- Formula: H4Si
- Molecular weight: 32.1173
- IUPAC Standard InChIKey: BLRPTPMANUNPDV-UHFFFAOYSA-N
- CAS Registry Number: 7803-62-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
- Other names: Silicane; Silicon hydride (SiH4); Silicon tetrahydride; SiH4; Monosilane; Silicon hydride; UN 2203
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Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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+ = ( )
By formula: H- + H4Si = (H- H4Si)
|rH°||19.0 ± 4.0||kcal/mol||IMRB||Hajdasz, Ho, et al., 1994||gas phase|
|rH°||22.5 ± 4.5||kcal/mol||IMRE||Hajdasz and Squires, 1986||gas phase; QCISD Calculation: H-A = 20.2, 99MOC|
|rG°||11.6 ± 4.1||kcal/mol||IMRB||Hajdasz, Ho, et al., 1994||gas phase|
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Hajdasz, Ho, et al., 1994
Hajdasz, D.J.; Ho, Y.; Squires, R.R., Gas-Phase Chemistry of Pentacoordinate Silicon Hydrides, J. Am. Chem. Soc., 1994, 116, 23, 10751, https://doi.org/10.1021/ja00102a045 . [all data]
Hajdasz and Squires, 1986
Hajdasz, D.J.; Squires, R.R., Hypervalent silicon hydrides: SiH5-, J. Am. Chem. Soc., 1986, 108, 3139. [all data]
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- Symbols used in this document:
rG° Free energy of reaction at standard conditions rH° Enthalpy of reaction at standard conditions
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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