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rubidium chloride

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Quantity Value Units Method Reference Comment
IE (evaluated)8.50 ± 0.03eVN/AN/AL

Electron affinity determinations

EA (eV) Method Reference Comment
0.543 ± 0.010LPESMiller, Leopold, et al., 1986B
>1.53999EIAEEbinghaus, 1964From (RbCl)2; B

Ionization energy determinations

IE (eV) Method Reference Comment
8.2EIWilliams, 1982LBLHLM
8.3 ± 0.1PEPotts and Price, 1977LLK
8.3 ± 0.1PEPotts, Williams, et al., 1974LLK
8.50 ± 0.03PIBerkowitz, 1971LLK
8.7PEGoodman, Allen, et al., 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Rb+8.70 ± 0.03ClPIBerkowitz, 1971LLK
Rb+9.2 ± 0.5ClEIHastie and Swingler, 1969RDSH
Rb+8.9 ± 0.5ClEIBloom, Hastie, et al., 1968RDSH
Rb+21.17 ± 0.04Cl(-)PEPotts and Price, 1977Vertical value; LLK


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Miller, Leopold, et al., 1986
Miller, T.M.; Leopold, D.G.; Murray, K.K.; Lineberger, W.C., Electron Affinities of the Alkali Halides and the Structure of their Negative Ions, J. Chem. Phys., 1986, 85, 5, 2368, https://doi.org/10.1063/1.451091 . [all data]

Ebinghaus, 1964
Ebinghaus, H.Z., Negative Ionen aus Alkalihalogeniden und Electronenaffinitaten der Alkalimetalle und Alkalihalogenide, Z. Naturfor., 1964, 19A, 727. [all data]

Williams, 1982
Williams, D.J., Mass spectrometric study of the vaporization of the alkali chloride-cuprous chloride systems, Aust. J. Chem., 1982, 35, 1531. [all data]

Potts and Price, 1977
Potts, A.W.; Price, W.C., Photoelectron studies of ionic materials using molecular beam techniques, Phys. Scr., 1977, 16, 191. [all data]

Potts, Williams, et al., 1974
Potts, A.W.; Williams, T.A.; Price, W.C., Photoelectron spectra and electronic structure of diatomic alkali halides, Proc. Roy. Soc. London A, 1974, 341, 147. [all data]

Berkowitz, 1971
Berkowitz, J., Photoionization mass spectrometry photoelectron spectroscopy of high temperature vapor, Adv. High Temp. Chem., 1971, 3, 123. [all data]

Goodman, Allen, et al., 1974
Goodman, T.D.; Allen, J.D., Jr.; Cusachs, L.C.; Schweitzer, G.K., The photoelectron spectra of gaseous alkali halides, J. Electron Spectrosc. Relat. Phenom., 1974, 3, 289. [all data]

Hastie and Swingler, 1969
Hastie, J.W.; Swingler, D.L., Use of the quadrupole mass filter for high-temperature studies, High Temp. Sci., 1969, 1, 46. [all data]

Bloom, Hastie, et al., 1968
Bloom, H.; Hastie, J.W.; Morrison, J.D., Ionization and dissociation of the alkali halides by electron impact, J. Phys. Chem., 1968, 72, 3041. [all data]


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