Chloridosulfuric acid


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Reference Comment
45.8339.Dykyj, Svoboda, et al., 1999Based on data from 324. to 454. K.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

n-Pentadecanol + Chloridosulfuric acid = Pentadecyl sulfuric acid + Hydrogen chloride

By formula: C15H32O + ClHO3S = C15H32O4S + HCl

Quantity Value Units Method Reference Comment
Δr56. ± 3.kJ/molCmMarkitanova, Barsukov, et al., 1981liquid phase; solvent: Dichloromethane; Sulfation

1-Hexadecanol + Chloridosulfuric acid = C16H34O4S + Hydrogen chloride

By formula: C16H34O + ClHO3S = C16H34O4S + HCl

Quantity Value Units Method Reference Comment
Δr57. ± 3.kJ/molCmMarkitanova, Barsukov, et al., 1981liquid phase; solvent: Dichloromethane; Sulfation

1-Butanol + Chloridosulfuric acid = Butyl sulfuric acid + Hydrogen chloride

By formula: C4H10O + ClHO3S = C4H10O4S + HCl

Quantity Value Units Method Reference Comment
Δr58. ± 1.kJ/molCmMarkitanova, Barsukov, et al., 1981liquid phase; solvent: Dichloromethane; Sulfation

1-Undecanol + Chloridosulfuric acid = Undecyl sulfuric acid + Hydrogen chloride

By formula: C11H24O + ClHO3S = C11H24O4S + HCl

Quantity Value Units Method Reference Comment
Δr60. ± 3.kJ/molCmMarkitanova, Barsukov, et al., 1981liquid phase; solvent: Dichloromethane; Sulfation

1-Octanol + Chloridosulfuric acid = C8H18O4S + Hydrogen chloride

By formula: C8H18O + ClHO3S = C8H18O4S + HCl

Quantity Value Units Method Reference Comment
Δr55. ± 1.kJ/molCmMarkitanova, Barsukov, et al., 1981liquid phase; solvent: Dichloromethane; Sulfation

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R., Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]

Markitanova, Barsukov, et al., 1981
Markitanova, L.I.; Barsukov, I.I.; Passet, B.V., Determination of heat of sulfation by calorimetric titration, J. Gen. Chem. USSR, 1981, 51, 1286-1289. [all data]


Notes

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