Stibine
- Formula: H3Sb
- Molecular weight: 124.784
- CAS Registry Number: 7803-52-3
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
≤9.40 ± 0.02 | PI | Ruscic and Berkowitz, 1993 | LL |
9.51 | PE | Potts and Price, 1972 | LLK |
9.9 ± 0.3 | EI | Saalfeld and Svec, 1963 | RDSH |
9.58 | PI | Price and Passmore, 1963 | RDSH |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
HSb+ | 9.730 ± 0.008 | H2 | PI | Ruscic and Berkowitz, 1993 | LL |
SbH+ | 9.9 ± 0.2 | H2 | EI | Saalfeld and Svec, 1963 | RDSH |
H2Sb+ | 11.66 ± 0.02 | H | PI | Ruscic and Berkowitz, 1993 | LL |
SbH2+ | 11.8 ± 0.3 | H | EI | Saalfeld and Svec, 1963 | RDSH |
Sb+ | 12.1 ± 0.2 | H2+H | EI | Saalfeld and Svec, 1963 | RDSH |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ruscic and Berkowitz, 1993
Ruscic, B.; Berkowitz, J.,
Determination of consecutive bond energies by photoionization of SbHn (n=1-3),
J. Chem. Phys., 1993, 99, 5840. [all data]
Potts and Price, 1972
Potts, A.W.; Price, W.C.,
Photoelectron spectra and valence shell orbital structures of groups V VI hydrides,
Proc. R. Soc. London A:, 1972, 326, 181. [all data]
Saalfeld and Svec, 1963
Saalfeld, F.E.; Svec, H.J.,
The mass spectra of volatile hydrides. I. The monoelemental hydrides of the group IVB and VB elements,
Inorg. Chem., 1963, 2, 46. [all data]
Price and Passmore, 1963
Price, W.C.; Passmore, T.R.,
[Title unavailable],
Faraday Discuss. Chem. Soc., 1963, 35, 232. [all data]
Notes
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- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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