	1084.	1100.	1082.	1084.
Reference	Kamath, Asha, et al., 2001	Kovacevic and Kac, 2001	Kovacevic and Kac, 2001	Lota, de Rocca Serra, et al., 2001	Ly, Yamauchi, et al., 2001
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-1	OV-101	OV-101	DB-1	DB-5
Column length (m)	60.	50.	50.	30.	30.
Carrier gas	He	He	He	N2
Substrate
Column diameter (mm)	0.25	0.2	0.2	0.25	0.32
Phase thickness (μm)	0.25			0.25	0.5
T_start (C)	50.	50.	50.	80.	35.
T_end (C)	270.	250.	250.	225.	275.
Heat rate (K/min)	4.	2.	2.	4.	6.
Initial hold (min)
Final hold (min)
I	1080.	1086.	1086.	1069.	1101.
Reference	Mirza, Ahmadi, et al., 2001	Orav and Kann, 2001	Orav and Kann, 2001	Palá-Paúl, Pérez-Alonso, et al., 2001	Rouseff, Jella, et al., 2001
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	DB-1	HP-5 MS	PTE-5	DB-5MS
Column length (m)	60.	30.	30.	60.	30.
Carrier gas	He	He	Helium	H2	He
Substrate
Column diameter (mm)	0.25	0.2	0.25	0.32	0.32
Phase thickness (μm)			0.25	0.3	0.25
T_start (C)	50.	60.	50.	60.	40.
T_end (C)	250.	240.	250.	285.	195.
Heat rate (K/min)	3.	3.	5.	4.3	5.
Initial hold (min)	5.		2.		5.
Final hold (min)			5.		40.
I	1098.	1103.0	1094.	1098.	1099.
Reference	Rousis, Papadogianni, et al., 2001	Santos, Moreira, et al., 2001	Shang, Hu, et al., 2001	Stojanovic, Palic, et al., 2001	Suriyaphan, Drake, et al., 2001
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	SPB-1	OV-101	OV-101	CP Sil 5 CB	CP Sil 5 CB
Column length (m)	30.	50.	50.	25.	25.
Carrier gas	He	N2	N2		He
Substrate
Column diameter (mm)	0.32	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25			0.15	0.4
T_start (C)	50.	80.	80.	50.	60.
T_end (C)	250.	200.	200.	230.	260.
Heat rate (K/min)	2.	2.	2.	3.	5.
Initial hold (min)					40.
Final hold (min)
I	1092.	1088.	1088.	1100.	1078.
Reference	Vijayanand, Rao, et al., 2001	Yang, 2001	Yang, 2001, 2	Asekun and Ekundayo, 2000	Baser, Özek, et al., 2000
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	Optima-1	DB-5	RSL-200	DB-5	DB-5
Column length (m)	25.	30.	60.	30.	30.
Carrier gas	He	He	H2	H2	He
Substrate
Column diameter (mm)	0.20	0.32	0.32	0.32	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.5	0.25
T_start (C)	50.	40.	40.	60.	60.
T_end (C)	250.	230.	250.	245.	240.
Heat rate (K/min)	3.	6.	6.	3.	3.
Initial hold (min)	3.	2.		3.
Final hold (min)		5.		20.
I	1094.	1097.	1096.	1103.	1100.
Reference	de Beck, Bessière, et al., 2000	Czerny and Grosch, 2000	Jirovetz, Puschmann, et al., 2000	Kotseridis and Baumes, 2000	Maia, Zoghbi, et al., 2000
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-1	HP-1	DB-5	BP-1	HP-5
Column length (m)	25.	60.	30.	25.	30.
Carrier gas	Nitrogen	He	N2	N2	He
Substrate
Column diameter (mm)	0.50	0.25	0.22	0.33	0.25
Phase thickness (μm)	0.25	0.25	0.25	1.0	0.25
T_start (C)	60.	60.	70.	60.	60.
T_end (C)	220.	200.	230.	275.	275.
Heat rate (K/min)	5.	4.	4.	4.	4.
Initial hold (min)		5.	2.
Final hold (min)		25.	20.
I	1086.	1088.	1100.	1109.	1100.
Reference	Mallavarapu, Rao, et al., 2000	Meccia, Rojas, et al., 2000	Mitiku, Sawamura, et al., 2000	Mohagheghzadeh, Shams-Ardakani, et al., 2000	Mohagheghzadeh, Shams-Ardakani, et al., 2000, 2
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-1	OV-101	DB-5	SE-30	OV-101
Column length (m)	30.	50.	30.	25.	25.
Carrier gas	He	Nitrogen	He	He	N2
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.2	0.25
Phase thickness (μm)	0.25		0.25
T_start (C)	40.	40.	60.	60.	50.
T_end (C)	260.	200.	240.	230.	200.
Heat rate (K/min)	2.	2.	3.	3.	5.
Initial hold (min)	5.	10.
Final hold (min)	2.
I	1086.	1090.	1099.	1091.	1088.
Reference	Senatore, Napolitano, et al., 2000	Tamura, Boonbumrung, et al., 2000	Tellez, Dayan, et al., 2000	Ali N.A.M. and Jantan, 1999	Ayedoun, Adéoti, et al., 1999
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	Methyl Silicone	OV-1	OV-1	OV-1	SPB-1
Column length (m)	60.	25.	25.	25.	50.
Carrier gas		Hydrogen	Hydrogen	Hydrogen
Substrate
Column diameter (mm)	0.25	0.32	0.32	0.32	0.2
Phase thickness (μm)	0.25	0.30	0.30	0.30	0.33
T_start (C)	40.	50.	50.	50.	60.
T_end (C)	220.	200.	200.	200.	260.
Heat rate (K/min)	5.	3.	3.	3.	4.
Initial hold (min)	10.	1.	1.	1.
Final hold (min)		10.	10.	10.
I	1085.90	1080.	1080.	1080.	1085.
Reference	Baraldi, Rapparini, et al., 1999	Bicchi, Binello, et al., 1999	Bicchi, Binello, et al., 1999	Bicchi, Binello, et al., 1999	Choo, Wong, et al., 1999
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	OV-101	BP-5	HP-1	BP-1	OV-101
Column length (m)	25.	50.	25.	25.	50.
Carrier gas		He	H2	N2	N2
Substrate
Column diameter (mm)	0.32	0.32	0.32	0.50	0.2
Phase thickness (μm)		1.	0.17	0.25
T_start (C)	50.	40.	40.	60.	80.
T_end (C)	200.	190.	260.	220.	200.
Heat rate (K/min)	5.	2.	3.	5.	1.
Initial hold (min)		5.	5.
Final hold (min)				10.	20.
I	1084.	1106.	1084.	1086.	1092.
Reference	Kuiate, Zollo, et al., 1999	Lopez, Ferreira, et al., 1999	Lopes, Koketsu, et al., 1999	Mallavarapu, Kulkarni, et al., 1999	Menon, Chacko, et al., 1999
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	SE-30	OV-1	HP-1	CP Sil 5 CB
Column length (m)	30.	25.	25.	25.	25.
Carrier gas	He	He	H2		He
Substrate
Column diameter (mm)	0.25	0.2	0.25	0.20	0.25
Phase thickness (μm)			0.25
T_start (C)	40.	60.	40.	35.	50.
T_end (C)	230.	230.	220.	250.	230.
Heat rate (K/min)	4.	3.	3.	4.	3.
Initial hold (min)	1.	10.	5.
Final hold (min)			5.
I	1102.	1091.	1084.	1083.	1085.
Reference	Mockute and Bernotiene, 1999	Mohd and Jantan, 1999	Oberhofer, Nikiforov, et al., 1999	Ong and Acree, 1999	Oyedeji, Olawore, et al., 1999
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-1	OV-101	Ultra-2	BP-1	CP Sil 5 CB
Column length (m)	50.	50.	25.	25.	25.
Carrier gas	He	He		N2	He
Substrate
Column diameter (mm)	0.25	0.25	0.2	0.5	0.25
Phase thickness (μm)	0.25	0.25			0.39
T_start (C)	70.	70.	40.	60.	60.
T_end (C)	240.	220.	300.	220.	220.
Heat rate (K/min)	4.	2.	5.	5.	5.
Initial hold (min)		5.	4.		5.
Final hold (min)				10.	20.
I	1070.	1081.	1089.	1087.	1088.
Reference	Palá-Paúl, Pérez-Alonso, et al., 1999	Pateira, Nogueira, et al., 1999	Quiroz, Fuentes-Contreras, et al., 1999	Rao, Bhattacharya, et al., 1999	Rustaiyan, Masoudi, et al., 1999
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	CP Sil 5 CB	DB-1	DB-1	DB-5	OV-101
Column length (m)	25.	60.	60.	30.	25.
Carrier gas	N2	He	He	H2	Nitrogen
Substrate
Column diameter (mm)	0.25	0.25	0.32	0.32	0.20
Phase thickness (μm)	0.39	0.25
T_start (C)	60.	50.	60.	32.	60.
T_end (C)	220.	220.	230.	260.	220.
Heat rate (K/min)	5.	4.	3.	7.	4.
Initial hold (min)				5.	0.
Final hold (min)			5.	5.	0.
I	1091.	1092.	1087.	1107.	1088.
Reference	Rustaiyan and Nadji, 1999	Sefidkon and Mirza, 1999	Shafiee, Javidnia, et al., 1999	Sun and Petracek, 1999	Tropnikova, Zenkevich, et al., 1999
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	SPB-5	CP Sil 5 CB	OV-101	DB-5MS	SPB-5
Column length (m)	60.	25.	25.	30.	50.
Carrier gas	He	N2	He	He	He
Substrate
Column diameter (mm)	0.32		0.20	0.25	0.32
Phase thickness (μm)	1.	0.39		0.25	0.25
T_start (C)	40.	60.	80.	60.	60.
T_end (C)	200.	220.	240.	240.	240.
Heat rate (K/min)	3.	5.	6.	3.	3.
Initial hold (min)	5.
Final hold (min)	2.				20.
I	1101.	1087.	1088.	1098.	1099.
Reference	Viallon C., Verdier-Metz I., et al., 1999	Weyerstahl, Marschall, et al., 1999	Zenkevich, Kosman, et al., 1999	Zoghbi, Andrade, et al., 1999	Doneanu and Anitescu, 1998
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	BP-5	SE-30	OV-1	CBP-1
Column length (m)	30.	50.	25.	50.	30.
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.32	0.2	0.32	0.25
Phase thickness (μm)	0.25	1.		0.25
T_start (C)	60.	40.	60.	50.	60.
T_end (C)	240.	190.	180.	250.	240.
Heat rate (K/min)	3.	2.	3.	10.	4.
Initial hold (min)		5.	10.	5.
Final hold (min)				20.
I	1092.	1106.	1085.	1090.	1084.
Reference	El-Sakhawy, El-Tantawy, et al., 1998	Ferreira, Ardanuy, et al., 1998	Jantan, Ahmad, et al., 1998	Kökdil, Kurucu, et al., 1998	Lamarque, Maestri, et al., 1998
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	HP-1	HP-5	HP-1	HP-1
Column length (m)	30.	25.	25.	25.	60.
Carrier gas	He		He		He
Substrate
Column diameter (mm)	0.25	0.32	0.2	0.2	0.25
Phase thickness (μm)	0.25		0.33		0.25
T_start (C)	60.	35.	70.	35.	50.
T_end (C)	240.	250.	290.	200.	280.
Heat rate (K/min)	3.	4.	3.	5.	4.
Initial hold (min)			8.	5.	5.
Final hold (min)			20.
I	1098.	1083.	1100.	1083.	1079.
Reference	Maia, Zohhbi, et al., 1998	Ong and Acree, 1998	Poiana, Sicari, et al., 1998	Quiroz A. and Niemeyer H.M., 1998	Stashenko, Cervantes, et al., 1998
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	OV-101	CP Sil 5 CB	CP Sil 5 CB	CP Sil 5 CB	BPX-5
Column length (m)	25.	25.	25.	25.	50.
Carrier gas		N2	N2	He	He
Substrate
Column diameter (mm)	0.32	0.32	0.32	0.25	0.22
Phase thickness (μm)		0.25	0.25	0.25	0.25
T_start (C)	50.	50.	50.	60.	50.
T_end (C)	200.	290.	290.	300.	250.
Heat rate (K/min)	5.	4.	4.	6.	3.
Initial hold (min)					1.
Final hold (min)					10.
I	1088.	1082.	1082.	1082.	1109.
Reference	Zollo, Biyiti, et al., 1998	Bos, Woerdenbag, et al., 1997	Bos, Woerdenbag, et al., 1997	Bos, Woerdenbag, et al., 1997, 2	D'Arcy, Rintoul, et al., 1997
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	OV-1	SPB-Sulfur	SPB-Sulfur	DB-5	DB-1
Column length (m)	30.	30.	30.	30.
Carrier gas	He	He	He	He
Substrate
Column diameter (mm)	0.32	0.32	0.32	0.25
Phase thickness (μm)	0.25	4.	4.	0.25
T_start (C)	40.	45.	45.	50.	80.
T_end (C)	270.	240.	240.	250.	220.
Heat rate (K/min)	2.	5.	5.	2.	6.
Initial hold (min)	4.	13.	13.	5.
Final hold (min)		5.	5.
I	1102.	1090.	1092.	1092.	1074.
Reference	Kökdil, Kurucu, et al., 1997	Mariaca, Berger, et al., 1997	Mariaca, Berger, et al., 1997	Reverchon, Porta, et al., 1997	Salgueiro, Vila, et al., 1997
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	DB-5	CBP-1	HP-1	OV-101
Column length (m)	30.	30.	25.	23.	50.
Carrier gas	Helium	He	He	He	N2
Substrate
Column diameter (mm)	0.25	0.25	0.22	0.32	0.25
Phase thickness (μm)	0.25			0.17	0.17
T_start (C)	60.	60.	60.	60.	50.
T_end (C)	240.	240.	240.	250.	220.
Heat rate (K/min)	3.	4.	5.	5.	5.
Initial hold (min)				3.
Final hold (min)				30.
I	1099.	1094.	1084.	1084.	1091.
Reference	Tellez, Estell, et al., 1997	Zunino, Novillo-Newton, et al., 1997	Zygadlo, Ariza-Espinar, et al., 1997	Ayedoun, Adeoti, et al., 1996	Chacko, Jayalekshmy, et al., 1996
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-1	OV-101	BP-1	BP-1	BP-1
Column length (m)	30.	50.	25.	25.	25.
Carrier gas	N2	He	N2	N2	N2
Substrate
Column diameter (mm)	0.53	0.25	0.50	0.50	0.50
Phase thickness (μm)	0.88
T_start (C)	60.	50.	60.	60.	60.
T_end (C)	300.	250.	220.	220.	220.
Heat rate (K/min)	8.	2.	5.	5.	5.
Initial hold (min)
Final hold (min)	15.
I	1089.	1085.	1086.	1087.	1088.
Reference	Malizia, Molli, et al., 1996	Orav, Kailas, et al., 1996	Rajeswara, Kaul, et al., 1996	Rajeswara, Kaul, et al., 1996	Rajeswara, Kaul, et al., 1996
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-1	HP-1	SPB-1	OV-101	OV-101
Column length (m)	60.	25.	50.	15.	15.
Carrier gas	He	Helium	He	He	He
Substrate
Column diameter (mm)	0.32	0.32	0.2	0.32	0.32
Phase thickness (μm)	0.50	0.25	0.33
T_start (C)	50.	60.	40.	35.	35.
T_end (C)	250.	220.	200.	250.	250.
Heat rate (K/min)	8.	4.	3.	6.	6.
Initial hold (min)	1.	2.	3.	3.	3.
Final hold (min)	6.	20.	30.
I	1084.	1084.	1087.	1071.	1090.
Reference	Sagrero-Nieves and Bartley, 1996	Thanh, Dung, et al., 1996	Wong and Lai, 1996	Chisholm, Guiher, et al., 1995	Chisholm, Guiher, et al., 1995
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	OV-101	HP-5	DB-1	DB-1	DB-1
Column length (m)	52.		60.	60.	60.
Carrier gas	He		He	He	He
Substrate
Column diameter (mm)	0.26		0.25	0.25	0.25
Phase thickness (μm)			0.25	0.25	0.25
T_start (C)	50.	35.	50.	70.	70.
T_end (C)	220.	200.	250.	270.	270.
Heat rate (K/min)	3.	6.	3.5	2.5	2.5
Initial hold (min)		2.	5.	5.	5.
Final hold (min)
I	1091.	1104.	1084.	1083.	1083.
Reference	Dzumayev, Tsibulskaya, et al., 1995	Larsen and Frisvad, 1995	Stashenko, Torres, et al., 1995	Tirado, Stashenko, et al., 1995	Tirado, Stashenko, et al., 1995
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5 MS	OV-1	DB-1	HP-5	HP-5
Column length (m)	30.	50.	60.
Carrier gas	Helium	N2
Substrate
Column diameter (mm)	0.25	0.27	0.32
Phase thickness (μm)		0.2	0.50
T_start (C)	50.	80.	50.	40.	40.
T_end (C)	250.	240.	225.	210.	210.
Heat rate (K/min)	4.	3.	2.	2.	2.
Initial hold (min)
Final hold (min)
I	1104.	1085.	1085.	1111.	1112.
Reference	Gomez and Ledbetter, 1994	Ramanoelina, Viano, et al., 1994	Sagrero-Nieves, Bartley, et al., 1994	Collin, Deslauriers, et al., 1993	Collin, Deslauriers, et al., 1993
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-101	OV-101	Methyl Silicone	Methyl Silicone	Ultra-1
Column length (m)	50.	50.	50.	50.	50.
Carrier gas	H2		N2	N2	He
Substrate
Column diameter (mm)	0.32	0.22	0.25	0.25	0.31
Phase thickness (μm)	0.3		0.17	0.17	0.17
T_start (C)	65.	80.	80.	80.	30.
T_end (C)	300.	200.	200.	200.	210.
Heat rate (K/min)	2.	2.	2.	3.	2.
Initial hold (min)	5.				4.
Final hold (min)
I	1084.	1092.	1092.	1092.	1084.
Reference	Demarne and van der Walt, 1993	Egolf and Jurs, 1993	Gopalakrishnan, Menon, et al., 1993	Gopalakrishnan, Menon, et al., 1993	Iwaoka, Zhang, et al., 1993
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	CP Sil 5 CB	Methyl Silicone	OV-101	OV-101	SE-54
Column length (m)	25.	25.	50.	50.	30.
Carrier gas					Hydrogen
Substrate
Column diameter (mm)	0.25	0.50	0.25	0.25	0.25
Phase thickness (μm)					0.25
T_start (C)	60.	60.	80.	80.	60.
T_end (C)	280.	220.	200.	200.	250.
Heat rate (K/min)	5.	5.	2.	2.	2.
Initial hold (min)					5.
Final hold (min)					2.
I	1090.	1087.	1088.	1088.	1099.
Reference	Kaul, Singh, et al., 1993	Mallavarapu, Ramesh, et al., 1993	Tamura, Yang, et al., 1993	Tamura, Yang, et al., 1993	Kollmannsberger, Nitz, et al., 1992
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-1	DB-1	DB-1	DB-1	DB-1
Column length (m)	30.	30.	30.	60.	60.
Carrier gas	He	He	N2
Substrate
Column diameter (mm)	0.25	0.25
Phase thickness (μm)	1.0	1.0
T_start (C)	40.	40.	80.	30.	30.
T_end (C)	250.	250.	220.	200.	200.
Heat rate (K/min)	3.	3.	4.	4.	4.
Initial hold (min)				25.	25.
Final hold (min)	30.	30.		30.	30.
I	1085.	1092.	1085.	1083.	1070.
Reference	Peppard, 1992	Peppard, 1992	Velasco-Negueruela, Pérez Alonso, et al., 1991	Buttery, Takeoka, et al., 1990	Buttery, Takeoka, et al., 1990
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-1	CP Sil 8 CB	HP-5	HP-5	OV-101
Column length (m)	60.	25.	50.	50.	50.
Carrier gas	He		H2	H2	Nitrogen
Substrate
Column diameter (mm)	0.25	0.20	0.3	0.3	0.25
Phase thickness (μm)
T_start (C)	30.	60.	80.	80.	70.
T_end (C)	200.	230.	250.	250.	200.
Heat rate (K/min)	4.	3.	16.	16.	2.
Initial hold (min)	25.	10.
Final hold (min)	5.
I	1083.	1102.	1092.	1101.	1091.
Reference	Buttery, Teranishi, et al., 1990	Jantan and Goh, 1990	Spadone, Takeoka, et al., 1990	Spadone, Takeoka, et al., 1990	Sugisawa, Nakamura, et al., 1990
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	OV-101	BP-1	OV-101	OV-101	DB-1
Column length (m)	50.	25.	50.	50.	60.
Carrier gas	Nitrogen		N2	N2
Substrate
Column diameter (mm)	0.25	0.33	0.25	0.25	0.32
Phase thickness (μm)
T_start (C)	80.	45.	80.	80.	50.
T_end (C)	200.	180.	200.	200.	250.
Heat rate (K/min)	2.	3.	2.	2.	4.
Initial hold (min)		3.			0.1
Final hold (min)					5.
I	1087.	1083.	1086.	1086.	1083.
Reference	Sugisawa, Nakamura, et al., 1990	Wyllie, Brophy, et al., 1990	Yang and Sugisawa, 1990	Yang and Sugisawa, 1990	Binder and Flath, 1989
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	BP-1	SE-30	OV-101	OV-101	OV-101
Column length (m)	50.	40.	50.	50.	50.
Carrier gas	H2	He	N2	N2	N2
Substrate
Column diameter (mm)	0.30	0.50	0.25	0.25	0.25
Phase thickness (μm)		0.75
T_start (C)	40.	30.	80.	80.	80.
T_end (C)	250.	220.	200.	200.	200.
Heat rate (K/min)	10.	3.	2.	2.	2.
Initial hold (min)	1.
Final hold (min)
I	1084.	1085.	1088.	1083.	1086.
Reference	Brophy, Davies, et al., 1989	de Pooter, de Buyck, et al., 1989	Sugisawa, Yamamoto, et al., 1989	Sugisawa, Yang, et al., 1989	Sugisawa, Yang, et al., 1989
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-1	DB-1	SE-54	DB-1	DB-5
Column length (m)	60.	60.	25.	60.	30.
Carrier gas	He	He	N2	He	Hydrogen
Substrate
Column diameter (mm)	0.32	0.32	0.25	0.315	0.35
Phase thickness (μm)				0.25	1.0
T_start (C)	30.	30.	60.	50.	45.
T_end (C)	210.	210.	260.	250.	220.
Heat rate (K/min)	2.	2.	6.	4.	2.
Initial hold (min)	4.	4.	2.
Final hold (min)
I	1083.	1086.	1100.	1083.	1114.
Reference	Takeoka and Butter, 1989	Takeoka and Butter, 1989	Bestmann, Classen, et al., 1988	Engel, Flath, et al., 1988	Georgilopoulos and Gallois, 1988
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	OV-1	OV-101	OV-3	OV-101	OV-101
Column length (m)	60.	45.	150.	50.	50.
Carrier gas	Helium	He	He
Substrate
Column diameter (mm)	0.50	0.25	0.66	0.30	0.30
Phase thickness (μm)	1.2
T_start (C)	40.	100.	30.	40.	40.
T_end (C)	220.	180.	170.	230.	230.
Heat rate (K/min)	2.	3.	1.	3.5	3.5
Initial hold (min)				5.	5.
Final hold (min)
I	1085.	1112.	1120.	1084.	1086.
Reference	Wahab, Aboutabl, et al., 1987	Wu, Zhao, et al., 1987	Buttery, Flath, et al., 1986	Nykanen, 1986	Nykanen, 1986
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	OV-101	OV-3	OV-3	DB-1	DB-1
Column length (m)	30.	150.	150.	50.	50.
Carrier gas	He	He
Substrate
Column diameter (mm)	0.5	0.66	0.66	0.32	0.32
Phase thickness (μm)	0.8
T_start (C)	40.	20.	20.	0.	50.
T_end (C)	220.	170.	170.	250.	250.
Heat rate (K/min)	2.	1.	1.	3.	3.
Initial hold (min)
Final hold (min)		120.
I	1092.	1120.	1120.	1083.	1083.
Reference	De Pooter and Schamp, 1986	Buttery and Ling, 1985	Buttery, Xu, et al., 1985	Habu, Flath, et al., 1985	Habu, Flath, et al., 1985
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-1	SE-30	OV-1	SE-30+Igepal	SE-30+Igepal
Column length (m)	60.		183.	100.	100.
Carrier gas		Helium	N2
Substrate
Column diameter (mm)	0.32		0.762	0.25	0.25
Phase thickness (μm)
T_start (C)	50.	70.	0.	70.	70.
T_end (C)	250.	170.	230.	170.	170.
Heat rate (K/min)	4.	2.	1.	1.	1.
Initial hold (min)	0.1
Final hold (min)	5.
I	1082.	1118.	1084.	1091.	1095.
Reference	Flath, Mon, et al., 1983	Alves and Jennings, 1979	Schreyen, Dirinck, et al., 1979	Shibamoto and Jennings, 1977	Shibamoto and Jennings, 1977
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

References

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes

Bertuzzi, Tirillini, et al., 2013
Bertuzzi, G.; Tirillini, B.; Angelini, P.; Venanzoni, R., Antioxidative action of Citrus limonum essential oil on scin, Eur. J. Medicinal Plants, 2013, 3, 1, 1-9, https://doi.org/10.9734/EJMP/2013/1987 . [all data]

Pinheiro, de Queiros, et al., 2013
Pinheiro, P.F.; de Queiros, V.T.; Rondelli, V.M.; Costa, A.V.; MArcelino, T. deP.; Pratissoli, D., Insecticidal activity of citronells grass essential oil on Frankliniella schultzei and Myzus persicae, Cienc. Agrotec. Lavras, 2013, 37, 2, 138-144, https://doi.org/10.1590/S1413-70542013000200004 . [all data]

Pripdeevech and Saansoomchai, 2013
Pripdeevech, P.; Saansoomchai, J., Antibacterial activity and chemical composition of essential oil and various extracts of Fagraea fragrans Roxb. flowers, Chiang Mai J. Sci., 2013, 40, 2, 214-223. [all data]

Rodriques, Amorim, et al., 2013
Rodriques, K.A. da.F.; Amorim, L.V.; de Oliveira, J.M.G.; Dias, C.N.; Moraes, D.F.C.; Andrade, E.H. deA.; Maia, J.G.S.; Carneiro, S.M.P.; Carvalho, F.A. deA., Eugenia uniflora L. essential oil as a potential anti-Leishmania agent: effect on Leishmania amazonensis and possible mechanism of action, Evidence-Based Complementary and Alternative Medicine, 2013, 2013, 1-10, https://doi.org/10.1155/2013/279726 . [all data]

Sardashti, Valizadeh, et al., 2013
Sardashti, A.R.; Valizadeh, J.; Adhami, Y., Variations in the essential oil composition of Peroskia abrotonolides of different growth stage in Baluchestan, Middle-East J. Sci. Res., 2013, 13, 6, 781-784. [all data]

Alizadeh and Shaabani, 2012
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Kim and Lee, 2002
Kim, N.-S.; Lee, D.-S., Comparison of different extraction methods for the analysis of fragrances from Lavandula species by gas chromatography-mass spectrometry, J. Chromatogr. A, 2002, 982, 1, 31-47, https://doi.org/10.1016/S0021-9673(02)01445-0 . [all data]

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Kovacevic and Kac, 2002
Kovacevic, N.; Kac, M., Analytical, nutritional, and clinical methods section. Determination and verification of hop varieties by analysis of essential oils, Food Chem., 2002, 77, 4, 489-494, https://doi.org/10.1016/S0308-8146(02)00114-0 . [all data]

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Maia, Zoghbi, et al., 2002
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Pino, J.A.; Marbot, R.; Vazquez, C., Characterization of volatiles in Loquat fruit (Eriobotrya japonica Lindl.), Revista CENIC Ciencias Quimicas, 2002, 33, 3, 115-119. [all data]

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Sefidkon, 2002
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Tellez, M.R.; Khan, I.A.; Kobaisy, M.; Schrader, K.K.; Dayan, F.E.; Osbrink, W., Composition of the essential oil of Lepidium meyenii (Walp.), Phytochemistry, 2002, 61, 2, 149-155, https://doi.org/10.1016/S0031-9422(02)00208-X . [all data]

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Doimo, 2001
Doimo, L., Iso-citrals and iso-geraniols in lemon-myrtle (Backhousia citriodora F. Muell.) essential oils, J. Essent. Oil Res., 2001, 13, 4, 236-237, https://doi.org/10.1080/10412905.2001.9699680 . [all data]

Fernando and Grün, 2001
Fernando, L.N.; Grün, I.U., Headspace-SPME analysis of volatiles of the ridge gourd (Luffa acutangula) and bitter gourd (Momordica charantia) flowers, Flavour Fragr. J., 2001, 16, 4, 289-293, https://doi.org/10.1002/ffj.999 . [all data]

Flamini, Cioni, et al., 2001
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Czerny and Grosch, 2000
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Kotseridis and Baumes, 2000
Kotseridis, Y.; Baumes, R., Identification of impact odorants in Bordeaux red grape juice, in the commercial yeast used for its fermentation, and in the produced wine, J. Agric. Food Chem., 2000, 48, 2, 400-406, https://doi.org/10.1021/jf990565i . [all data]

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Mockute and Bernotiene, 1999
Mockute, D.; Bernotiene, G., The main citral-geraniol and carvacrol chemotypes of the essential oil of Thymus pulegioides L. growing wild in Vilnius district (Lithuania), J. Agric. Food Chem., 1999, 47, 9, 3787-3790, https://doi.org/10.1021/jf980987c . [all data]

Mohd and Jantan, 1999
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Ong and Acree, 1999
Ong, P.K.C.; Acree, T.E., Similarities in the aroma chemistry of Gewürztraminer variety wines and lychee (Litchi chinesis Sonn.) fruit, J. Agric. Food Chem., 1999, 47, 2, 665-670, https://doi.org/10.1021/jf980452j . [all data]

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Sun and Petracek, 1999
Sun, D.; Petracek, P.D., Grapefruit gland oil composition is affected by wax application, storage temperature, and storage time, J. Agric. Food Chem., 1999, 47, 5, 2067-2069, https://doi.org/10.1021/jf981064k . [all data]

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Binder and Flath, 1989
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Notes

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References

Symbols used in this document:

T_end Final temperature

T_start Initial temperature
Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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