Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Stibine


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
<=9.40 ± 0.02PIRuscic and Berkowitz, 1993LL
9.51PEPotts and Price, 1972LLK
9.9 ± 0.3EISaalfeld and Svec, 1963RDSH
9.58PIPrice and Passmore, 1963RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
HSb+9.730 ± 0.008H2PIRuscic and Berkowitz, 1993LL
SbH+9.9 ± 0.2H2EISaalfeld and Svec, 1963RDSH
H2Sb+11.66 ± 0.02HPIRuscic and Berkowitz, 1993LL
SbH2+11.8 ± 0.3HEISaalfeld and Svec, 1963RDSH
Sb+12.1 ± 0.2H2+HEISaalfeld and Svec, 1963RDSH

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ruscic and Berkowitz, 1993
Ruscic, B.; Berkowitz, J., Determination of consecutive bond energies by photoionization of SbHn (n=1-3), J. Chem. Phys., 1993, 99, 5840. [all data]

Potts and Price, 1972
Potts, A.W.; Price, W.C., Photoelectron spectra and valence shell orbital structures of groups V VI hydrides, Proc. R. Soc. London A:, 1972, 326, 181. [all data]

Saalfeld and Svec, 1963
Saalfeld, F.E.; Svec, H.J., The mass spectra of volatile hydrides. I. The monoelemental hydrides of the group IVB and VB elements, Inorg. Chem., 1963, 2, 46. [all data]

Price and Passmore, 1963
Price, W.C.; Passmore, T.R., [Title unavailable], Faraday Discuss. Chem. Soc., 1963, 35, 232. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References