e-Diazene, bis(bicyclo[2.2.2]oct-1-yl)-


Reaction thermochemistry data

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

cis-1-Azobicyclo[2.2.2]octane = e-Diazene, bis(bicyclo[2.2.2]oct-1-yl)-

By formula: C16H26N2 = C16H26N2

Quantity Value Units Method Reference Comment
Δr-25.91 ± 0.68kJ/molKinSchmittel and Ruchardt, 1987solid phase; solvent: Mesitylene

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias and Joel F. Liebman

Ionization energy determinations

IE (eV) Method Reference Comment
7.86PEEngel, Gerth, et al., 1988Vertical value

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Schmittel and Ruchardt, 1987
Schmittel, M.; Ruchardt, C., Stereoisomerization and homolytic decomposition of cis and trans bridgehead diazenes, J. Am. Chem. Soc., 1987, 109, 2750-2759. [all data]

Engel, Gerth, et al., 1988
Engel, P.S.; Gerth, D.B.; Keys, D.E.; Scholz, J.N.; Houk, K.N.; Rozeboom, M.D.; Eaton, T.A.; Glass, R.S.; Broeker, J.L., Ionization potentials of some azoalkanes by photoelectron spectroscopy, Tetrahedron, 1988, 44, 6811. [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References