chlorine fluoride

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to ClF+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)12.66 ± 0.01eVN/AN/AL

Electron affinity determinations

EA (eV) Method Reference Comment
>1.50 ± 0.20EIAEIllenberger, Baumgartel, et al., 1979From CFCl3; B
>1.50 ± 0.40EIAEThynne, 1972From SF5Cl; B
2.86 ± 0.20EIAEDudin, Gorokhov, et al., 1979From ClF3; B
1.50 ± 0.30NBIEDispert and Lacmann, 1978From CF2Cl2; G3MP2B3 calculations indicate an EA of ca. 2.1 eV; B

Ionization energy determinations

IE (eV) Method Reference Comment
12.74 ± 0.01PEDeKock, Higginson, et al., 1972LLK
12.66 ± 0.01PEDeKock, Higginson, et al., 1972LLK
12.74 ± 0.01PEAnderson, Mamantov, et al., 1971LLK
12.66 ± 0.01PEAnderson, Mamantov, et al., 1971LLK
12.65 ± 0.01PIDibeler, Walker, et al., 1970RDSH
12.7 ± 0.3EIIrsa and Friedman, 1958RDSH
12.77PEDyke, Josland, et al., 1984Vertical value; LBLHLM

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Cl+12.04F-PIDibeler, Walker, et al., 1970RDSH
Cl+15.50 ± 0.04FPIDibeler, Walker, et al., 1970RDSH


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Illenberger, Baumgartel, et al., 1979
Illenberger, T.; Baumgartel, H.; Scheunemann, H., Negative Ion Formation in CF2Cl2, CF3Cl, and CFCl3 Following Low Energy (0-10eV) Impact with Near Monoenergetic Electrons, Chem. Phys., 1979, 37, 1, 21, . [all data]

Thynne, 1972
Thynne, J.C.J., Negative Ion Studies with a Time-of-Flight Mass Spectrometer., Dyn. Mass Spectrom., 1972, 3, 67. [all data]

Dudin, Gorokhov, et al., 1979
Dudin, A.V.; Gorokhov, L.N.; Baluev, A.V., A Study of the Electron Impact Ionization of Chlorine Trifluoride and Its Decomposition Products by Mass Spectrometry, Izv. Akad. Nauk SSR Ser. Khim. 2408, 1979. [all data]

Dispert and Lacmann, 1978
Dispert, H.; Lacmann, K., Negative ion formation in collisions between potassium and fluoro- and chloromethanes: Electron affinities and bond dissociation energies, Int. J. Mass Spectrom. Ion Phys., 1978, 28, 49. [all data]

DeKock, Higginson, et al., 1972
DeKock, R.L.; Higginson, B.R.; Lloyd, D.R.; Breeze, A.; Cruickshank, D.W.J.; Armstrong, D.R., Photoelectron spectra of halides. V. Experimental theoretical study of the electronic structures of ClF, ClF3, BrF and BrF3, Mol. Phys., 1972, 24, 1059. [all data]

Anderson, Mamantov, et al., 1971
Anderson, C.P.; Mamantov, G.; Bull, W.E.; Grimm, F.A.; Carver, J.C.; Carlson, T.A., Photoelectron spectrum of chlorine monofluoride, Chem. Phys. Lett., 1971, 12, 137. [all data]

Dibeler, Walker, et al., 1970
Dibeler, V.H.; Walker, J.A.; McCulloh, K.E., Photoionization study of chlorine monofluoride and the dissociation energy of fluorine, J. Chem. Phys., 1970, 53, 4414. [all data]

Irsa and Friedman, 1958
Irsa, A.P.; Friedman, L., Mass spectra of halogen fluorides, J. Inorg. Nucl. Chem., 1958, 6, 77. [all data]

Dyke, Josland, et al., 1984
Dyke, J.M.; Josland, G.D.; Snijders, J.G.; Boerrigter, P.M., Ionization energies of the diatomic halogens and interhalogens studied with relativistic hartree-fock-slater calculations, Chem. Phys., 1984, 91, 419. [all data]


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