Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

chlorine fluoride

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to ClF+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)12.66 ± 0.01eVN/AN/AL

Electron affinity determinations

EA (eV) Method Reference Comment
>1.50 ± 0.20EIAEIllenberger, Baumgartel, et al., 1979From CFCl3; B
>1.50 ± 0.40EIAEThynne, 1972From SF5Cl; B
2.86 ± 0.20EIAEDudin, Gorokhov, et al., 1979From ClF3; B
1.50 ± 0.30NBIEDispert and Lacmann, 1978From CF2Cl2; G3MP2B3 calculations indicate an EA of ca. 2.1 eV; B

Ionization energy determinations

IE (eV) Method Reference Comment
12.74 ± 0.01PEDeKock, Higginson, et al., 1972LLK
12.66 ± 0.01PEDeKock, Higginson, et al., 1972LLK
12.74 ± 0.01PEAnderson, Mamantov, et al., 1971LLK
12.66 ± 0.01PEAnderson, Mamantov, et al., 1971LLK
12.65 ± 0.01PIDibeler, Walker, et al., 1970RDSH
12.7 ± 0.3EIIrsa and Friedman, 1958RDSH
12.77PEDyke, Josland, et al., 1984Vertical value; LBLHLM

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Cl+12.04F-PIDibeler, Walker, et al., 1970RDSH
Cl+15.50 ± 0.04FPIDibeler, Walker, et al., 1970RDSH

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Illenberger, Baumgartel, et al., 1979
Illenberger, T.; Baumgartel, H.; Scheunemann, H., Negative Ion Formation in CF2Cl2, CF3Cl, and CFCl3 Following Low Energy (0-10eV) Impact with Near Monoenergetic Electrons, Chem. Phys., 1979, 37, 1, 21, https://doi.org/10.1016/0301-0104(79)80003-8 . [all data]

Thynne, 1972
Thynne, J.C.J., Negative Ion Studies with a Time-of-Flight Mass Spectrometer., Dyn. Mass Spectrom., 1972, 3, 67. [all data]

Dudin, Gorokhov, et al., 1979
Dudin, A.V.; Gorokhov, L.N.; Baluev, A.V., A Study of the Electron Impact Ionization of Chlorine Trifluoride and Its Decomposition Products by Mass Spectrometry, Izv. Akad. Nauk SSR Ser. Khim. 2408, 1979. [all data]

Dispert and Lacmann, 1978
Dispert, H.; Lacmann, K., Negative ion formation in collisions between potassium and fluoro- and chloromethanes: Electron affinities and bond dissociation energies, Int. J. Mass Spectrom. Ion Phys., 1978, 28, 49. [all data]

DeKock, Higginson, et al., 1972
DeKock, R.L.; Higginson, B.R.; Lloyd, D.R.; Breeze, A.; Cruickshank, D.W.J.; Armstrong, D.R., Photoelectron spectra of halides. V. Experimental theoretical study of the electronic structures of ClF, ClF3, BrF and BrF3, Mol. Phys., 1972, 24, 1059. [all data]

Anderson, Mamantov, et al., 1971
Anderson, C.P.; Mamantov, G.; Bull, W.E.; Grimm, F.A.; Carver, J.C.; Carlson, T.A., Photoelectron spectrum of chlorine monofluoride, Chem. Phys. Lett., 1971, 12, 137. [all data]

Dibeler, Walker, et al., 1970
Dibeler, V.H.; Walker, J.A.; McCulloh, K.E., Photoionization study of chlorine monofluoride and the dissociation energy of fluorine, J. Chem. Phys., 1970, 53, 4414. [all data]

Irsa and Friedman, 1958
Irsa, A.P.; Friedman, L., Mass spectra of halogen fluorides, J. Inorg. Nucl. Chem., 1958, 6, 77. [all data]

Dyke, Josland, et al., 1984
Dyke, J.M.; Josland, G.D.; Snijders, J.G.; Boerrigter, P.M., Ionization energies of the diatomic halogens and interhalogens studied with relativistic hartree-fock-slater calculations, Chem. Phys., 1984, 91, 419. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References