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rubidium iodide

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Electron affinity determinations

EA (eV) Reference Comment
0.710 ± 0.040Miller, Leopold, et al., 1986Extrapolated by polarizability and radius from experimental data.; B

Ionization energy determinations

IE (eV) Method Reference Comment
7.2 ± 0.4EIEmons, Horlbeck, et al., 1982LBLHLM
6.6 ± 0.4EIBiefeld, 1978LLK
7.1 ± 0.1PEPotts and Price, 1977LLK
7.1 ± 0.1PEPotts, Williams, et al., 1974LLK
7.31 ± 0.03PIBerkowitz, 1971LLK
8.0 ± 0.3EIPlatel, 1965RDSH
7.3PEGoodman, Allen, et al., 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
I+14.4 ± 0.3RbEIPlatel, 1965RDSH
Rb+9.4 ± 0.4IEIBiefeld, 1978LLK
Rb+7.53 ± 0.03IPIBerkowitz, 1971LLK
Rb+8.1 ± 0.3IEIPlatel, 1965RDSH
Rb+21.33 ± 0.04I(-)PEPotts and Price, 1977Vertical value; LLK
Rb+22.21 ± 0.04I(-)PEPotts and Price, 1977Vertical value; LLK


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Miller, Leopold, et al., 1986
Miller, T.M.; Leopold, D.G.; Murray, K.K.; Lineberger, W.C., Electron Affinities of the Alkali Halides and the Structure of their Negative Ions, J. Chem. Phys., 1986, 85, 5, 2368, https://doi.org/10.1063/1.451091 . [all data]

Emons, Horlbeck, et al., 1982
Emons, H.-H.; Horlbeck, W.; Kiessling, D., Massenspektrometrische untersuchung der gasphase uber alkalimetalliodiden, Z. Anorg. Allg. Chem., 1982, 488, 212. [all data]

Biefeld, 1978
Biefeld, R.M., The vaporization thermodynamics of rubidium iodide as determined by mass-loss Knudsen effusion and mass spectrometry, J. Chem. Thermodyn., 1978, 10, 907. [all data]

Potts and Price, 1977
Potts, A.W.; Price, W.C., Photoelectron studies of ionic materials using molecular beam techniques, Phys. Scr., 1977, 16, 191. [all data]

Potts, Williams, et al., 1974
Potts, A.W.; Williams, T.A.; Price, W.C., Photoelectron spectra and electronic structure of diatomic alkali halides, Proc. Roy. Soc. London A, 1974, 341, 147. [all data]

Berkowitz, 1971
Berkowitz, J., Photoionization mass spectrometry photoelectron spectroscopy of high temperature vapor, Adv. High Temp. Chem., 1971, 3, 123. [all data]

Platel, 1965
Platel, G., Mesures des potentials d'apparition des ions obtenus par impact electronique dans la phase vapeur des iodures alcalins et des melanges LiI-MI, J. Chim. Phys., 1965, 62, 1176. [all data]

Goodman, Allen, et al., 1974
Goodman, T.D.; Allen, J.D., Jr.; Cusachs, L.C.; Schweitzer, G.K., The photoelectron spectra of gaseous alkali halides, J. Electron Spectrosc. Relat. Phenom., 1974, 3, 289. [all data]


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