Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

chlorine trifluoride

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.

Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to ClF3+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
>2.40 ± 0.10EIAEBaluev, Nikitin, et al., 1980From ClF5; G3MP2B3 calculations indicate an EA of ca. 3.3 eV; B

Ionization energy determinations

IE (eV) Method Reference Comment
12.65 ± 0.05PEDeKock, Higginson, et al., 1972LLK
13.0 ± 0.2EIIrsa and Friedman, 1958RDSH
13.05 ± 0.05EIDudin, Gorokhov, et al., 1979Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
F2<35>Cl+13.78 ± 0.07FEIDudin, Gorokhov, et al., 1979LLK
ClF2+12.8 ± 0.3FEIIrsa and Friedman, 1958RDSH


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Baluev, Nikitin, et al., 1980
Baluev, A.V.; Nikitin, I.M.; Fedorova, L.I.; Rossolovskii, V.Ya., Mass Spectrometric Study of Chlorine Pentafluoride Ionization by Electron Impact, Izv. Akad. Nauk SSR Ser. Khim. 487, 1980. [all data]

DeKock, Higginson, et al., 1972
DeKock, R.L.; Higginson, B.R.; Lloyd, D.R.; Breeze, A.; Cruickshank, D.W.J.; Armstrong, D.R., Photoelectron spectra of halides. V. Experimental theoretical study of the electronic structures of ClF, ClF3, BrF and BrF3, Mol. Phys., 1972, 24, 1059. [all data]

Irsa and Friedman, 1958
Irsa, A.P.; Friedman, L., Mass spectra of halogen fluorides, J. Inorg. Nucl. Chem., 1958, 6, 77. [all data]

Dudin, Gorokhov, et al., 1979
Dudin, A.V.; Gorokhov, L.N.; Baluev, A.V., A study of the electron-impact ionization of chlorine trifluoride and its decomposition products by mass spectrometry, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1979, 11, 2408. [all data]


Go To: Top, Gas phase ion energetics data, References