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Phosphine

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

H4P+ + Phosphine = (H4P+ bullet Phosphine)

By formula: H4P+ + H3P = (H4P+ bullet H3P)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar11.5kcal/molDTLong and Franklin, 1974gas phase
Quantity Value Units Method Reference Comment
Deltar25.9cal/mol*KDTLong and Franklin, 1974gas phase

(H4P+ bullet Phosphine) + Phosphine = (H4P+ bullet 2Phosphine)

By formula: (H4P+ bullet H3P) + H3P = (H4P+ bullet 2H3P)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar9.2kcal/molDTLong and Franklin, 1974gas phase
Quantity Value Units Method Reference Comment
Deltar22.3cal/mol*KDTLong and Franklin, 1974gas phase

(H4P+ bullet 2Phosphine) + Phosphine = (H4P+ bullet 3Phosphine)

By formula: (H4P+ bullet 2H3P) + H3P = (H4P+ bullet 3H3P)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar7.3kcal/molDTLong and Franklin, 1974gas phase
Quantity Value Units Method Reference Comment
Deltar18.4cal/mol*KDTLong and Franklin, 1974gas phase

(H4P+ bullet 3Phosphine) + Phosphine = (H4P+ bullet 4Phosphine)

By formula: (H4P+ bullet 3H3P) + H3P = (H4P+ bullet 4H3P)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar6.5kcal/molDTLong and Franklin, 1974gas phase
Quantity Value Units Method Reference Comment
Deltar15.0cal/mol*KDTLong and Franklin, 1974gas phase

(H4P+ bullet 4Phosphine) + Phosphine = (H4P+ bullet 5Phosphine)

By formula: (H4P+ bullet 4H3P) + H3P = (H4P+ bullet 5H3P)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar5.5kcal/molDTLong and Franklin, 1974gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar13.2cal/mol*KN/ALong and Franklin, 1974gas phase; Entropy change calculated or estimated

H5P2+ + Phosphine = (H5P2+ bullet Phosphine)

By formula: H5P2+ + H3P = (H5P2+ bullet H3P)

Quantity Value Units Method Reference Comment
Deltar9.kcal/molDTLong and Franklin, 1974gas phase
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KDTLong and Franklin, 1974gas phase

H6P3+ + Phosphine = (H6P3+ bullet Phosphine)

By formula: H6P3+ + H3P = (H6P3+ bullet H3P)

Quantity Value Units Method Reference Comment
Deltar10.8kcal/molDTLong and Franklin, 1974gas phase
Quantity Value Units Method Reference Comment
Deltar34.cal/mol*KDTLong and Franklin, 1974gas phase

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Long and Franklin, 1974
Long, J.W.; Franklin, J.L., Ion - Solvation Reactions of Phosphine, J. Am. Chem. Soc., 1974, 96, 8, 2320, https://doi.org/10.1021/ja00815a003 . [all data]


Notes

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