Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

thallium chloride

Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Quantity Value Units Method Reference Comment
IE (evaluated)9.70 ± 0.03eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
9.70PEBancroft and Bristow, 1983LBLHLM
9.70 ± 0.03PIBerkowitz and Walter, 1968RDSH
9.8PEBancroft and Bristow, 1983Vertical value; LBLHLM
9.92PEEgdell and Orchard, 1978Vertical value; LLK
9.91PEEvans and Orchard, 1975Vertical value; LLK
9.894PEBerkowitz, 1972Vertical value; LLK
9.925PEBerkowitz, 1971Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Cl+16.9 ± 0.1TlEIKhvostenko and Sultanov, 1965RDSH
Tl+7.01Cl-PIBerkowitz and Walter, 1968RDSH
Tl+9.93 ± 0.02ClPIBerkowitz and Walter, 1968RDSH


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bancroft and Bristow, 1983
Bancroft, G.M.; Bristow, D.J., High resolution HeI and HeII photoelectron spectra of the thallium halides: Valence bands and Tl 5d ligand field splittings, Can. J. Chem., 1983, 61, 2669. [all data]

Berkowitz and Walter, 1968
Berkowitz, J.; Walter, T.A., Photoionization of high-temperature vapors. IV.TIF, TICI, and TIBr, J. Chem. Phys., 1968, 49, 1184. [all data]

Egdell and Orchard, 1978
Egdell, R.G.; Orchard, A.F., He(II) Photoelectron spectra of indium(I) and thallium(I) halides, J. Chem. Soc. Faraday Trans. 2, 1978, 74, 1179. [all data]

Evans and Orchard, 1975
Evans, S.; Orchard, A.F., The vapour phase ultra-violet photoelectron spectroscopy of metal halides at elevated temperatures, J. Electron Spectrosc. Relat. Phenom., 1975, 6, 207. [all data]

Berkowitz, 1972
Berkowitz, J., Photoelectron spectroscopy of high-temperature vapors. I. TlCl, TlBr, and TlI, J. Chem. Phys., 1972, 56, 2766. [all data]

Berkowitz, 1971
Berkowitz, J., Photoionization mass spectrometry photoelectron spectroscopy of high temperature vapor, Adv. High Temp. Chem., 1971, 3, 123. [all data]

Khvostenko and Sultanov, 1965
Khvostenko, V.I.; Sultanov, A.Sh., Ionisation of thallium(I) chloride, bromide, and iodide molecules by electron bombardment, Zh. Fiz. Khim., 1965, 39, 475, In original 252. [all data]


Go To: Top, Gas phase ion energetics data, References